742 research outputs found

    Automatic assembly design project 1968/9: report of technical survey committee

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    An Industrial survey has been carried out to determine the desired features of an automatic as machine. A questionnaire was circulated to industry and the results of the 38% response obtained were analysed and plotted. From these, conclusions were drawn as to the industrial requirements of an assembly machine

    Hydrogen Isocyanide in Comet 73P/Schwassmann-Wachmann (Fragment B)

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    We present a sensitive 3-sigma upper limit of 1.1% for the HNC/HCN abundance ratio in comet 73P/Schwassmann-Wachmann (Fragment B), obtained on May 10-11, 2006 using Caltech Submillimeter Observatory (CSO). This limit is a factor of ~7 lower than the values measured previously in moderately active comets at 1 AU from the Sun. Comet 73P/Schwassmann-Wachmann was depleted in most volatile species, except of HCN. The low HNC/HCN ratio thus argues against HNC production from polymers produced from HCN. However, thermal degradation of macromolecules, or polymers, produced from ammonia and carbon compounds, such as acetylene, methane, or ethane appears a plausible explanation for the observed variations of the HNC/HCN ratio in moderately active comets, including the very low ratio in comet 73P/Schwassmann-Wachmann reported here. Similar polymers have been invoked previously to explain anomalous 14N/15N ratios measured in cometary CN.Comment: 6 pages, 5 figures, 2 table

    Abundance Measurements of Titan's Stratospheric HCN, HC3_3N, C3_3H4_4, and CH3_3CN from ALMA Observations

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    Previous investigations have employed more than 100 close observations of Titan by the Cassini orbiter to elucidate connections between the production and distribution of Titan's vast, organic-rich chemical inventory and its atmospheric dynamics. However, as Titan transitions into northern summer, the lack of incoming data from the Cassini orbiter presents a potential barrier to the continued study of seasonal changes in Titan's atmosphere. In our previous work (Thelen et al., 2018), we demonstrated that the Atacama Large Millimeter/submillimeter Array (ALMA) is well suited for measurements of Titan's atmosphere in the stratosphere and lower mesosphere (~100-500 km) through the use of spatially resolved (beam sizes <1'') flux calibration observations of Titan. Here, we derive vertical abundance profiles of four of Titan's trace atmospheric species from the same 3 independent spatial regions across Titan's disk during the same epoch (2012 to 2015): HCN, HC3_3N, C3_3H4_4, and CH3_3CN. We find that Titan's minor constituents exhibit large latitudinal variations, with enhanced abundances at high latitudes compared to equatorial measurements; this includes CH3_3CN, which eluded previous detection by Cassini in the stratosphere, and thus spatially resolved abundance measurements were unattainable. Even over the short 3-year period, vertical profiles and integrated emission maps of these molecules allow us to observe temporal changes in Titan's atmospheric circulation during northern spring. Our derived abundance profiles are comparable to contemporary measurements from Cassini infrared observations, and we find additional evidence for subsidence of enriched air onto Titan's south pole during this time period. Continued observations of Titan with ALMA beyond the summer solstice will enable further study of how Titan's atmospheric composition and dynamics respond to seasonal changes.Comment: 15 pages, 16 figures, 2 tables. Accepted for publication in Icarus, September 201

    Ethyl cyanide on Titan: Spectroscopic detection and mapping using ALMA

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    We report the first spectroscopic detection of ethyl cyanide (C2_2H5_5CN) in Titan's atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/submillimeter array (ALMA). The presence of C2_2H5_5CN in Titan's ionosphere was previously inferred from Cassini ion mass spectrometry measurements of C2_2H5_5CNH+^+. Here we report the detection of 27 rotational lines from C2_2H5_5CN (in 19 separate emission features detected at >3σ>3\sigma confidence), in the frequency range 222-241 GHz. Simultaneous detections of multiple emission lines from HC3_3N, CH3_3CN and CH3_3CCH were also obtained. In contrast to HC3_3N, CH3_3CN and CH3_3CCH, which peak in Titan's northern (spring) hemisphere, the emission from C2_2H5_5CN is found to be concentrated in the southern (autumn) hemisphere, suggesting a distinctly different chemistry for this species, consistent with a relatively short chemical lifetime for C2_2H5_5CN. Radiative transfer models show that most of the C2_2H5_5CN is concentrated at altitudes 300-600 km, suggesting production predominantly in the mesosphere and above. Vertical column densities are found to be in the range (2-5)×1014\times10^{14} cm2^{-2}.Comment: Published in 2015, ApJL, 800, L1
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