1,039 research outputs found
Effects of heat release in a turbulent, reacting shear layer
Experiments were conducted to study the effects of heat release in a planar, gas-phase, reacting mixing layer formed between two free streams, one containing hydrogen in
an inert diluent, the other, fluorine in an inert diluent. Sufficiently high concentrations of reactants were utilized to produce adiabatic flame temperature rises of up to
940 K (corresponding to 1240 K absolute). The temperature field was measured at eight fixed points across the layer. Flow visualization was accomplished by schlieren
spark and motion picture photography. Mean velocity information was extracted from Pitot-probe dynamic pressure measurements. The results showed that the growth rate of the layer, for conditions of zero streamwise pressure gradient, decreased slightly with increasing heat release. The overall entrainment into the layer was substantially reduced as a consequence of heat release. A posteriori
calculations suggest that the decrease in layer growth rate is consistent with a corresponding reduction in turbulent shear stress. Large-scale coherent structures
were observed at all levels of heat release in this investigation. The mean structure spacing decreased with increasing temperature. This decrease was more than the
corresponding decrease in shear-layer growth rate, and suggests that the mechanisms of vortex amalgamation are, in some manner, inhibited by heat release. The mean
temperature rise profiles; normalized by the adiabatic flame temperature rise, were not greatly changed in shape over the range of heat release of this investigation. A
small decrease in normalized mean temperature rise with heat release was however observed. Imposition of a favourable pressure gradient in a mixing layer with heat
release resulted in an additional decrease in layer growth rate, and caused only a very slight increase in the mixing and amount of chemical product formation. The
additional decrease in layer growth rate is shown to be accounted for in terms of the change in free-stream velocity ratio induced by the pressure gradient
Effects of heat release in a turbulent, reacting shear layer
Experiments were conducted to study the effects of heat release in a planar, gas-phase, reacting mixing layer formed between two free streams, one containing hydrogen in
an inert diluent, the other, fluorine in an inert diluent. Sufficiently high concentrations of reactants were utilized to produce adiabatic flame temperature rises of up to
940 K (corresponding to 1240 K absolute). The temperature field was measured at eight fixed points across the layer. Flow visualization was accomplished by schlieren
spark and motion picture photography. Mean velocity information was extracted from Pitot-probe dynamic pressure measurements. The results showed that the growth rate of the layer, for conditions of zero streamwise pressure gradient, decreased slightly with increasing heat release. The overall entrainment into the layer was substantially reduced as a consequence of heat release. A posteriori
calculations suggest that the decrease in layer growth rate is consistent with a corresponding reduction in turbulent shear stress. Large-scale coherent structures
were observed at all levels of heat release in this investigation. The mean structure spacing decreased with increasing temperature. This decrease was more than the
corresponding decrease in shear-layer growth rate, and suggests that the mechanisms of vortex amalgamation are, in some manner, inhibited by heat release. The mean
temperature rise profiles; normalized by the adiabatic flame temperature rise, were not greatly changed in shape over the range of heat release of this investigation. A
small decrease in normalized mean temperature rise with heat release was however observed. Imposition of a favourable pressure gradient in a mixing layer with heat
release resulted in an additional decrease in layer growth rate, and caused only a very slight increase in the mixing and amount of chemical product formation. The
additional decrease in layer growth rate is shown to be accounted for in terms of the change in free-stream velocity ratio induced by the pressure gradient
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Characterizing large strain crush response of redwood
Containers for the transportation of hazardous and radioactive materials incorporate redwood in impact limiters. Redwood is an excellent energy absorber, but only the most rudimentary information exists on its crush properties. The objectives of the study were to fill the information gap by collecting triaxial load-deformation data for redwood; to use these data to characterize redwood crush, assess current wood failure theories, provide developments toward a complete stress-strain theory for redwood; and to review the literature on strain-rate effects on redwood crush performance. The load-deformation responses of redwood at temperature conditions corresponding to ambient (70{degrees}F), 150{degrees}F, and {minus}20{degrees}F conditions were measured in approximately 100 confined compression tests for crush levels leading to material densification. Data analysis provided a more complete description of redwood crush performance and a basis for assessing proposed general orthotropic stress-strain relationships for redwood. A review of existing literature indicated that strain-rate effects cause at most a 20 percent increase in crush stress parallel to grain
Theory of optical spectra of polar quantum wells: Temperature effects
Theoretical and numerical calculations of the optical absorption spectra of
excitons interacting with longitudinal-optical phonons in quasi-2D polar
semiconductors are presented. In II-VI semiconductor quantum wells, exciton
binding energy can be tuned on- and off-resonance with the longitudinal-optical
phonon energy by varying the quantum well width. A comprehensive picture of
this tunning effect on the temperature-dependent exciton absorption spectrum is
derived, using the exciton Green's function formalism at finite temperature.
