781 research outputs found
Fluxes of Copper-Complexing Ligands from Estuarine Sediments
Most studies of the organic complexation of Cu in natural waters have focused on distributions and processes in the water column, where a significant fraction of Cu-complexing ligands may be biologically produced. We present direct evidence for a flux of Cu-complexing ligands from estuarine sediments, demonstrating that sediments are a significant, yet previously unrecognized source of the ligands. Fluxes of Cu-complexing ligands from Chesapeake Bay sediments range from 300 to 1,200 nmol m-2 d-1, exceeding fluxes of total dissolved Cu by 3-\u3e40-fold, suggesting that any Cu fluxing from the sediments is likely to be organically complexed. Our results indicate that benthic fluxes may supply from 10 to 50% of the standing stock of Cu-complexing ligands in Chesapeake Bay and suggest that such fluxes may strongly influence the biogeochemistry of Cu in shallow water environments and potentially in the ocean as a whole
Relativistic hydrodynamics on spacelike and null surfaces: Formalism and computations of spherically symmetric spacetimes
We introduce a formulation of Eulerian general relativistic hydrodynamics
which is applicable for (perfect) fluid data prescribed on either spacelike or
null hypersurfaces. Simple explicit expressions for the characteristic speeds
and fields are derived in the general case. A complete implementation of the
formalism is developed in the case of spherical symmetry. The algorithm is
tested in a number of different situations, predisposing for a range of
possible applications. We consider the Riemann problem for a polytropic gas,
with initial data given on a retarded/advanced time slice of Minkowski
spacetime. We compute perfect fluid accretion onto a Schwarzschild black hole
spacetime using ingoing null Eddington-Finkelstein coordinates. Tests of fluid
evolution on dynamic background include constant density and TOV stars sliced
along the radial null cones. Finally, we consider the accretion of
self-gravitating matter onto a central black hole and the ensuing increase in
the mass of the black hole horizon.Comment: 23 pages, 13 figures, submitted to Phys. Rev.
Representation of climate extreme indices in the ACCESS1.3b coupled atmosphereâland surface model
Climate extremes, such as heat waves and heavy precipitation events, have large impacts on ecosystems and societies. Climate models provide useful tools for studying underlying processes and amplifying effects associated with extremes. The Australian Community Climate and Earth System Simulator (ACCESS) has recently been coupled to the Community Atmosphere Biosphere Land Exchange (CABLE) model. We examine how this model represents climate extremes derived by the Expert Team on Climate Change Detection and Indices (ETCCDI) and compare them to observational data sets using the AMIP framework. We find that the patterns of extreme indices are generally well represented. Indices based on percentiles are particularly well represented and capture the trends over the last 60 years shown by the observations remarkably well. The diurnal temperature range is underestimated, minimum temperatures (TMIN) during nights are generally too warm and daily maximum temperatures (TMAX) too low in the model. The number of consecutive wet days is overestimated, while consecutive dry days are underestimated. The maximum consecutive 1-day precipitation amount is underestimated on the global scale. Biases in TMIN correlate well with biases in incoming longwave radiation, suggesting a relationship with biases in cloud cover. Biases in TMAX depend on biases in net shortwave radiation as well as evapotranspiration. The regions and season where the bias in evapotranspiration plays a role for the TMAX bias correspond to regions and seasons where soil moisture availability is limited. Our analysis provides the foundation for future experiments that will examine how land-surface processes contribute to these systematic biases in the ACCESS modelling system
Three Dimensional Numerical General Relativistic Hydrodynamics I: Formulations, Methods, and Code Tests
This is the first in a series of papers on the construction and validation of
a three-dimensional code for general relativistic hydrodynamics, and its
application to general relativistic astrophysics. This paper studies the
consistency and convergence of our general relativistic hydrodynamic treatment
and its coupling to the spacetime evolutions described by the full set of
Einstein equations with a perfect fluid source. The numerical treatment of the
general relativistic hydrodynamic equations is based on high resolution shock
capturing schemes. These schemes rely on the characteristic information of the
system. A spectral decomposition for general relativistic hydrodynamics
suitable for a general spacetime metric is presented. Evolutions based on three
different approximate Riemann solvers coupled to four different discretizations
of the Einstein equations are studied and compared. The coupling between the
hydrodynamics and the spacetime (the right and left hand side of the Einstein
equations) is carried out in a treatment which is second order accurate in {\it
both} space and time. Convergence tests for all twelve combinations with a
variety of test beds are studied, showing consistency with the differential
equations and correct convergence properties. The test-beds examined include
shocktubes, Friedmann-Robertson-Walker cosmology tests, evolutions of
self-gravitating compact (TOV) stars, and evolutions of relativistically
