Antarctic intermediate water circulation in the South Atlantic over the past 25,000years

Antarctic Intermediate Water is an essential limb of the Atlantic meridional overturning circulation that redistributes heat and nutrients within the Atlantic Ocean. Existing reconstructions have yielded conflicting results on the history of Antarctic Intermediate Water penetration into the Atlantic across the most recent glacial termination. In this study we present leachate, foraminiferal, and detrital neodymium isotope data from three intermediate-depth cores collected from the southern Brazil margin in the South Atlantic covering the past 25kyr. These results reveal that strong chemical leaching following decarbonation does not extract past seawater neodymium composition in this location. The new foraminiferal records reveal no changes in seawater Nd isotopes during abrupt Northern Hemisphere cold events at these sites. We therefore conclude that there is no evidence for greater incursion of Antarctic Intermediate Water into the South Atlantic during either the Younger Dryas or Heinrich Stadial 1. We do, however, observe more radiogenic Nd isotope values in the intermediate-depth South Atlantic during the mid-Holocene. This radiogenic excursion coincides with evidence for a southward shift in the Southern Hemisphere westerlies that may have resulted in a greater entrainment of radiogenic Pacific-sourced water during intermediate water production in the Atlantic sector of the Southern Ocean. Our intermediate-depth records show similar values to a deglacial foraminiferal Nd isotope record from the deep South Atlantic during the Younger Dryas but are clearly distinct during the Last Glacial Maximum and Heinrich Stadial 1, demonstrating that the South Atlantic remained chemically stratified during Heinrich Stadial 1.Natural Environment Research Council (Grant IDs: NE/K005235/1, NE/F006047/1), National Science Foundation (Grant ID: OCE -1335191), Rutherford Memorial Scholarship, DFG Research Center/Cluster of Excellence “The Ocean in the Earth System”, FAPESP (Grant ID: 2012/17517-3), CAPES (Grant IDs: 1976/2014, 564/2015

Construction of the Galapagos platform by large submarine volcanic terraces

Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q03015, doi:10.1029/2007GC001795.New multibeam bathymetric and side-scan sonar data from the southwestern edge of the Galápagos platform reveal the presence of ∼60 large, stepped submarine terraces between depths of 800 m and 3500 m. These terraces are unique features, as none are known from any other archipelago that share this geomorphic form or size. The terraces slope seaward at 3000 m) lava flow fields west of Fernandina and Isabela Islands. The terraces are formed of thick sequences of lava flows that coalesce to form the foundation of the Galápagos platform, on which the subaerial central volcanoes are built. The compositions of basalts dredged from the submarine terraces indicate that most lavas are chemically similar to subaerial lavas erupted from Sierra Negra volcano on southern Isabela Island. There are no regular major element, trace element, or isotopic variations in the submarine lavas as a function of depth, relative stratigraphic position, or geographic location along the southwest margin of the platform. We hypothesize that magma supply at the western edge of the Galápagos hot spot, which is influenced by both plume and mid-ocean ridge magmatic processes, leads to episodic eruption of large lava flows. These large lava flows coalesce to form the archipelagic apron upon which the island volcanoes are built.This work was supported by the National Science Foundation grants OCE0002818 and EAR0207605 (D.G.), OCE0002461 (D.J.F. and M.K.), OCE05-25864 (M.K.), and EAR0207425 (K.H.)

Late Archean to Early Proterozoic lithospheric mantle beneath the western North China craton: Sr–Nd–Os isotopes of peridotite xenoliths from Yangyuan and Fansi

