4,363 research outputs found

    Measurement of the linear viscoelastic behavior of antimisting kerosene

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    Measurements of dynamic viscoelastic properties in very small oscillating shear deformations was made on solutions of a jet fuel, Jet A, containing an antimisting polymeric additive, FM-9. A few measurements were also made on solutions of FM-9 in a mixed solvent of mineral oil, Tetralin, and 0-terphenyl. Two samples of FM-9 had approximate number-average molecular weights of 12,000,000 and 8,100,000 as deduced from analysis of the measurements. The ranges of variables were 2.42 to 4.03 g/1 in concentration (0.3 to 0.5% by weight), 1 to 35 in temperature, 1.3 to 9.4 cp in solvent viscosity, and 103 to 6100 Hz in frequency. Measurements in the Jet A solvent were made both with and without a modifying carrier. The results were compared with the Zimm theory and the viscoelastic behavior was found to resemble rather closely that of ordinary non-polar polymers in theta solvents. The relation of the results to the antithixotropic behavior of such solutions a high shear rates is discussed in terms of intramolecular and intermolecular interactions

    On the mechanism of the highly viscous flow

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    The asymmetry model for the highly viscous flow postulates thermally activated jumps from a practically undistorted ground state to strongly distorted, but stable structures, with a pronounced Eshelby backstress from the distorted surroundings. The viscosity is ascribed to those stable distorted structures which do not jump back, but relax by the relaxation of the surrounding viscoelastic matrix. It is shown that this mechanism implies a description in terms of the shear compliance, with a viscosity which can be calculated from the cutoff of the retardation spectrum. Consistency requires that this cutoff lies close to the Maxwell time. The improved asymmetry model compares well with experiment.Comment: 8 pages, 3 figures, 49 references; revised version accepted in Journal of Chemical Physic

    Scattering of Dirac electrons by circular mass barriers: valley filter and resonant scattering

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    The scattering of two-dimensional (2D) massless Dirac electrons is investigated in the presence of a random array of circular mass barriers. The inverse momentum relaxation time and the Hall factor are calculated and used to obtain parallel and perpendicular resistivity components within linear transport theory. We found a non zero perpendicular resistivity component which has opposite sign for electrons in the different K and K' valleys. This property can be used for valley filter purposes. The total cross-section for scattering on penetrable barriers exhibit resonances due to the presence of quasi-bound states in the barriers that show up as sharp gaps in the cross-section while for Schr\"{o}dinger electrons they appear as peaks.Comment: 10 pages, 11 figure

    Low-Energy Conductivity of Single- and Double-Layer Graphene from the Uncertainty Principle

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    The minimum conductivity value as well as the linear dependence of conductivity on the charge density near the Dirac point in single and doublelayer graphene is derived from the energy-time uncertainty principle applied to ballistic charge carriers

    Nonlinear Transport of Bose-Einstein Condensates Through Waveguides with Disorder

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    We study the coherent flow of a guided Bose-Einstein condensate incident over a disordered region of length L. We introduce a model of disordered potential that originates from magnetic fluctuations inherent to microfabricated guides. This model allows for analytical and numerical studies of realistic transport experiments. The repulsive interaction among the condensate atoms in the beam induces different transport regimes. Below some critical interaction (or for sufficiently small L) a stationary flow is observed. In this regime, the transmission decreases exponentially with L. For strong interaction (or large L), the system displays a transition towards a time dependent flow with an algebraic decay of the time averaged transmission.Comment: 15 pages, 9 figure

    Energy Requirement of Control: Comments on Szilard's Engine and Maxwell's Demon

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    In mathematical physical analyses of Szilard's engine and Maxwell's demon, a general assumption (explicit or implicit) is that one can neglect the energy needed for relocating the piston in Szilard's engine and for driving the trap door in Maxwell's demon. If this basic assumption is wrong, then the conclusions of a vast literature on the implications of the Second Law of Thermodynamics and of Landauer's erasure theorem are incorrect too. Our analyses of the fundamental information physical aspects of various type of control within Szilard's engine and Maxwell's demon indicate that the entropy production due to the necessary generation of information yield much greater energy dissipation than the energy Szilard's engine is able to produce even if all sources of dissipation in the rest of these demons (due to measurement, decision, memory, etc) are neglected.Comment: New, simpler and more fundamental approach utilizing the physical meaning of control-information and the related entropy production. Criticism of recent experiments adde

    Coherent transport through graphene nanoribbons in the presence of edge disorder

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    We simulate electron transport through graphene nanoribbons of experimentally realizable size (length L up to 2 micrometer, width W approximately 40 nm) in the presence of scattering at rough edges. Our numerical approach is based on a modular recursive Green's function technique that features sub-linear scaling with L of the computational effort. We identify the influence of the broken A-B sublattice (or chiral) symmetry and of K-K' scattering by Fourier spectroscopy of individual scattering states. For long ribbons we find Anderson-localized scattering states with a well-defined exponential decay over 10 orders of magnitude in amplitude.Comment: 8 pages, 6 Figure

    Underscreened Kondo effect in S=1 magnetic quantum dots: Exchange, anisotropy and temperature effects

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    We present a theoretical analysis of the effects of uniaxial magnetic anisotropy and contact-induced exchange field on the underscreened Kondo effect in S=1 magnetic quantum dots coupled to ferromagnetic leads. First, by using the second-order perturbation theory we show that the coupling to spin-polarized electrode results in an effective exchange field BeffB_{\rm eff} and an effective magnetic anisotropy DeffD_{\rm eff}. Second, we confirm these findings by using the numerical renormalization group method, which is employed to study the dependence of the quantum dot spectral functions, as well as quantum dot spin, on various parameters of the system. We show that the underscreened Kondo effect is generally suppressed due to the presence of effective exchange field and can be restored by tuning the anisotropy constant, when Deff=Beff|D_{\rm eff}| = |B_{\rm eff}|. The Kondo effect can also be restored by sweeping an external magnetic field, and the restoration occurs twice in a single sweep. From the distance between the restored Kondo resonances one can extract the information about both the exchange field and the effective anisotropy. Finally, we calculate the temperature dependence of linear conductance for the parameters where the Kondo effect is restored and show that the restored Kondo resonances display a universal scaling of S=1/2S=1/2 Kondo effect.Comment: 13 pages, 9 figures (version as accepted for publication in Physical Review B

    Viscoelasticity and metastability limit in supercooled liquids

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    A supercooled liquid is said to have a kinetic spinodal if a temperature Tsp exists below which the liquid relaxation time exceeds the crystal nucleation time. We revisit classical nucleation theory taking into account the viscoelastic response of the liquid to the formation of crystal nuclei and find that the kinetic spinodal is strongly influenced by elastic effects. We introduce a dimensionless parameter \lambda, which is essentially the ratio between the infinite frequency shear modulus and the enthalpy of fusion of the crystal. In systems where \lambda is larger than a critical value \lambda_c the metastability limit is totally suppressed, independently of the surface tension. On the other hand, if \lambda < \lambda_c a kinetic spinodal is present and the time needed to experimentally observe it scales as exp[\omega/(\lambda_c-\lambda)^2], where \omega is roughly the ratio between surface tension and enthalpy of fusion
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