13,747 research outputs found
Polymeric filament thinning and breakup in microchannels
The effects of elasticity on filament thinning and breakup are investigated
in microchannel cross flow. When a viscous solution is stretched by an external
immiscible fluid, a low 100 ppm polymer concentration strongly affects the
breakup process, compared to the Newtonian case. Qualitatively, polymeric
filaments show much slower evolution, and their morphology features multiple
connected drops. Measurements of filament thickness show two main temporal
regimes: flow- and capillary-driven. At early times both polymeric and
Newtonian fluids are flow-driven, and filament thinning is exponential. At
later times, Newtonian filament thinning crosses over to a capillary-driven
regime, in which the decay is algebraic. By contrast, the polymeric fluid first
crosses over to a second type of flow-driven behavior, in which viscoelastic
stresses inside the filament become important and the decay is again
exponential. Finally, the polymeric filament becomes capillary-driven at late
times with algebraic decay. We show that the exponential flow thinning behavior
allows a novel measurement of the extensional viscosities of both Newtonian and
polymeric fluids.Comment: 7 pages, 7 figure
Electron Dynamics in a Coupled Quantum Point Contact Structure with a Local Magnetic Moment
We develop a theoretical model for the description of electron dynamics in
coupled quantum wires when the local magnetic moment is formed in one of the
wires. We employ a single-particle Hamiltonian that takes account of the
specific geometry of potentials defining the structure as well as electron
scattering on the local magnetic moment. The equations for the wave functions
in both wires are derived and the approach for their solution is discussed. We
determine the transmission coefficient and conductance of the wire having the
local magnetic moment and show that our description reproduces the
experimentally observed features.Comment: Based on work presented at 2004 IEEE NTC Quantum Device Technology
Worksho
Dynamics of short polymer chains in solution
We present numerical and analytical results describing the effect of
hydrodynamic interactions on the dynamics of a short polymer chain in solution.
A molecular dynamics algorithm for the polymer is coupled to a direct
simulation Monte Carlo algorithm for the solvent. We give an explicit
expression for the velocity autocorrelation function of the centre of mass of
the polymer which agrees well with numerical results if Brownian dynamics,
hydrodynamic correlations and sound wave scattering are included
Thermodiffusion in model nanofluids by molecular dynamics simulations
In this work, a new algorithm is proposed to compute single particle
(infinite dilution) thermodiffusion using Non-Equilibrium Molecular Dynamics
simulations through the estimation of the thermophoretic force that applies on
a solute particle. This scheme is shown to provide consistent results for
simple Lennard-Jones fluids and for model nanofluids (spherical non-metallic
nanoparticles + Lennard-Jones fluid) where it appears that thermodiffusion
amplitude, as well as thermal conductivity, decrease with nanoparticles
concentration. Then, in nanofluids in the liquid state, by changing the nature
of the nanoparticle (size, mass and internal stiffness) and of the solvent
(quality and viscosity) various trends are exhibited. In all cases the single
particle thermodiffusion is positive, i.e. the nanoparticle tends to migrate
toward the cold area. The single particle thermal diffusion 2 coefficient is
shown to be independent of the size of the nanoparticle (diameter of 0.8 to 4
nm), whereas it increases with the quality of the solvent and is inversely
proportional to the viscosity of the fluid. In addition, this coefficient is
shown to be independent of the mass of the nanoparticle and to increase with
the stiffness of the nanoparticle internal bonds. Besides, for these
configurations, the mass diffusion coefficient behavior appears to be
consistent with a Stokes-Einstein like law
Angular velocity distribution of a granular planar rotator in a thermalized bath
The kinetics of a granular planar rotator with a fixed center undergoing
inelastic collisions with bath particles is analyzed both numerically and
analytically by means of the Boltzmann equation. The angular velocity
distribution evolves from quasi-gaussian in the Brownian limit to an algebraic
decay in the limit of an infinitely light particle. In addition, we compare
this model with a planar rotator with a free center. We propose experimental
tests that might confirm the predicted behaviors.Comment: 10 Pages, 9 Figure
Gaussian approximation for finitely extensible bead-spring chains with hydrodynamic interaction
The Gaussian Approximation, proposed originally by Ottinger [J. Chem. Phys.,
90 (1) : 463-473, 1989] to account for the influence of fluctuations in
hydrodynamic interactions in Rouse chains, is adapted here to derive a new
mean-field approximation for the FENE spring force. This "FENE-PG" force law
approximately accounts for spring-force fluctuations, which are neglected in
the widely used FENE-P approximation. The Gaussian Approximation for
hydrodynamic interactions is combined with the FENE-P and FENE-PG spring force
approximations to obtain approximate models for finitely-extensible bead-spring
chains with hydrodynamic interactions. The closed set of ODE's governing the
evolution of the second-moments of the configurational probability distribution
in the approximate models are used to generate predictions of rheological
properties in steady and unsteady shear and uniaxial extensional flows, which
are found to be in good agreement with the exact results obtained with Brownian
dynamics simulations. In particular, predictions of coil-stretch hysteresis are
in quantitative agreement with simulations' results. Additional simplifying
diagonalization-of-normal-modes assumptions are found to lead to considerable
savings in computation time, without significant loss in accuracy.Comment: 26 pages, 17 figures, 2 tables, 75 numbered equations, 1 appendix
with 10 numbered equations Submitted to J. Chem. Phys. on 6 February 200
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