Author Posting. © Elsevier B.V., 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Lithos 102 (2008): 25-42, doi:10.1016/j.lithos.2007.04.005.Sr-Nd-Os isotopic analyses are presented for peridotite xenoliths from Tertiary alkali basalts in Yangyuan and Fansi with the aim of identifying and characterizing the relics of ancient lithospheric mantle that survived lithospheric removal in the western North China Craton (NCC). The analyzed samples are residual lherzolites and harzburgites, ranging from fertile to highly depleted (0.36-4.0 wt% Al2O3) composition. Some LREE-enriched samples are characterized by moderate 87Sr/86Sr (0.7044 to 0.7047) and low εNd (–6.9 to –10.6), pointing to an EMI-type signature. This is distinct from the predominant depleted isotopic composition in mantle xenoliths from eastern China. Os isotopic ratios range from 0.1106 to 0.1325. The lower limit is the most unradiogenic value measured so far for Cenozoic basalt-borne xenoliths from eastern China. Two samples show radiogenic Os ratios higher than that of the primitive upper mantle, one sample has an anomalously high Os concentration (>9 ppb). These samples also show high La/Yb, consistent with the addition of radiogenic components during the infiltration of asthenosphere-derived and/or subduction-related melts in the lithospheric mantle. The remaining samples define positive correlations between 187Os/188Os and indices of melt extraction, which yield model ages of 2.4-2.8 Ga. This age of melt extraction overlaps with the Nd model age of the overlying crust, indicating a coupled crust-mantle system in the western NCC. This contrasts with the decoupled nature in the eastern NCC, suggesting distinct mantle domains underneath the NCC. Such a heterogeneous age structure of the upper mantle is compatible with the view that the lithospheric removal was largely limited to the eastern NCC.The authors gratefully acknowledge the financial support from the National Science Foundation of China (40673038; 49925308), the Chinese Academy of Sciences and China Scholarship Council to YGX for a six-month visit to the USA and from Japan Society for the Promotion of Science to KS (Grant-in Aid #14703002)

Melt generation beneath Arctic Ridges: Implications from Ule

We present new 238U-230Th-226Ra-210Pb, 235U-231Pa, and Nd, Sr, Hf, and Pb isotope data for the slow- to ultraslow-spreading Mohns, Knipovich, and Gakkel Ridges. Combined with previous work, our data from the Arctic Ridges cover the full range of axial depths from the deep northernmost Gakkel Ridge shallowing upwards to the Knipovich, Mohns, and Kolbeinsey Ridges north of Iceland. Age-constrained samples from the Mohns and Knipovich Ridges have (230Th/238U) activity ratios ranging from 1.165 to 1.30 and 1.101 to 1.225, respectively. The high 230Th excesses of Kolbeinsey, Mohns, and Knipovich mid-ocean ridge basalts (MORB) are erupted from ridges producing relatively thin (Mohns, Knipovich) to thick (Kolbeinsey) oceanic crust with evidence for sources ranging from mostly peridotite (Kolbeinsey) to eclogite-rich mantle (Mohns, Knipovich). Age-constrained lavas from 85ºE on the Gakkel Ridge, on the other hand, overlie little to no crust and range from small (~5%) 230Th excesses to small 238U excesses (~5%). The strong negative correlation between (230Th/238U) values vs. axial ridge depth among Arctic ridge basalts is controlled not only by solidus depth influence on 238U-230Th disequilibria, but also by variations in mantle source lithology and depth to the base of the lithosphere, which is expected to vary at ultra-slow spreading ridges. Small 231Pa excesses (65% excess) in age constrained basalts support the presence of eclogite in the mantle source for this region. Conversely, the ultraslow-spreading Gakkel Ridge basalts are homogeneous, with Sr, Nd, and Hf radiogenic isotopic signatures indicative of a long time-averaged depleted mantle source. The Gakkel samples have minimum (226 Ra/230Th) ratios ranging from 3.07 to 3.65 ± 3%, which lie along and extend the global negative correlation between 226Ra and 230Th excesses observed in MORB. The new 230Th-226Ra data support a model for global MORB production in which deep melts record interaction with shallower materials. This scenario requires either mixing with shallow-derived melts, or melt-rock reaction with shallower rocks in the lithosphere or crust

Isotopic constraints on the genesis and evolution of basanitic lavas at Haleakala, Island of Maui, Hawaii

