Adsorbent filled membranes for gas separation. Part 1. Improvement of the gas separation properties of polymeric membranes by incorporation of microporous adsorbents

The effect of the introduction of specific adsorbents on the gas separation properties of polymeric membranes has been studied. For this purpose both carbon molecular sieves and zeolites are considered. The results show that zeolites such as silicate-1, 13X and KY improve to a large extent the separation properties of poorly selective rubbery polymers towards a mixture of carbon dioxide/methane. Some of the filled rubbery polymers achieve intrinsic separation properties comparable to cellulose acetate, polysulfone or polyethersulfone. However, zeolite 5A leads to a decrease in permeability and an unchanged selectivity. This is due to the impermeable character of these particles, i.e. carbon dioxide molecules cannot diffuse through the porous structure under the conditions applied. Using silicate-1 also results in an improvement of the oxygen/nitrogen separation properties which is mainly due to a kinetic effect. Carbon molecular sieves do not improve the separation performances or only to a very small extent. This is caused by a mainly dead-end (not interconnected) porous structure which is inherent to their manufacturing process

Cellular spanning trees and Laplacians of cubical complexes

We prove a Matrix-Tree Theorem enumerating the spanning trees of a cell complex in terms of the eigenvalues of its cellular Laplacian operators, generalizing a previous result for simplicial complexes. As an application, we obtain explicit formulas for spanning tree enumerators and Laplacian eigenvalues of cubes; the latter are integers. We prove a weighted version of the eigenvalue formula, providing evidence for a conjecture on weighted enumeration of cubical spanning trees. We introduce a cubical analogue of shiftedness, and obtain a recursive formula for the Laplacian eigenvalues of shifted cubical complexes, in particular, these eigenvalues are also integers. Finally, we recover Adin's enumeration of spanning trees of a complete colorful simplicial complex from the cellular Matrix-Tree Theorem together with a result of Kook, Reiner and Stanton.Comment: 24 pages, revised version, to appear in Advances in Applied Mathematic

Simplicial matrix-tree theorems

We generalize the definition and enumeration of spanning trees from the setting of graphs to that of arbitrary-dimensional simplicial complexes $\Delta$, extending an idea due to G. Kalai. We prove a simplicial version of the Matrix-Tree Theorem that counts simplicial spanning trees, weighted by the squares of the orders of their top-dimensional integral homology groups, in terms of the Laplacian matrix of $\Delta$. As in the graphic case, one can obtain a more finely weighted generating function for simplicial spanning trees by assigning an indeterminate to each vertex of $\Delta$ and replacing the entries of the Laplacian with Laurent monomials. When $\Delta$ is a shifted complex, we give a combinatorial interpretation of the eigenvalues of its weighted Laplacian and prove that they determine its set of faces uniquely, generalizing known results about threshold graphs and unweighted Laplacian eigenvalues of shifted complexes.Comment: 36 pages, 2 figures. Final version, to appear in Trans. Amer. Math. So

Simplicial and Cellular Trees

Much information about a graph can be obtained by studying its spanning trees. On the other hand, a graph can be regarded as a 1-dimensional cell complex, raising the question of developing a theory of trees in higher dimension. As observed first by Bolker, Kalai and Adin, and more recently by numerous authors, the fundamental topological properties of a tree --- namely acyclicity and connectedness --- can be generalized to arbitrary dimension as the vanishing of certain cellular homology groups. This point of view is consistent with the matroid-theoretic approach to graphs, and yields higher-dimensional analogues of classical enumerative results including Cayley's formula and the matrix-tree theorem. A subtlety of the higher-dimensional case is that enumeration must account for the possibility of torsion homology in trees, which is always trivial for graphs. Cellular trees are the starting point for further high-dimensional extensions of concepts from algebraic graph theory including the critical group, cut and flow spaces, and discrete dynamical systems such as the abelian sandpile model.Comment: 39 pages (including 5-page bibliography); 5 figures. Chapter for forthcoming IMA volume "Recent Trends in Combinatorics

Preparation of zeolite filled glassy polymer membranes

The incorporation of zeolite particles in the micrometer range into polymeric matrices was investigated as a way to improve the gas separation properties of the polymer materials used in the form of membranes. The adhesion between the polymer phase and the external surface of the particles appeared to be a major problem in the preparation of such membranes when the polymer is in the glassy state at room temperature. Various methods were investigated to improve the internal membrane structure, that is, surface modification of the zeolite external surface, preparation above the glass-transition temperature, and heat treatment. Improved structures were obtained as observed by scanning electron microscopy, but the influence on the gas separation properties was not in agreement with the observed structural improvements

Resonant Raman Scattering by quadrupolar vibrations of Ni-Ag Core-shell Nanoparticles

Low-frequency Raman scattering experiments have been performed on thin films consisting of nickel-silver composite nanoparticles embedded in alumina matrix. It is observed that the Raman scattering by the quadrupolar modes, strongly enhanced when the light excitation is resonant with the surface dipolar excitation, is mainly governed by the silver electron contribution to the plasmon excitation. The Raman results are in agreement with a core-shell structure of the nanoparticles, the silver shell being loosely bonded to the nickel core.Comment: 3 figures. To be published in Phys. Rev.

Quantum integrability of quadratic Killing tensors

Quantum integrability of classical integrable systems given by quadratic Killing tensors on curved configuration spaces is investigated. It is proven that, using a "minimal" quantization scheme, quantum integrability is insured for a large class of classic examples.Comment: LaTeX 2e, no figure, 35 p., references added, minor modifications. To appear in the J. Math. Phy

The location, clustering, and propagation of massive star formation in giant molecular clouds

Massive stars are key players in the evolution of galaxies, yet their formation pathway remains unclear. In this work, we use data from several galaxy-wide surveys to build an unbiased dataset of ~700 massive young stellar objects (MYSOs), ~200 giant molecular clouds (GMCs), and ~100 young (<10 Myr) optical stellar clusters (SCs) in the Large Magellanic Cloud. We employ this data to quantitatively study the location and clustering of massive star formation and its relation to the internal structure of GMCs. We reveal that massive stars do not typically form at the highest column densities nor centers of their parent GMCs at the ~6 pc resolution of our observations. Massive star formation clusters over multiple generations and on size scales much smaller than the size of the parent GMC. We find that massive star formation is significantly boosted in clouds near SCs. Yet, whether a cloud is associated with a SC does not depend on either the cloud's mass or global surface density. These results reveal a connection between different generations of massive stars on timescales up to 10 Myr. We compare our work with Galactic studies and discuss our findings in terms of GMC collapse, triggered star formation, and a potential dichotomy between low- and high-mass star formation.Comment: 13 pages, 7 figures, in pres

A non-partitionable Cohen-Macaulay simplicial complex

A long-standing conjecture of Stanley states that every Cohen-Macaulay simplicial complex is partitionable. We disprove the conjecture by constructing an explicit counterexample. Due to a result of Herzog, Jahan and Yassemi, our construction also disproves the conjecture that the Stanley depth of a monomial ideal is always at least its depth.Comment: Final version. 13 pages, 2 figure