5 research outputs found
Mantle Pb paradoxes : the sulfide solution
Author Posting. © Springer, 2006. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Contributions to Mineralogy and Petrology 152 (2006): 295-308, doi:10.1007/s00410-006-0108-1.There is growing evidence that the budget of Pb in mantle peridotites is largely
contained in sulfide, and that Pb partitions strongly into sulfide relative to silicate melt. In
addition, there is evidence to suggest that diffusion rates of Pb in sulfide (solid or melt)
are very fast. Given the possibility that sulfide melt âwetsâ sub-solidus mantle silicates,
and has very low viscosity, the implications for Pb behavior during mantle melting are
profound. There is only sparse experimental data relating to Pb partitioning between
sulfide and silicate, and no data on Pb diffusion rates in sulfides. A full understanding of
Pb behavior in sulfide may hold the key to several long-standing and important Pb
paradoxes and enigmas. The classical Pb isotope paradox arises from the fact that all
known mantle reservoirs lie to the right of the Geochron, with no consensus as to the
identity of the âbalancingâ reservoir. We propose that long-term segregation of sulfide
(containing Pb) to the core may resolve this paradox. Another Pb paradox arises from the fact that the Ce/Pb ratio of both OIB and MORB
is greater than bulk earth, and constant at a value of 25. The constancy of this âcanonical
ratioâ implies similar partition coefficients for Ce and Pb during magmatic processes
(Hofmann et al. 1986), whereas most experimental studies show that Pb is more
incompatible in silicates than Ce. Retention of Pb in residual mantle sulfide during
melting has the potential to bring the bulk partitioning of Ce into equality with Pb if the
sulfide melt/silicate melt partition coefficient for Pb has a value of ~ 14. Modeling shows
that the Ce/Pb (or Nd/Pb) of such melts will still accurately reflect that of the source, thus
enforcing the paradox that OIB and MORB mantles have markedly higher Ce/Pb (and
Nd/Pb) than the bulk silicate earth. This implies large deficiencies of Pb in the mantle
sources for these basalts. Sulfide may play other important roles during magmagenesis:
1). advective/diffusive sulfide networks may form potent metasomatic agents (in both
introducing and obliterating Pb isotopic heterogeneities in the mantle); 2). silicate melt
networks may easily exchange Pb with ambient mantle sulfides (by diffusion or
assimilation), thus âsamplingâ Pb in isotopically heterogeneous mantle domains
differently from the silicate-controlled isotope tracer systems (Sr, Nd, Hf), with an
apparent âde-couplingâ of these systems.Our intemperance
should not be blamed on the support we gratefully acknowledge from NSF: EAR-
0125917 to SRH and OCE-0118198 to GAG
Abrupt changes of hydrothermal activity in a lava dome detected by combined seismic and muon monitoring
Abstract The recent 2014 eruption of the Ontake volcano in Japan recalled that hydrothermal fields of moderately active volcanoes have an unpredictable and hazardous behavior that may endanger human beings. Steam blasts can expel devastating ejecta and create craters of several tens of meters. The management of such hydrothermal events in populated areas is problematic because of their very short time of occurrence. At present no precursory signal is clearly identified as a potential warning of imminent danger. Here we show how the combination of seismic noise monitoring and muon density tomography allows to detect, with an unprecedented space and time resolution, the increase of activity (at timescales of few hours to few days) of a hydrothermal spot located 50 to 100âm below the summit of an active volcano, the La SoufriĂšre of Guadeloupe, in the Lesser Antilles. We show how the combination of those two methods improves the risk evaluation of short-term hazards and the localization of the involved volumes in the volcano. We anticipate that the deployment of networks of various sensors including temperature probes, seismic antennas and cosmic muon telescopes around such volcanoes could valuably contribute to early warning decisions