© The Author(s), 2016. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geochimica et Cosmochimica Acta 195 (2016): 201-225, doi:10.1016/j.gca.2016.08.017.To understand the dynamics of solid mantle upwelling and melting in the Hawaiian plume, we present new major and trace element data, Nd, Sr, Hf, and Pb isotopic compositions, and 238U-230Th-226Ra and 235U-231Pa-227Ac activities for 13 Haleakala Crater nepheline normative basanites with ages ranging from ~900 to 4100 yr B.P.. These basanites of the Hana Volcanics exhibit an enrichment in incompatible trace elements and a more depleted isotopic signature than similarly aged Hawaiian shield lavas from Kilauea and Mauna Loa. Here we posit that as the Pacific lithosphere beneath the active shield volcanoes moves away from the center of the Hawaiian plume, increased incorporation of an intrinsic depleted component with relatively low 206Pb/204Pb produces the source of the basanites of the Hana Volcanics. Haleakala Crater basanites have average (230Th/238U) of 1.23 (n=13), average age-corrected (226Ra/230Th) of 1.25 (n=13), and average (231Pa/235U) of 1.67 (n=4), significantly higher than Kilauea and Mauna Loa tholeiites. U-series modeling shows that solid mantle upwelling velocity for Haleakala Crater basanites ranges from ~0.7 to 1.0 cm/yr, compared to ~10 to 20 cm/yr for tholeiites and ~1 to 2 cm/yr for alkali basalts. These modeling results indicate that solid mantle upwelling rates and porosity of the melting zone are lower for Hana Volcanics basanites than for shield-stage tholeiites from Kilauea and Mauna Loa and alkali basalts from Hualalai. The melting rate, which is directly proportional to both the solid mantle upwelling rate and the degree of melting, is therefore greatest in the center of the Hawaiian plume and lower on its periphery. Our results indicate that solid mantle upwelling velocity is at least 10 times higher at the center of the plume than at its periphery under Haleakala.Funding for this project was provided by NSF grants EAR-0001924 and EAR-9909473 to KWWS.2018-08-2

Lithogenic particle transport trajectories on the Northwest Atlantic Margin

Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 126(1), (2021): e2020JC016802, https://doi.org/10.1029/2020JC016802.The neodymium isotopic composition of the detrital (lithogenic) fraction (εNd‐detrital) of surface sediments and sinking particles was examined to constrain transport trajectories associated with hemipelagic sedimentation on the northwest Atlantic margin. The provenance of resuspended sediments and modes of lateral transport in the water column were of particular interest given the energetic hydrodynamic regime that sustains bottom and intermediate nepheloid layers over the margin. A large across‐margin gradient of ∼5 εNd units was observed for surface sediments, implying strong contrasts in sediment provenance, with εNd‐detrital values on the lower slope similar to those of “upstream regions” (Scotian margin) under the influence of the Deep Western Boundary Current (DWBC). Sinking particles collected at three depths at a site (total water depth, ∼3,000 m) on the New England margin within the core of the DWBC exhibited a similarly large range in εNd‐detrital values. The εNd‐detrital values of particles intercepted at intermediate water depths (1,000 and 2,000 m) were similar to each other but significantly higher than those at 3,000 m (∼50 m above the seafloor). These observations suggest that lithogenic material accumulating in the upper two traps was primarily advected in intermediate nepheloid layers emanating from the adjacent shelf, while that at 3,000 m is strongly influenced by sediment resuspension and along‐margin, southward lateral transport within the bottom nepheloid layer via entrainment in the DWBC. Our results highlight the importance of both along‐ and across‐margin sediment transport as vectors for lithogenic material and associated organic carbon transport.This research was funded by the NSF Ocean Sciences Chemical Oceanography program (OCE‐0425677; OCE‐0851350). JH was partly supported by the National Research Foundation of Korea (NRF) grant funded by the Korean Government (2020R1A2C1008378).2021-06-0