boosted TOV stars. Special attention is paid to the numerical evolution of
strongly gravitating objects, e.g., neutron stars, in the full theory of
general relativity, including a simple, yet effective treatment for the surface
region of the star (where the rest mass density is abruptly dropping to zero).Comment: 45 pages RevTeX, 34 figure
Self-activated, Nanostructured Composite for Improved CaL-CLC technology
The development of bifunctional CaO/CuO matrix composites with both high and stable reactivity is a research priority and key for the development of calcium looping integrated with chemical looping combustion (CaL-CLC), a new CO2 capture technology that eliminates the requirement for pure O2 for the regeneration of CaO-based sorbents. In this work, a simple but effective approach was first used, i.e., solution combustion synthesis (SCS), to produce various nanostructured CaO/CuO matrix composites with homogenous elemental distributions. All CaO/CuO matrix composites possessed increased CO2 uptake in the form of self-activation and excellent cyclically stable O2 carrying capacity over as many as 40 reaction cycles. For instance, the final carbonation conversion of CaO-CuO-1-800-30 was 51.3%, approximately 52.7% higher than that of the original material (33.6%). Here, the self-activation phenomenon have been observed for the first time in contrast to the rapid decay in CO2 uptake capacity previously reported, due mainly to the increase of both specific surface area and pore volume. In-situ X-ray diffraction (in-situ XRD) analysis revealed that no side reactions occurred between CaO/CaCO3 and CuO/Cu during the overall process. All of these results make CaO/CuO matrix composites an attractive candidate for CaL-CLC
Improving Visual-Patient-Avatar Design Prior to Its Clinical Release: A Mixed Qualitative and Quantitative Study
Visual-Patient-avatar, an avatar-based visualisation of patient monitoring, is a newly developed technology aiming to promote situation awareness through user-centred design. Before the technologyâs introduction into clinical practice, the initial design used to validate the concept had to undergo thorough examination and adjustments where necessary. This mixed qualitative and quantitative study, consisting of three different study parts, aimed to create a design with high user acceptance regarding perceived professionalism and potential for identification while maintaining its original functionality. The first qualitative part was based on structured interviews and explored anaesthesia personnelâs first impressions regarding the original design. Recurrent topics were identified using inductive coding, participantsâ interpretations of the vital sign visualisations analysed and design modifications derived. The second study part consisted of a redesign process, in which the visualisations were adapted according to the results of the first part. In a third, quantitative study part, participants rated Likert scales about Visual-Patient-avatarâs appearance and interpreted displayed vital signs in a computer-based survey. The first, qualitative study part included 51 structured interviews. Twenty-eight of 51 (55%) participants mentioned the appearance of Visual-Patient-avatar. In 23 of 51 (45%) interviews, 26 statements about the general impression were identified with a balanced count of positive (14 of 26) and negative (12 of 26) comments. The analysis of vital sign visualisations showed deficits in several vital sign visualisations, especially central venous pressure. These findings were incorporated into part two, the redesign of Visual-Patient-avatar. In the subsequent quantitative analysis of study for part three, 20 of 30 (67%) new participants agreed that the avatar looks professional enough for medical use. Finally, the participants identified 73% (435 of 600 cases) of all vital sign visualisations intuitively correctly without prior instruction. This study succeeded in improving the original design with good user acceptance and a reasonable degree of intuitiveness of the new, revised design. Furthermore, the study identified aspects relevant for the release of Visual-Patient-avatar, such as the requirement for providing at least some training, despite the designâs intuitiveness. The results of this study will guide further research and improvement of the technology. The study provides a link between Visual-Patient-avatar as a scientific concept and as an actual product from a cognitive engineering point of view, and may serve as an example of methods to study the designs of technologies in similar contexts
Anesthesia personnelâs visual attention regarding patient monitoring in simulated non-critical and critical situations, an eye-tracking study
Background: Cognitive ergonomics design of patient monitoring may reduce human factor errors in high-stress environments. Eye-tracking is a suitable tool to gain insight into the distribution of visual attention of healthcare professionals with patient monitors, which may facilitate their further development.
Methods: This prospective, exploratory, high-fidelity simulation study compared anesthesia personnel's visual attention (fixation count and dwell-time) to 15 areas of interest on the patient monitor during non-critical and critical anesthesia situations. Furthermore, we examined the extent to which participants' experience influenced visual attention and which vital signs displayed on the patient monitor received the most visual attention. We used mixed zero-inflated Poisson regression and mixed linear models to analyze the data.
