58,868 research outputs found
Homogeneous SPC/E water nucleation in large molecular dynamics simulations
We perform direct large molecular dynamics simulations of homogeneous SPC/E
water nucleation, using up to molecules. Our large system
sizes allow us to measure extremely low and accurate nucleation rates, down to
, helping close the gap between
experimentally measured rates .
We are also able to precisely measure size distributions, sticking
efficiencies, cluster temperatures, and cluster internal densities. We
introduce a new functional form to implement the Yasuoka-Matsumoto nucleation
rate measurement technique (threshold method). Comparison to nucleation models
shows that classical nucleation theory over-estimates nucleation rates by a few
orders of magnitude. The semi-phenomenological nucleation model does better,
under-predicting rates by at worst, a factor of 24. Unlike what has been
observed in Lennard-Jones simulations, post-critical clusters have temperatures
consistent with the run average temperature. Also, we observe that
post-critical clusters have densities very slightly higher, , than
bulk liquid. We re-calibrate a Hale-type vs. scaling relation using
both experimental and simulation data, finding remarkable consistency in over
orders of magnitude in the nucleation rate range, and K in the
temperature range.Comment: Accepted for publication in the Journal of Chemical Physic
Synchrotron X-ray emission from old pulsars
We study the synchrotron radiation as the observed non-thermal X-ray emission
from old pulsars (Myr) to investigate the particle acceleration in
their magnetospheres. We assume that the power-law component of the observed
X-ray spectra is caused by the synchrotron radiation from electrons and
positrons in the magnetosphere. We consider two pair production mechanisms of
X-ray emitting particles, the magnetic and the photon-photon pair productions.
High-energy photons, which ignite the pair production, are emitted via the
curvature radiation of the accelerated particles. We use the analytical
description for the radiative transfer and estimate the luminosity of the
synchrotron radiation. We find that for pulsars with the spin-down luminosity
erg s, the locations of the particle
acceleration and the non-thermal X-ray emission are within cm
from the centre of the neutron star, where the magnetic pair production occurs.
For pulsars with the spin-down luminosity erg
s such as J0108-1431, the synchrotron radiation is difficult to explain
the observed non-thermal component even if we consider the existence of the
strong and small-scale surface magnetic field structures.Comment: 25 pages, 7 figures, 2 tables, accepted for publication in MNRA
Loopy belief propagation and probabilistic image processing
Estimation of hyperparameters by maximization of the marginal likelihood in probabilistic image processing is investigated by using the cluster variation method. The algorithms are substantially equivalent to generalized loopy belief propagation
Absorption spectrum of (H2O)-O-18 in the range 12 400-14 520 cm(-1)
Fourier transform spectra recorded using (a) natural abundance water vapor, (b) (H2O)-O-18-enriched water vapor, and (c) (H2O)-O-17-enriched water vapor are analyzed. The ratio of intensities in three spectra is used to identify 927 lines due to absorption by (H2O)-O-18. Intensities and self-broadening parameters are derived for these lines. Using theoretical linelists, comparisons with previously assigned (H2O)-O-16 spectra, and automatic searches for combination differences, 747 lines are assigned. These lines belong to 14 vibrational states in the 3nu + delta and 4nu polyads. Newly determined (H2O)-O-18 vibrational band origins include 4nu(1) at 13 793.09 cm(-1), 3nu(1) + nu(3) at 13 795.40 cm(-1), 2nu(1) + 2nu(3) at 14 188.82 cm(-1), nu(1) + 3nu(3) at 14 276.34 cm(-1), and 2nu(2) + 2nu(2) + nu(3) at 13 612.71 cm(-1). These results are compared with data in HITRAN. (C) 2002 Elsevier Science (USA)
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