Previous investigations have employed more than 100 close observations of
Titan by the Cassini orbiter to elucidate connections between the production
and distribution of Titan's vast, organic-rich chemical inventory and its
atmospheric dynamics. However, as Titan transitions into northern summer, the
lack of incoming data from the Cassini orbiter presents a potential barrier to
the continued study of seasonal changes in Titan's atmosphere. In our previous
work (Thelen et al., 2018), we demonstrated that the Atacama Large
Millimeter/submillimeter Array (ALMA) is well suited for measurements of
Titan's atmosphere in the stratosphere and lower mesosphere (~100-500 km)
through the use of spatially resolved (beam sizes <1'') flux calibration
observations of Titan. Here, we derive vertical abundance profiles of four of
Titan's trace atmospheric species from the same 3 independent spatial regions
across Titan's disk during the same epoch (2012 to 2015): HCN, HC3N,
C3H4, and CH3CN. We find that Titan's minor constituents exhibit large
latitudinal variations, with enhanced abundances at high latitudes compared to
equatorial measurements; this includes CH3CN, which eluded previous
detection by Cassini in the stratosphere, and thus spatially resolved abundance
measurements were unattainable. Even over the short 3-year period, vertical
profiles and integrated emission maps of these molecules allow us to observe
temporal changes in Titan's atmospheric circulation during northern spring. Our
derived abundance profiles are comparable to contemporary measurements from
Cassini infrared observations, and we find additional evidence for subsidence
of enriched air onto Titan's south pole during this time period. Continued
observations of Titan with ALMA beyond the summer solstice will enable further
study of how Titan's atmospheric composition and dynamics respond to seasonal
changes.Comment: 15 pages, 16 figures, 2 tables. Accepted for publication in Icarus,
September 201