Cathode chemistries and electrode parameters affecting the fast charging performance of li-ion batteries

Li-ion battery fast-charging technology plays an important role in popularizing electric vehicles (EV), which critically need a charging process that is as simple and quick as pumping fuel for conventional internal combustion engine vehicles. To ensure stable and safe fast charging of Li-ion battery, understanding the electrochemical and thermal behaviors of battery electrodes under high rate charges is crucial, since it provides insight into the limiting factors that restrict the battery from acquiring energy at high rates. In this work, charging simulations are performed on Li-ion batteries that use the LiCoO2 (LCO), LiMn2O4 (LMO), and LiFePO4 (LFP) as the cathodes. An electrochemical-thermal coupling model is first developed and experimentally validated on a 2.6Ah LCO based Li-ion battery and is then adjusted to study the LMO and LFP based batteries. LCO, LMO, and LFP based Li-ion batteries exhibited different thermal responses during charges due to their different entropy profiles, and results show that the entropy change of the LCO battery plays a positive role in alleviating its temperature rise during charges. Among the batteries, the LFP battery is difficult to be charged at high rates due to the charge transfer limitation caused by the low electrical conductivity of the LFP cathode, which, however, can be improved through doping or adding conductive additives. A parametric study is also performed by considering different electrode thicknesses and secondary particle sizes. It reveals that the concentration polarization at the electrode and particle levels can be weaken by using thin electrodes and small solid particles, respectively. These changes are helpful to mitigate the diffusion limitation and improve the performance of Li-ion batteries during high rate charges, but careful consideration should be taken when applying these changes since they can reduce the energy density of the batteries

Melosh rotation: source of the proton's missing spin

It is shown that the observed small value of the integrated spin structure function for protons could be naturally understood within the naive quark model by considering the effect from Melosh rotation. The key to this problem lies in the fact that the deep inelastic process probes the light-cone quarks rather than the instant-form quarks, and that the spin of the proton is the sum of the Melosh rotated light-cone spin of the individual quarks rather than simply the sum of the light-cone spin of the quarks directly.Comment: 5 latex page

Postbuckling behaviour of beams with discrete nonlinear restraints

A beam with nonlinearly ‐ elastic lateral restraints attached at discrete points along its span is investigated via analytical and numerical methods. Previous results for the critical moment and the deflected shape based on an eigenvalue analysis of a similar beam with linearly ‐ elastic restraints are discussed, along with a validation of these results against an equivalent finite element model and results from numerical continuation. A beam with nonlinearly ‐ elastic restraints is then analysed with treatments for both quadratic and cubic restraint force–displacement relationships being provided. After formulation of the potential energy functionals, the governing differential equations of the system are derived via the calculus of variations and appropriate boundary conditions are applied. The equations are then solved using the numerical continuation software AUTO ‐ 07p for a standard I ‐ section beam. The variation in elastic critical buckling moment with the linear component of the restraint stiffness is tracked via a two ‐ parameter numerical continuation, allowing determination of the stiffness values at which the critical buckling modes changes qualitatively. Using these stiffness values, subsequent analyses are conducted to examine the influence of the nonlinear component of the restraint stiffness, from which post ‐ buckling equilibrium paths and deformation modes are extracted. The results of these analyses are then compared with an equivalent Rayleigh–Ritz formulation whereby the displacement components are represented by Fourier series. Equilibrium equations are derived by minimizing the potential energy functional with respect to the amplitudes of the constituent harmonics of the Fourier series. The amplitudes are solved for in the post ‐ buckling range by AUTO ‐ O7p and equilibrium paths are produced and compared to the equivalent solutions of the differential equations, with good agreement observed

Stochastic stability of viscoelastic systems under Gaussian and Poisson white noise excitations

As the use of viscoelastic materials becomes increasingly popular, stability of viscoelastic structures under random loads becomes increasingly important. This paper aims at studying the asymptotic stability of viscoelastic systems under Gaussian and Poisson white noise excitations with Lyapunov functions. The viscoelastic force is approximated as equivalent stiffness and damping terms. A stochastic differential equation is set up to represent randomly excited viscoelastic systems, from which a Lyapunov function is determined by intuition. The time derivative of this Lyapunov function is then obtained by stochastic averaging. Approximate conditions are derived for asymptotic Lyapunov stability with probability one of the viscoelastic system. Validity and utility of this approach are illustrated by a Duffing-type oscillator possessing viscoelastic forces, and the influence of different parameters on the stability region is delineated

NMR evidence of strong-correlated superconductivity in LiFeAs: tuning toward an SDW ordering

In this letter, we reported the results of NMR study on LiFeAs single crystals. We find a strong evidence of the low temperature spin fluctuations; by changing sample preparation conditions, the system can be tuned toward an spin-density-wave (SDW) quantum-critical point. The detection of an interstitial Li(2) ion, possibly locating in the tetrahedral hole, suggests that the off-stoichiometry and/or lattice defect can probably account for the absence of the SDW ordering in LiFeAs. These facts show that LiFeAs is a strongly correlated system and the superconductivity is likely originated from the SDW fluctuations.Comment: 5 pages, s figure

Stabilization of charge ordering in La_(1/3)Sr_(2/3)FeO_(3-d) by magnetic exchange

The magnetic exchange energies in charge ordered La_(1/3)Sr_(2/3)FeO_(3-d) (LSFO) and its parent compound LaFeO_(3) (LFO) have been determined by inelastic neutron scattering. In LSFO, the measured ratio of ferromagnetic exchange between Fe3+ - Fe5+ pairs (J_F) and antiferromagnetic exchange between Fe3+ - Fe3+ pairs (J_AF) fulfills the criterion for charge ordering driven by magnetic interactions (|J_F/J_AF| > 1). The 30% reduction of J_AF as compared to LFO indicates that doped holes are delocalized, and charge ordering occurs without a dominant influence from Coulomb interactions.Comment: 18 pages, 4 color figure