How chip size impacts steam pretreatment effectiveness for biological conversion of poplar wood into fermentable sugars

Background Woody biomass is highly recalcitrant to enzymatic sugar release and often requires significant size reduction and severe pretreatments to achieve economically viable sugar yields in biological production of sustainable fuels and chemicals. However, because mechanical size reduction of woody biomass can consume significant amounts of energy, it is desirable to minimize size reduction and instead pretreat larger wood chips prior to biological conversion. To date, however, most laboratory research has been performed on materials that are significantly smaller than applicable in a commercial setting. As a result, there is a limited understanding of the effects that larger biomass particle size has on the effectiveness of steam explosion pretreatment and subsequent enzymatic hydrolysis of wood chips. Results To address these concerns, novel downscaled analysis and high throughput pretreatment and hydrolysis (HTPH) were applied to examine whether differences exist in the composition and digestibility within a single pretreated wood chip due to heterogeneous pretreatment across its thickness. Heat transfer modeling, Simons’ stain testing, magnetic resonance imaging (MRI), and scanning electron microscopy (SEM) were applied to probe the effects of pretreatment within and between pretreated wood samples to shed light on potential causes of variation, pointing to enzyme accessibility (i.e., pore size) distribution being a key factor dictating enzyme digestibility in these samples. Application of these techniques demonstrated that the effectiveness of pretreatment of Populus tremuloides can vary substantially over the chip thickness at short pretreatment times, resulting in spatial digestibility effects and overall lower sugar yields in subsequent enzymatic hydrolysis. Conclusions These results indicate that rapid decompression pretreatments (e.g., steam explosion) that specifically alter accessibility at lower temperature conditions are well suited for larger wood chips due to the non-uniformity in temperature and digestibility profiles that can result from high temperature and short pretreatment times. Furthermore, this study also demonstrated that wood chips were hydrated primarily through the natural pore structure during pretreatment, suggesting that preserving the natural grain and transport systems in wood during storage and chipping processes could likely promote pretreatment efficacy and uniformity

Universal quantum Controlled-NOT gate

An investigation of an optimal universal unitary Controlled-NOT gate that performs a specific operation on two unknown states of qubits taken from a great circle of the Bloch sphere is presented. The deep analogy between the optimal universal C-NOT gate and the `equatorial' quantum cloning machine (QCM) is shown. In addition, possible applications of the universal C-NOT gate are briefly discussed.Comment: 18 reference

Demonstration of Feed-Forward Control for Linear Optics Quantum Computation

One of the main requirements in linear optics quantum computing is the ability to perform single-qubit operations that are controlled by classical information fed forward from the output of single photon detectors. These operations correspond to pre-determined combinations of phase corrections and bit-flips that are applied to the post-selected output modes of non-deterministic quantum logic devices. Corrections of this kind are required in order to obtain the correct logical output for certain detection events, and their use can increase the overall success probability of the devices. In this paper, we report on the experimental demonstration of the use of this type of feed-forward system to increase the probability of success of a simple non-deterministic quantum logic operation from approximately 1/4 to 1/2. This logic operation involves the use of one target qubit and one ancilla qubit which, in this experiment, are derived from a parametric down-conversion photon pair. Classical information describing the detection of the ancilla photon is fed-forward in real-time and used to alter the quantum state of the output photon. A fiber optic delay line is used to store the output photon until a polarization-dependent phase shift can be applied using a high speed Pockels cell

Stimulated emission of polarization-entangled photons

Entangled photon pairs -- discrete light quanta that exhibit non-classical correlations -- play a crucial role in quantum information science (for example in demonstrations of quantum non-locality and quantum cryptography). At the macroscopic optical field level non-classical correlations can also be important, as in the case of squeezed light, entangled light beams and teleportation of continuous quantum variables. Here we use stimulated parametric down-conversion to study entangled states of light that bridge the gap between discrete and macroscopic optical quantum correlations. We demonstrate experimentally the onset of laser-like action for entangled photons. This entanglement structure holds great promise in quantum information science where there is a strong demand for entangled states of increasing complexity.Comment: 5 pages, 4 figures, RevTeX

Probabilistic Quantum Logic Operations Using Polarizing Beam Splitters

It has previously been shown that probabilistic quantum logic operations can be performed using linear optical elements, additional photons (ancilla), and post-selection based on the output of single-photon detectors. Here we describe the operation of several quantum logic operations of an elementary nature, including a quantum parity check and a quantum encoder, and we show how they can be combined to implement a controlled-NOT (CNOT) gate. All of these gates can be constructed using polarizing beam splitters that completely transmit one state of polarization and totally reflect the orthogonal state of polarization, which allows a simple explanation of each operation. We also describe a polarizing beam splitter implementation of a CNOT gate that is closely analogous to the quantum teleportation technique previously suggested by Gottesman and Chuang [Nature 402, p.390 (1999)]. Finally, our approach has the interesting feature that it makes practical use of a quantum-eraser technique.Comment: 9 pages, RevTex; Submitted to Phys. Rev. A; additional references inlcude

Single Photons on Pseudo-Demand from Stored Parametric Down-Conversion

We describe the results of a parametric down-conversion experiment in which the detection of one photon of a pair causes the other photon to be switched into a storage loop. The stored photon can then be switched out of the loop at a later time chosen by the user, providing a single photon for potential use in a variety of quantum information processing applications. Although the stored single photon is only available at periodic time intervals, those times can be chosen to match the cycle time of a quantum computer by using pulsed down-conversion. The potential use of the storage loop as a photonic quantum memory device is also discussed.Comment: 8 pages, 7 Figs., RevTe

Probing the quantum vacuum with an artificial atom in front of a mirror

Quantum fluctuations of the vacuum are both a surprising and fundamental phenomenon of nature. Understood as virtual photons flitting in and out of existence, they still have a very real impact, \emph{e.g.}, in the Casimir effects and the lifetimes of atoms. Engineering vacuum fluctuations is therefore becoming increasingly important to emerging technologies. Here, we shape vacuum fluctuations using a "mirror", creating regions in space where they are suppressed. As we then effectively move an artificial atom in and out of these regions, measuring the atomic lifetime tells us the strength of the fluctuations. The weakest fluctuation strength we observe is 0.02 quanta, a factor of 50 below what would be expected without the mirror, demonstrating that we can hide the atom from the vacuum

Quantum computing with mixed states

We discuss a model for quantum computing with initially mixed states. Although such a computer is known to be less powerful than a quantum computer operating with pure (entangled) states, it may efficiently solve some problems for which no efficient classical algorithms are known. We suggest a new implementation of quantum computation with initially mixed states in which an algorithm realization is achieved by means of optimal basis independent transformations of qubits.Comment: 2 figures, 52 reference