Results: Analyzing 23 ten-minute scenarios, we found significantly more fixations to the areas of interest on the patient monitor during critical than non-critical situations (rate ratio of 1.45; 95% CI 1.33 to 1.59; p < 0.001). However, the dwell-time on the areas of interest did not significantly differ between the non-critical and critical situations (coefficient of - 1.667; 95% CI - 4.549 to 1.229; p = 0.27). The professional experience did not significantly influence the visual attention (fixation: rate ratio of 0.88; 95% CI 0.54 to 1.43; p = 0.61 and dwell-time: coefficient of 0.889; 95% CI - 1.465 to 3.229; p = 0.27). Over all situations, anesthesia personnel paid the most attention to the vital signs blood pressure (fixation: mean [SD] of 108 [74.83]; dwell-time: mean [SD] of 27 [15.90] seconds), end-expiratory carbon dioxide (fixation: mean [SD] of 59 [47.39]; dwell-time: mean [SD] of 30 [21.51] seconds), and the electrocardiogram (fixation: mean [SD] of 58 [64.70]; dwell-time: mean [SD] of 15 [14.95] seconds).
Conclusions: Critical anesthesia situations increased anesthesia personnel's visual interaction with the patient monitor. Furthermore, we found that their visual attention focused mainly on a few vital signs. To assist clinicians in critical situations, manufacturers should optimize monitors to convey necessary information as easily and quickly as possible and optimize the visibility of less frequently observed but equally critical vital signs, especially when they are in an abnormal range.
Keywords: Anesthesia, general; Eye-tracking technology; Patient monitoring; Patient simulation; Situation awareness; Visual attention
Physicians' perceptions of two ways of algorithm presentation: graphic versus text-based approach
Acute bleeding during surgery or after trauma harms patients, and challenges involved physicians. Protocols and cognitive aids can help in such situations. This dual-centre study investigated physicians' opinions regarding two ways to present cognitive aids, graphic âHaemostasis Traffic Lightâ and text-based, using the example of a coagulation management algorithm to identify the strengths and limitations of both presentation modalities. Using qualitative research methods, we identified recurring answer patterns and derived major topics and subthemes through inductive coding. Eighty-four physicians participated. We assigned each half randomly to one of the cognitive aids (graphic/text-based) and determined 447 usable statements. We qualitatively deduced the importance of having a cognitive aid for physicians. Furthermore, it is noticeable that the graphic group made more positive comments (154 of 242 (64%) statements), while the text-based participants made more negative annotations (126 of 205 (61%) statements), suggesting a generally stronger approval of this cognitive aid
Relativistic Hydrodynamics around Black Holes and Horizon Adapted Coordinate Systems
Despite the fact that the Schwarzschild and Kerr solutions for the Einstein
equations, when written in standard Schwarzschild and Boyer-Lindquist
coordinates, present coordinate singularities, all numerical studies of
accretion flows onto collapsed objects have been widely using them over the
years. This approach introduces conceptual and practical complications in
places where a smooth solution should be guaranteed, i.e., at the gravitational
radius. In the present paper, we propose an alternative way of solving the
general relativistic hydrodynamic equations in background (fixed) black hole
spacetimes. We identify classes of coordinates in which the (possibly rotating)
black hole metric is free of coordinate singularities at the horizon,
independent of time, and admits a spacelike decomposition. In the spherically
symmetric, non-rotating case, we re-derive exact solutions for dust and perfect
fluid accretion in Eddington-Finkelstein coordinates, and compare with
numerical hydrodynamic integrations. We perform representative axisymmetric
computations. These demonstrations suggest that the use of those coordinate
systems carries significant improvements over the standard approach, especially
for higher dimensional studies.Comment: 10 pages, 4 postscript figures, accepted for publication in Phys.
Rev.
Numerical simulation of small perturbation on an accretion disk due to the collision of a star with the disk near the black hole
In this paper, perturbations of an accretion disk by a star orbiting around a
black hole are studied. We report on a numerical experiment, which has been
carried out by using a parallel-machine code originally developed by D\"{o}nmez
(2004). An initially steady state accretion disk near a non-rotating
(Schwarzschild) black hole interacts with a "star", modeled as an initially
circular region of increased density. Part of the disk is affected by the
interaction. In some cases, a gap develops and shock wave propagates through
the disk. We follow the evolution for order of one dynamical period and we show
how the non-axisymetric density perturbation further evolves and moves
downwards where the material of the disk and the star become eventually
accreted onto the central body.
When the star perturbs the steady state accretion disk, the disk around the
black hole is destroyed by the effect of perturbation. The perturbed accretion
disk creates a shock wave during the evolution and it loses angular momentum
when the gas hits on the shock waves. Colliding gas with the shock wave is the
one of the basic mechanism of emitting the rays in the accretion disk. The
series of supernovae occurring in the inner disk could entirely destroy the
disk in that region which leaves a more massive black hole behind, at the
center of galaxies.Comment: 20pages, 8 figures, accepted for publication in Astrophysics and
Space Scienc
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