The effective exciton-phonon interaction is included in the Bethe-Salpeter
equation. Numerical results are illustrated for ZnSe-based quantum wells. At
low temperatures, both a single exciton peak as well as a continuum resonance
state are found in the optical absorption spectra. By contrast, at high enough
temperatures, a splitting of the exciton line due to the real phonon absorption
processes is predicted. Possible previous experimental observations of this
splitting are discussed.Comment: 10 pages, 9 figures, to appear in Phys. Rev. B. Permanent address:
[email protected]
History of Inuit Community Exposure to Lead, Cadmium, and Mercury in Sewage Lake Sediments
Exposure to lead, cadmium, and mercury is known to be high in many arctic Inuit communities. These metals are emitted from industrial and urban sources, are distributed by long-range atmospheric transport to remote regions, and are found in Inuit country foods. Current community exposure to these metals can be measured in food, but feces and urine are also excellent indicators of total exposure from ingestion and inhalation because a high percentage of each metal is excreted. Bulk domestic sewage or its residue in a waste treatment system is a good substitute measure. Domestic waste treatment systems that accumulate metals in sediment provide an accurate historical record of changes in ingestion or inhalation. We collected sediment cores from an arctic lake used for facultative domestic sewage treatment to identify the history of community exposure to Pb, Cd, and Hg. Cores were dated and fluxes were measured for each metal. A nearby lake was sampled to measure combined background and atmospheric inputs, which were subtracted from sewage lake data. Pb, Cd, and Hg inputs from sewage grew rapidly after the onset of waste disposal in the late 1960s and exceeded the rate of population growth in the contributing community from 1970 to 1990. The daily per-person Pb input in 1990 (720,000 ng/person per day) exceeded the tolerable daily intake level. The Cd input (48,000 ng/person per day) and Hg input (19,000 ng/person per day) were below the respective TDI levels at the time
Controlled assembly of SNAP-PNA-fluorophore systems on DNA templates to produce fluorescence resonance energy transfer
The SNAP protein is a widely used self-labeling tag that can be used for tracking protein localization and trafficking in living systems. A model system providing controlled alignment of SNAP-tag units can provide a new way to study clustering of fusion proteins. In this work, fluorescent SNAP-PNA conjugates were controllably assembled on DNA frameworks forming dimers, trimers, and tetramers. Modification of peptide nucleic acid (PNA) with the O6-benzyl guanine (BG) group allowed the generation of site-selective covalent links between PNA and the SNAP protein. The modified BG-PNAs were labeled with fluorescent Atto dyes and subsequently chemo-selectively conjugated to SNAP protein. Efficient assembly into dimer and oligomer forms was verified via size exclusion chromatography (SEC), electrophoresis (SDS-PAGE), and fluorescence spectroscopy. DNA directed assembly of homo- and hetero-dimers of SNAP-PNA constructs induced homo- and hetero-FRET, respectively. Longer DNA scaffolds controllably aligned similar fluorescent SNAP-PNA constructs into higher oligomers exhibiting homo-FRET. The combined SEC and homo-FRET studies indicated the 1:1 and saturated assemblies of SNAP-PNA-fluorophore:DNA formed preferentially in this system. This suggested a kinetic/stoichiometric model of assembly rather than binomially distributed products. These BG-PNA-fluorophore building blocks allow facile introduction of fluorophores and/or assembly directing moieties onto any protein containing SNAP. Template directed assembly of PNA modified SNAP proteins may be used to investigate clustering behavior both with and without fluorescent labels which may find use in the study of assembly processes in cells
On the determination of the Fermi surface in high-Tc superconductors by angle-resolved photoemission spectroscopy
We study the normal state electronic excitations probed by angle resolved
photoemission spectroscopy (ARPES) in Bi2201 and Bi2212. Our main goal is to
establish explicit criteria for determining the Fermi surface from ARPES data
on strongly interacting systems where sharply defined quasiparticles do not
exist and the dispersion is very weak in parts of the Brillouin zone.
Additional complications arise from strong matrix element variations within the
zone. We present detailed results as a function of incident photon energy, and
show simple experimental tests to distinguish between an intensity drop due to
matrix element effects and spectral weight loss due to a Fermi crossing. We
reiterate the use of polarization selection rules in disentangling the effect
of umklapps due to the BiO superlattice in Bi2212. We conclude that, despite
all the complications, the Fermi surface can be determined unambiguously: it is
a single large hole barrel centered about (pi,pi) in both materials.Comment: Expanded discussion of symmetrization method in Section 5, figures
remain the sam
and Oxygen Stoichiometry: Structure, Resistivity, Fermi Surface Topology and Normal State Properties
(2212) single crystal samples
were studied using transmission electron microscopy (TEM), plane
() and axis () resistivity, and high resolution
angle-resolved ultraviolet photoemission spectroscopy (ARUPS). TEM reveals that
the modulation in the axis for doped 2212 is dominantly
of type that is not sensitive to the oxygen content of the system, and the
system clearly shows a structure of orthorhombic symmetry. Oxygen annealed
samples exhibit a much lower axis resistivity and a resistivity minimum at
K. He-annealed samples exhibit a much higher axis resistivity and
behavior below 300K. The Fermi surface (FS) of oxygen annealed
2212 mapped out by ARUPS has a pocket in the FS around the
point and exhibits orthorhombic symmetry. There are flat, parallel sections of
the FS, about 60\% of the maximum possible along , and about 30\%
along . The wavevectors connecting the flat sections are about
along , and about along , rather than . The symmetry of the near-Fermi-energy dispersing
states in the normal state changes between oxygen-annealed and He-annealed
samples.Comment: APS_REVTEX 3.0, 49 pages, including 11 figures, available upon
request. Submitted to Phys. Rev. B
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