6,931 research outputs found
Distributional fixed point equations for island nucleation in one dimension: a retrospective approach for capture zone scaling
The distributions of inter-island gaps and captures zones for islands
nucleated on a one-dimensional substrate during submonolayer deposition are
considered using a novel retrospective view. This provides an alternative
perspective on why scaling occurs in this continuously evolving system.
Distributional fixed point equations for the gaps are derived both with and
without a mean field approximation for nearest neighbour gap size correlation.
Solutions to the equations show that correct consideration of fragmentation
bias justifies the mean field approach which can be extended to provide
closed-from equations for the capture zones. Our results compare favourably to
Monte Carlo data for both point and extended islands using a range of critical
island size . We also find satisfactory agreement with theoretical
models based on more traditional fragmentation theory approaches.Comment: 9 pages, 7 figures and 1 tabl
The random phase approximation applied to ice
Standard density functionals without van der Waals interactions yield an
unsatisfactory description of ice phases, specifically, high density phases
occurring under pressure are too unstable compared to the common low density
phase I observed at ambient conditions. Although the description is
improved by using functionals that include van der Waals interactions, the
errors in relative volumes remain sizable. Here we assess the random phase
approximation (RPA) for the correlation energy and compare our results to
experimental data as well as diffusion Monte Carlo data for ice. The RPA yields
a very balanced description for all considered phases, approaching the accuracy
of diffusion Monte Carlo in relative energies and volumes. This opens a route
towards a concise description of molecular water phases on surfaces and in
cavities
Limit curve theorems in Lorentzian geometry
The subject of limit curve theorems in Lorentzian geometry is reviewed. A
general limit curve theorem is formulated which includes the case of converging
curves with endpoints and the case in which the limit points assigned since the
beginning are one, two or at most denumerable. Some applications are
considered. It is proved that in chronological spacetimes, strong causality is
either everywhere verified or everywhere violated on maximizing lightlike
segments with open domain. As a consequence, if in a chronological spacetime
two distinct lightlike lines intersect each other then strong causality holds
at their points. Finally, it is proved that two distinct components of the
chronology violating set have disjoint closures or there is a lightlike line
passing through each point of the intersection of the corresponding boundaries.Comment: 25 pages, 1 figure. v2: Misprints fixed, matches published versio
Wave-number Selection by Target Patterns and Side Walls in Rayleigh-Benard Convection
We present experimental results for Rayleigh-Benard convection patterns in a
cylindrical container with static side-wall forcing induced by a heater. This
forcing stabilized a pattern of concentric rolls (a target pattern) with the
central roll (the umbilicus) at the center of the cell after a jump from the
conduction to the convection state. A quasi-static increase of the control
parameter (epsilon) beyond 0.8 caused the umbilicus of the pattern to move off
center. As observed by others, a further quasi-static increase of epsilon up to
15.6 caused a sequence of transitions. Each transition began with the
displacement of the umbilicus and then proceeded with the loss of one
convection roll at the umbilicus and the return of the umbilicus to a location
near the center of the cell. Alternatively, with decreasing epsilon new rolls
formed at the umbilicus but large umbilicus displacements did not occur. In
addition to quantitative measurements of the umbilicus displacement, we
determined and analyzed the entire wave-director field of each image. The wave
numbers varied in the axial direction, with minima at the umbilicus and at the
cell wall and a maximum at a radial position close to 2/3 Gamma. The wave
numbers at the maximum showed hysteretic jumps at the transitions, but on
average agreed well with the theoretical predictions for the wave numbers
selected in the far field of an infinitely extended target pattern.Comment: ReVTeX, 11 pages, 16 eps figures include
Deriving genetic programming fitness properties by static analysis
Deriving Genetic Programming Fitness Properties by Static Analysis Colin G. Johnson The aim of this paper is to introduce the idea of using static analysis of computer programs as a way of measuring fitness in genetic programming. Such techniques extract information about the programs without explicitly running them, and in particular they infer properties which hold across the whole of the input space of a program. This can be applied to measure fitness, and has a number of advantages over measuring fitness by running members of the population on test cases. The most important advantage is that if a solution is found then it is possible to formally trust that solution to be correct across all inputs. This paper introduces these ideas, discusses various ways in which they could be applied, discusses the type of problems for which they are appropriate, and ends by giving a simple test example and some questions for future research
Integration of the Friedmann equation for universes of arbitrary complexity
An explicit and complete set of constants of the motion are constructed
algorithmically for Friedmann-Lema\^{i}tre-Robertson-Walker (FLRW) models
consisting of an arbitrary number of non-interacting species. The inheritance
of constants of the motion from simpler models as more species are added is
stressed. It is then argued that all FLRW models admit what amounts to a unique
candidate for a gravitational epoch function (a dimensionless scalar invariant
derivable from the Riemann tensor without differentiation which is monotone
throughout the evolution of the universe). The same relations that lead to the
construction of constants of the motion allow an explicit evaluation of this
function. In the simplest of all models, the CDM model, it is shown
that the epoch function exists for all models with , but for
almost no models with .Comment: Final form to appear in Physical Review D1
Synchrotron radiation study of the relation between structure and strain in polyurethane elastomers
This paper describes a system for the study of the relation between structure and applied strain in thermoplastic polyurethane elastomers using the Australian National Beamline Facility at the Photon Factory, KEK, Tsukuba, Japan. The system uses the sagittal focusing monochromator at beamline 20B to provide a high-intensity focused beam which then falls on the specimen mounted in a miniature tensometer mounted in the unique vacuum diffractometer (BIGDIFF). Imaging plates were used to record simultaneously SAXS and WAXS patterns from the specimen at a particular strain. The change in SAXS and WAXS patterns with loading and unloading was recorded using a ten-plate imaging-plate changer
Painleve-Gullstrand Coordinates for the Kerr Solution
We construct a coordinate system for the Kerr solution, based on the zero
angular momentum observers dropped from infinity, which generalizes the
Painleve-Gullstrand coordinate system for the Schwarzschild solution. The Kerr
metric can then be interpreted as describing space flowing on a (curved)
Riemannian 3-manifold. The stationary limit arises as the set of points on this
manifold where the speed of the flow equals the speed of light, and the
horizons as the set of points where the radial speed equals the speed of light.
