636 research outputs found
Van der Waals effects on grazing incidence fast atom diffraction for H/LiF(001)
We theoretically address grazing incidence fast atom diffraction (GIFAD) for
H atoms impinging on a LiF(001) surface. Our model combines a description of
the H-LiF(001) interaction obtained from Density Functional Theory calculations
with a semi-quantum treatment of the dynamics. We analyze simulated diffraction
patterns in terms of the incidence channel, the impact energy associated with
the motion normal to the surface, and the relevance of Van der Waals (VdW)
interactions. We then contrast our simulations with experimental patterns for
different incidence conditions. Our most important finding is that, for normal
energies lower than 0.5 eV and incidence along the channel, the inclusion
of Van der Waals interactions in our potential energy surface yields a greatly
improved accord between simulations and experiments. This agreement strongly
suggests a non-negligible role of Van der Waals interactions in H/LiF(001)
GIFAD in the low-to-intermediate normal energy regime
The two gap transitions in GeSn: effect of non-substitutional complex defects
The existence of non-substitutional -Sn defects in GeSn
was confirmed by emission channeling experiments [Decoster et al., Phys. Rev. B
81, 155204 (2010)], which established that although most Sn enters
substitutionally (-Sn) in the Ge lattice, a second significant fraction
corresponds to the Sn-vacancy defect complex in the split-vacancy configuration
( -Sn ), in agreement with our previous theoretical study [Ventura et
al., Phys. Rev. B 79, 155202 (2009)]. Here, we present our electronic structure
calculation for GeSn, including substitutional -Sn as
well as non-substitutional -Sn defects. To include the presence of
non-substitutional complex defects in the electronic structure calculation for
this multi-orbital alloy problem, we extended the approach for the purely
substitutional alloy by Jenkins and Dow [Jenkins and Dow, Phys. Rev. B 36, 7994
(1987)]. We employed an effective substitutional two-site cluster equivalent to
the real non-substitutional -Sn defect, which was determined by a
Green's functions calculation. We then calculated the electronic structure of
the effective alloy purely in terms of substitutional defects, embedding the
effective substitutional clusters in the lattice. Our results describe the two
transitions of the fundamental gap of GeSn as a function of the
total Sn-concentration: namely from an indirect to a direct gap, first, and the
metallization transition at higher . They also highlight the role of
-Sn in the reduction of the concentration range which corresponds to the
direct-gap phase of this alloy, of interest for optoelectronics applications.Comment: 11 pages, 9 Figure
Non-substitutional single-atom defects in the Ge_(1-x)Sn_x alloy
Ge_(1-x)Sn_x alloys have proved difficult to form at large x, contrary to
what happens with other group IV semiconductor combinations. However, at low x
they are typical examples of well-behaved substitutional compounds, which is
desirable for harnessing the electronic properties of narrow band
semiconductors. In this paper, we propose the appearance of another kind of
single-site defect (), consisting of a single Sn atom in the center
of a Ge divacancy, that may account for these facts. Accordingly, we examine
the electronic and structural properties of these alloys by performing
extensive numerical ab-initio calculations around local defects. The results
show that the environment of the defect relaxes towards a cubic
octahedral configuration, facilitating the nucleation of metallic white tin and
its segregation, as found in amorphous samples. Using the information stemming
from these local defect calculations, we built a simple statistical model to
investigate at which concentration these defects can be formed in
thermal equilibrium. These results agree remarkably well with experimental
findings, concerning the critical concentration above which the homogeneous
alloys cannot be formed at room temperature. Our model also predicts the
observed fact that at lower temperature the critical concentration increases.
We also performed single site effective-field calculations of the electronic
structure, which further support our hypothesis.Comment: 12 pages, 1 table, 16 figure
The effect of Coulomb interaction at ferromagnetic-paramagnetic metallic perovskite junctions
We study the effect of Coulomb interactions in transition metal oxides
junctions. In this paper we analyze charge transfer at the interface of a three
layer ferromagnetic-paramagnetic-ferromagnetic metallic oxide system. We choose
a charge model considering a few atomic planes within each layer and obtain
results for the magnetic coupling between the ferromagnetic layers. For large
number of planes in the paramagnetic spacer we find that the coupling
oscillates with the same period as in RKKY but the amplitude is sensitive to
the Coulomb energy. At small spacer thickness however, large differences may
appear as function of : the number of electrons per atom in the ferromagnetics
and paramagnetics materials, the dielectric constant at each component, and the
charge defects at the interface plane emphasizing the effects of charge
transfer.Comment: tex file and 7 figure
First-Principles Approach to Electrorotation Assay
We have presented a theoretical study of electrorotation assay based on the
spectral representation theory. We consider unshelled and shelled spheroidal
particles as an extension to spherical ones. From the theoretical analysis, we
find that the coating can change the characteristic frequency at which the
maximum rotational angular velocity occurs. The shift in the characteristic
frequency is attributed to a change in the dielectric properties of the
bead-coating complex with respect to those of the uncoated particles. By
adjusting the dielectric properties and the thickness of the coating, it is
possible to obtain good agreement between our theoretical predictions and the
assay data.Comment: 17 pages, 4 eps figures; minor revisions, accepted for publications
by J. Phys.: Condens. Matte
Electrorotation of a pair of spherical particles
We present a theoretical study of electrorotation (ER) of two spherical
particles under the action of a rotating electric field. When the two particles
approach and finally touch, the mutual polarization interaction between the
particles leads to a change in the dipole moment of the individual particle and
hence the ER spectrum, as compared to that of the well-separated particles. The
mutual polarization effects are captured by the method of multiple images. From
the theoretical analysis, we find that the mutual polarization effects can
change the characteristic frequency at which the maximum angular velocity of
electrorotation occurs. The numerical results can be understood in the spectral
representation theory.Comment: Minor revisions; accepted by Phys. Rev.
