The influence of the preparation method of NiOx photocathodes on the efficiency of p-type dye-sensitised solar cells

Improving the efficiency of p-type dye-sensitized solar cells (DSCs) is an important part of the development of high performance tandem DSCs. The optimization of the conversion efficiency of p-DSCs could make a considerable contribution in the improvement of solar cells at a molecular level. Nickel oxide is the most widely used material in p-DSCs, due to its ease of preparation, chemical and structural stability, and electrical properties. However, improvement of the quality and conductivity of NiO based photocathodes needs to be achieved to bring further improvements to the solar cell efficiency. The subject of this review is to consider the effect of the preparation of NiO surfaces on their efficiency as photocathodes. (C) 2015 Elsevier B.V. All rights reserved

Quantized Scaling of Growing Surfaces

The Kardar-Parisi-Zhang universality class of stochastic surface growth is studied by exact field-theoretic methods. From previous numerical results, a few qualitative assumptions are inferred. In particular, height correlations should satisfy an operator product expansion and, unlike the correlations in a turbulent fluid, exhibit no multiscaling. These properties impose a quantization condition on the roughness exponent $\chi$ and the dynamic exponent $z$. Hence the exact values $\chi = 2/5, z = 8/5$ for two-dimensional and $\chi = 2/7, z = 12/7$ for three-dimensional surfaces are derived.Comment: 4 pages, revtex, no figure

An Exactly Solved Model of Three Dimensional Surface Growth in the Anisotropic KPZ Regime

We generalize the surface growth model of Gates and Westcott to arbitrary inclination. The exact steady growth velocity is of saddle type with principal curvatures of opposite sign. According to Wolf this implies logarithmic height correlations, which we prove by mapping the steady state of the surface to world lines of free fermions with chiral boundary conditions.Comment: 9 pages, REVTEX, epsf, 3 postscript figures, submitted to J. Stat. Phys, a wrong character is corrected in eqs. (31) and (32

Teaching reading through imaginative play situations in grades one and two

Thesis (Ed.M.)--Boston Universit

Interface roughening with nonlinear surface tension

Using stability arguments, this Brief Report suggests that a term that enhances the surface tension in the presence of large height fluctuations should be included in the Kardar-Parisi-Zhang equation. A one-loop renormalization group analysis then shows for interface dimensions larger than $\simeq 3.3$ an unstable strong-coupling fixed point that enters the system from infinity. The relevance of these results to the roughening transition is discussed.Comment: 4 pages RevTeX, 1 figur

Upper critical dimension, dynamic exponent and scaling functions in the mode-coupling theory for the Kardar-Parisi-Zhang equation

We study the mode-coupling approximation for the KPZ equation in the strong coupling regime. By constructing an ansatz consistent with the asymptotic forms of the correlation and response functions we determine the upper critical dimension d_c=4, and the expansion z=2-(d-4)/4+O((4-d)^2) around d_c. We find the exact z=3/2 value in d=1, and estimate the values 1.62, 1.78 for z, in d=2,3. The result d_c=4 and the expansion around d_c are very robust and can be derived just from a mild assumption on the relative scale on which the response and correlation functions vary as z approaches 2.Comment: RevTex, 4 page

Probability distribution of the free energy of a directed polymer in a random medium

We calculate exactly the first cumulants of the free energy of a directed polymer in a random medium for the geometry of a cylinder. By using the fact that the n-th moment of the partition function is given by the ground state energy of a quantum problem of n interacting particles on a ring of length L, we write an integral equation allowing to expand these moments in powers of the strength of the disorder gamma or in powers of n. For n small and n of order (L gamma)^(-1/2), the moments take a scaling form which allows to describe all the fluctuations of order 1/L of the free energy per unit length of the directed polymer. The distribution of these fluctuations is the same as the one found recently in the asymmetric exclusion process, indicating that it is characteristic of all the systems described by the Kardar-Parisi-Zhang equation in 1+1 dimensions.Comment: 18 pages, no figure, tu appear in PRE 61 (2000

Directed polymers and interfaces in random media : free-energy optimization via confinement in a wandering tube

We analyze, via Imry-Ma scaling arguments, the strong disorder phases that exist in low dimensions at all temperatures for directed polymers and interfaces in random media. For the uncorrelated Gaussian disorder, we obtain that the optimal strategy for the polymer in dimension $1+d$ with $0<d<2$ involves at the same time (i) a confinement in a favorable tube of radius $R_S \sim L^{\nu_S}$ with $\nu_S=1/(4-d)<1/2$ (ii) a superdiffusive behavior $R \sim L^{\nu}$ with $\nu=(3-d)/(4-d)>1/2$ for the wandering of the best favorable tube available. The corresponding free-energy then scales as $F \sim L^{\omega}$ with $\omega=2 \nu-1$ and the left tail of the probability distribution involves a stretched exponential of exponent $\eta= (4-d)/2$. These results generalize the well known exact exponents $\nu=2/3$, $\omega=1/3$ and $\eta=3/2$ in $d=1$, where the subleading transverse length $R_S \sim L^{1/3}$ is known as the typical distance between two replicas in the Bethe Ansatz wave function. We then extend our approach to correlated disorder in transverse directions with exponent $\alpha$ and/or to manifolds in dimension $D+d=d_{t}$ with $0<D<2$. The strategy of being both confined and superdiffusive is still optimal for decaying correlations ($\alpha<0$), whereas it is not for growing correlations ($\alpha>0$). In particular, for an interface of dimension $(d_t-1)$ in a space of total dimension $5/3<d_t<3$ with random-bond disorder, our approach yields the confinement exponent $\nu_S = (d_t-1)(3-d_t)/(5d_t-7)$. Finally, we study the exponents in the presence of an algebraic tail $1/V^{1+\mu}$ in the disorder distribution, and obtain various regimes in the $(\mu,d)$ plane.Comment: 19 page

A numerical study of the development of bulk scale-free structures upon growth of self-affine aggregates

During the last decade, self-affine geometrical properties of many growing aggregates, originated in a wide variety of processes, have been well characterized. However, little progress has been achieved in the search of a unified description of the underlying dynamics. Extensive numerical evidence has been given showing that the bulk of aggregates formed upon ballistic aggregation and random deposition with surface relaxation processes can be broken down into a set of infinite scale invariant structures called "trees". These two types of aggregates have been selected because it has been established that they belong to different universality classes: those of Kardar-Parisi-Zhang and Edward-Wilkinson, respectively. Exponents describing the spatial and temporal scale invariance of the trees can be related to the classical exponents describing the self-affine nature of the growing interface. Furthermore, those exponents allows us to distinguish either the compact or non-compact nature of the growing trees. Therefore, the measurement of the statistic of the process of growing trees may become a useful experimental technique for the evaluation of the self-affine properties of some aggregates.Comment: 19 pages, 5 figures, accepted for publication in Phys.Rev.