A deeper analysis of what is meant by the flow of space reveals that the
acceleration of free-falling objects is generally not in the direction of this
flow. Finally, we compare the new coordinate system with the closely related
Doran coordinate system.Comment: 6 pages; v2: new section, matches final published version; v3: sign
error in the expression of the function delta correcte
Solution-Phase Synthesis of Heteroatom-Substituted Carbon Scaffolds for Hydrogen Storage
This paper reports a bottom-up solution-phase process for the preparation of pristine and heteroatom (boron, phosphorus, or nitrogen)-substituted carbon scaffolds that show good surface areas and enhanced hydrogen adsorption capacities and binding energies. The synthesis method involves heating chlorine-containing small organic molecules with metallic sodium at reflux in high-boiling solvents. For heteroatom incorporation, heteroatomic electrophiles are added to the reaction mixture. Under the reaction conditions, micrometer-sized graphitic sheets assembled by 3−5 nm-sized domains of graphene nanoflakes are formed, and when they are heteroatom-substituted, the heteroatoms are uniformly distributed. The substituted carbon scaffolds enriched with heteroatoms (boron ~7.3%, phosphorus ~8.1%, and nitrogen ~28.1%) had surface areas as high as 900 m^2 g^(−1) and enhanced reversible hydrogen physisorption capacities relative to pristine carbon scaffolds or common carbonaceous materials. In addition, the binding energies of the substituted carbon scaffolds, as measured by adsorption isotherms, were 8.6, 8.3, and 5.6 kJ mol^(−1) for the boron-, phosphorus-, and nitrogen-enriched carbon scaffolds, respectively
Demography and disorders of the French Bulldog population under primary veterinary care in the UK in 2013
Abstract Background Despite its Gallic name, the French Bulldog is a breed of both British and French origin that was first recognised by The Kennel Club in 1906. The French Bulldog has demonstrated recent rapid rises in Kennel Club registrations and is now (2017) the second most commonly registered pedigree breed in the UK. However, the breed has been reported to be predisposed to several disorders including ocular, respiratory, neurological and dermatological problems. The VetCompass™ Programme collates de-identified clinical data from primary-care veterinary practices in the UK for epidemiological research. Using VetCompass™ clinical data, this study aimed to characterise the demography and common disorders of the general population of French Bulldogs under veterinary care in the UK. Results French Bulldogs comprised 2228 (0.49%) of 445,557 study dogs under veterinary care during 2013. Annual proportional birth rates showed that the proportional ownership of French Bulldog puppies rose steeply from 0.02% of the annual birth cohort attending VetCompass™ practices in 2003 to 1.46% in 2013. The median age of the French Bulldogs overall was 1.3 years (IQR 0.6–2.5, range 0.0–13.0). The most common colours of French Bulldogs were brindle (solid or main) (32.36%) and fawn (solid or main) (29.9%). Of the 2228 French Bulldogs under veterinary care during 2013, 1612 (72.4%) had at least one disorder recorded. The most prevalent fine-level precision disorders recorded were otitis externa (14.0%, 95% CI: 12.6–15.5), diarrhoea (7.5%, 95% CI: 6.4–8.7), conjunctivitis (3.2%, 95% CI: 2.5–4.0), nails overlong (3.1%, 95% CI% 2.4–3.9) and skin fold dermatitis (3.0%, 95% CI% 2.3–3.8). The most prevalent disorder groups were cutaneous (17.9%, 95% CI: 16.3–19.6), enteropathy (16.7%, 95% CI: 15.2–18.3), aural (16.3%, 95% CI: 14.8–17.9), upper respiratory tract (12.7%, 95% CI: 11.3–14.1) and ophthalmological (10.5%, 95% CI: 9.3–11.9). Conclusions Ownership of French Bulldogs in the UK is rising steeply. This means that the disorder profiles reported in this study reflect a current young UK population and are likely to shift as this cohort ages. Otitis externa, diarrhoea and conjunctivitis were the most common disorders in French Bulldogs. Identification of health priorities based on VetCompass™ data can support evidence–based reforms to improve health and welfare within the breed
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