A Compromise between Neutrino Masses and Collider Signatures in the Type-II Seesaw Model
A natural extension of the standard gauge
model to accommodate massive neutrinos is to introduce one Higgs triplet and
three right-handed Majorana neutrinos, leading to a neutrino mass
matrix which contains three sub-matrices ,
and . We show that three light Majorana neutrinos (i.e., the mass
eigenstates of , and ) are exactly massless in this
model, if and only if
exactly holds. This no-go theorem implies that small but non-vanishing neutrino
masses may result from a significant but incomplete cancellation between
and terms in the Type-II
seesaw formula, provided three right-handed Majorana neutrinos are of TeV and experimentally detectable at the LHC. We propose three simple
Type-II seesaw scenarios with the flavor symmetry to
interpret the observed neutrino mass spectrum and neutrino mixing pattern. Such
a TeV-scale neutrino model can be tested in two complementary ways: (1)
searching for possible collider signatures of lepton number violation induced
by the right-handed Majorana neutrinos and doubly-charged Higgs particles; and
(2) searching for possible consequences of unitarity violation of the neutrino mixing matrix in the future long-baseline neutrino oscillation
experiments.Comment: RevTeX 19 pages, no figure
Measuring refugees’ capabilities: translation, adaptation, and valuation of the OxCAP-MH into Juba Arabic for use among South Sudanese male refugees in Uganda
Background: Forcibly displaced populations are highly vulnerable to psychosocial distress and mental disorders, including alcohol misuse. In an ongoing trial that seeks to develop a transdiagnostic intervention addressing psychological distress and alcohol use disorders among conflict-affected populations, we will carry out a cost-effectiveness evaluation using a capability-based Oxford Capabilities Mental Health (OxCAP-MH) measure. The OxCAP-MH is a 16-item questionnaire developed from the Capability Approach, that covers multiple domains of functioning and welfare. The aim of the current paper is to present the results of the translation, cultural adaptation and valuation of the OxCAP-MH into Juba Arabic for South Sudanese refugees living in Uganda. We adhered to the official Translation and Linguistic Validation process of the OxCAP-MH. To carry out the translation, the Concept Elaboration document, official English version of the OxCAP-MH, and the Back-Translation Review Template were used. Four independent translators were used for forward and back translations. The reconciled translated version was then piloted in two focus group discussions (N = 16) in Rhino refugee settlement. A most important to least important valuation of the sixteen capability domains covered in the OxCAP-MH was also done. Results: The Juba Arabic version of the OxCAP-MH was finalized following a systematic iterative process. The content of the Juba Arabic version remained unchanged, but key concepts were adapted to ensure cultural acceptability, feasibility, and comprehension of the measure in the local context of Rhino refugee settlement. Most participants had low levels of literacy and required support with filling in the tool. Participants suggested an additional capability that is currently not reflected in the OxCAP-MH, namely access to food. Furthermore, discussions around the valuation exercise of the sixteen domains led to two separate importance scales, which showed relevant differences. Conclusions: In this context, the OxCAP-MH was considered culturally acceptable. The valuation exercise proved cognitively demanding. Participants voiced confusion over how to answer the questions on the OxCAP-MH instrument due to low levels of literacy. These concerns invite consideration for future research to consider how measures such as the OxCAP-MH can be made more accessible to individuals with low literacy rates in resource poor settings
Comments on alternative calculations of the broadening of spectral lines of neutral sodium by H-atom collisions
With the exception of the sodium D-lines recent calculations of line
broadening cross-sections for several multiplets of sodium by Leininger et al
(2000) are in substantial disagreement with cross-sections interpolated from
the tables of Anstee and O'Mara (1995) and Barklem and O'Mara (1997). The
discrepancy is as large as a factor of three for the 3p-4d multiplet. The two
theories are tested by using the results of each to synthesize lines in the
solar spectrum. It is found that generally the data from the theory of Anstee,
Barklem and O'Mara produce the best match to the observed solar spectrum. It is
found, using a simple model for reflection of the optical electron by the
potential barrier between the two atoms, that the reflection coefficient is too
large for avoided crossings with the upper states of subordinate lines to
contribute to line broadening, supporting the neglect of avoided ionic
crossings by Anstee, Barklem and O'Mara for these lines. The large
discrepancies between the two sets of calculations is a result of an
approximate treatment of avoided ionic crossings for these lines by Leininger
et al (2000).Comment: 18 pages, 5 ps figures included, to appear in J Phys B: At. Mol. Opt.
Phy
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