Regional Pliocene exhumation of the Lesser Himalaya in the Indus drainage

New bulk sediment Sr and Nd isotope data, coupled with U–Pb dating of detrital zircon grains from sediment cored by the International Ocean Discovery Program in the Arabian Sea, allow the reconstruction of erosion in the Indus catchment since ∼17&thinsp;Ma. Increasing εNd values from 17 to 9.5&thinsp;Ma imply relatively more erosion from the Karakoram and Kohistan, likely linked to slip on the Karakoram Fault and compression in the southern and eastern Karakoram. After a period of relative stability from 9.5 to 5.7&thinsp;Ma, there is a long-term decrease in εNd values that corresponds with increasing relative abundance of &gt;300&thinsp;Ma zircon grains that are most common in Himalayan bedrocks. The continuous presence of abundant Himalayan zircons precludes large-scale drainage capture as the cause of decreasing εNd values in the submarine fan. Although the initial increase in Lesser Himalaya-derived 1500–2300&thinsp;Ma zircons after 8.3&thinsp;Ma is consistent with earlier records from the foreland basin, the much greater rise after 1.9&thinsp;Ma has not previously been recognized and suggests that widespread unroofing of the Crystalline Lesser Himalaya and to a lesser extent Nanga Parbat did not occur until after 1.9&thinsp;Ma. Because regional erosion increased in the Pleistocene compared to the Pliocene, the relative increase in erosion from the Lesser Himalaya does not reflect slowing erosion in the Karakoram and Greater Himalaya. No simple links can be made between erosion and the development of the South Asian Monsoon, implying a largely tectonic control on Lesser Himalayan unroofing.</p

Geodynamic implications for zonal and meridional isotopic patterns across the northern Lau and North Fiji Basins

Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 18 (2017): 1013–1042, doi:10.1002/2016GC006651.We present new Sr-Nd-Pb-Hf-He isotopic data for 65 volcanic samples from the northern Lau and North Fiji Basins. This includes 47 lavas obtained from 40 dredge sites spanning an east-west transect across the Lau and North Fiji basins, 10 ocean island basalt (OIB)-type lavas collected from seven Fijian islands, and eight OIB lavas sampled on Rotuma. For the first time, we are able to map clear north-south and east-west geochemical gradients in 87Sr/86Sr across the northern Lau and North Fiji Basins: lavas with the most geochemically enriched radiogenic isotopic signatures are located in the northeast Lau Basin, while signatures of geochemical enrichment are diminished to the south and west away from the Samoan hot spot. Based on these geochemical patterns and plate reconstructions of the region, these observations are best explained by the addition of Samoa, Rurutu, and Rarotonga hot spot material over the past 4 Ma. We suggest that underplated Samoan material has been advected into the Lau Basin over the past ∼4 Ma. As the slab migrated west (and toward the Samoan plume) via rollback over time, younger and hotter (and therefore less viscous) underplated Samoan plume material was entrained. Thus, entrainment efficiency of underplated plume material was enhanced, and Samoan plume signatures in the Lau Basin became stronger as the trench approached the Samoan hot spot. The addition of subducted volcanoes from the Cook-Austral Volcanic Lineament first from the Rarotonga hot spot, then followed by the Rurutu hot spot, contributes to the extreme geochemical signatures observed in the northeast Lau Basin.NSF Grant Number: EAR-1624840, EAR-1348082, and EAR-1347377; French Agence Nationale de la Recherche Grant Number: ANR-10-BLAN-06032017-09-1

A new method for the determination of low-level actinium-227 in geological samples

Author Posting. © The Author(s), 2012. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Journal of Radioanalytical and Nuclear Chemistry 296 (2013): 279-283, doi:10.1007/s10967-012-2140-0.We developed a new method for the determination of 227Ac in geological samples. The method uses extraction chromatographic techniques and alpha-spectrometry and is applicable for a range of natural matrices. Here we report on the procedure and results of the analysis of water (fresh and seawater) and rock samples. Water samples were acidified and rock samples underwent total dissolution via acid leaching. A DGA (N,N,N’,N’-tetra-n-octyldiglycolamide) extraction chromatographic column was used for the separation of actinium. The actinium fraction was prepared for alpha spectrometric measurement via cerium fluoride micro-precipitation. Recoveries of actinium in water samples were 80±8 % (number of analyses n=14) and in rock samples 70±12 % (n=30). The minimum detectable activities (MDA) were 0.017-0.5 Bq kg-1 for both matrices. Rock sample 227Ac activities ranged from 0.17 to 8.3 Bq kg-1 and water sample activities ranged from below MDA values to 14 Bq kg-1of 227Ac. From the analysis of several standard rock and water samples with the method we found very good agreement between our results and certified values