940 research outputs found
Ultra rapid strength development in dry-mix shotcrete for ultra rapid support in challenging mining conditions
Abstrac
Direct observation of charge inversion by multivalent ions as a universal electrostatic phenomenon
We have directly observed reversal of the polarity of charged surfaces in
water upon the addition of tri- and quadrivalent ions using atomic force
microscopy. The bulk concentration of multivalent ions at which charge
inversion reversibly occurs depends only very weakly on the chemical
composition, surface structure, size and lipophilicity of the ions, but is
dominated by their valence. These results support the theoretical proposal that
spatial correlations between ions are the driving mechanism behind charge
inversion.Comment: submitted to PRL, 26-04-2004 Changed the presentation of the theory
at the end of the paper. Changed small error in estimate of prefactor ("w" in
first version) of equation
Smoke-Free Policy in Vermont Public Housing Authorities
Introduction. Millions of adults and children living in public housing face exposure to second hand smoke from adjacent apartments. These tenants are less able to escape smoke exposure by moving, and Housing Authorities are beginning to implement smoke-free policies. We assessed the status of smoke-free policy in Vermont public housing, and explored the experience of tenants and managers in Burlington who recently implemented such a policy.https://scholarworks.uvm.edu/comphp_gallery/1080/thumbnail.jp
Crossover from 2-dimensional to 1-dimensional collective pinning in NbSe3
We have fabricated NbSe structures with widths comparable to the
Fukuyama-Lee-Rice phase-coherence length. For samples already in the
2-dimensional pinning limit, we observe a crossover from 2-dimensional to
1-dimensional collective pinning when the crystal width is less than 1.6
m, corresponding to the phase-coherence length in this direction. Our
results show that surface pinning is negligible in our samples, and provide a
means to probe the dynamics of single domains giving access to a new regime in
charge-density wave physics.Comment: 4 pages, 2 figures, and 1 table. Accepted for publication in Physical
Review
Convective Term and Transversely Driven Charge-Density Waves
We derive the convective terms in the damping which determine the structure
of the moving charge-density wave (CDW), and study the effect of a current
flowing transverse to conducting chains on the CDW dynamics along the chains.
In contrast to a recent prediction we find that the effect is orders of
magnitude smaller, and that contributions from transverse currents of electron-
and hole-like quasiparticles to the force exerted on the CDW along the chains
act in the opposite directions. We discuss recent experimental verification of
the effect and demonstrate experimentally that geometry effects might mimic the
transverse current effect.Comment: RevTeX, 9 pages, 1 figure, accepted for publications in PR
Understanding the errors of SHAPE-directed RNA structure modeling
Single-nucleotide-resolution chemical mapping for structured RNA is being
rapidly advanced by new chemistries, faster readouts, and coupling to
computational algorithms. Recent tests have shown that selective 2'-hydroxyl
acylation by primer extension (SHAPE) can give near-zero error rates (0-2%) in
modeling the helices of RNA secondary structure. Here, we benchmark the method
using six molecules for which crystallographic data are available: tRNA(phe)
and 5S rRNA from Escherichia coli, the P4-P6 domain of the Tetrahymena group I
ribozyme, and ligand-bound domains from riboswitches for adenine, cyclic
di-GMP, and glycine. SHAPE-directed modeling of these highly structured RNAs
gave an overall false negative rate (FNR) of 17% and a false discovery rate
(FDR) of 21%, with at least one helix prediction error in five of the six
cases. Extensive variations of data processing, normalization, and modeling
parameters did not significantly mitigate modeling errors. Only one varation,
filtering out data collected with deoxyinosine triphosphate during primer
extension, gave a modest improvement (FNR = 12%, and FDR = 14%). The residual
structure modeling errors are explained by the insufficient information content
of these RNAs' SHAPE data, as evaluated by a nonparametric bootstrapping
analysis. Beyond these benchmark cases, bootstrapping suggests a low level of
confidence (<50%) in the majority of helices in a previously proposed
SHAPE-directed model for the HIV-1 RNA genome. Thus, SHAPE-directed RNA
modeling is not always unambiguous, and helix-by-helix confidence estimates, as
described herein, may be critical for interpreting results from this powerful
methodology.Comment: Biochemistry, Article ASAP (Aug. 15, 2011
Salt marsh ecosystem biogeochemical responses to nutrient enrichment : a paired 15N tracer study
Author Posting. © Ecological Society of America, 2009. This article is posted here by permission of Ecological Society of America for personal use, not for redistribution. The definitive version was published in Ecology 90 (2009): 2535-2546, doi:10.1890/08-1051.1.We compared processing and fate of dissolved NO3− in two New England salt marsh ecosystems, one receiving natural flood tide concentrations of 1–4 μmol NO3−/L and the other receiving experimentally fertilized flood tides containing 70–100 μmol NO3−/L. We conducted simultaneous 15NO3− (isotope) tracer additions from 23 to 28 July 2005 in the reference (8.4 ha) and fertilized (12.4 ha) systems to compare N dynamics and fate. Two full tidal cycles were intensively studied during the paired tracer additions. Resulting mass balances showed that essentially 100% (0.48–0.61 mol NO3-N·ha−1·h−1) of incoming NO3− was assimilated, dissimilated, sorbed, or sedimented (processed) within a few hours in the reference system when NO3− concentrations were 1.3–1.8 μmol/L. In contrast, only 50–60% of incoming NO3− was processed in the fertilized system when NO3− concentrations were 84–96 μmol/L; the remainder was exported in ebb tidewater. Gross NO3− processing was 40 times higher in the fertilized system at 19.34–24.67 mol NO3-N·ha−1·h−1. Dissimilatory nitrate reduction to ammonium was evident in both systems during the first 48 h of the tracer additions but <1% of incoming 15NO3− was exported as 15NH4+. Nitrification rates calculated by 15NO3− dilution were 6.05 and 4.46 mol·ha−1·h−1 in the fertilized system but could not be accurately calculated in the reference system due to rapid (<4 h) NO3− turnover. Over the five-day paired tracer addition, sediments sequestered a small fraction of incoming NO3−, although the efficiency of sequestration was 3.8% in the reference system and 0.7% in the fertilized system. Gross sediment N sequestration rates were similar at 13.5 and 12.6 mol·ha−1·d−1, respectively. Macrophyte NO3− uptake efficiency, based on tracer incorporation in aboveground tissues, was considerably higher in the reference system (16.8%) than the fertilized system (2.6%), although bulk uptake of NO3− by plants was lower in the reference system (1.75 mol NO3−·ha−1·d−1) than the fertilized system (10 mol NO3−·ha−1·d−1). Nitrogen processing efficiency decreased with NO3− load in all pools, suggesting that the nutrient processing capacity of the marsh ecosystem was exceeded in the fertilized marsh.This work was funded by National Science
Foundation Grant DEB 0213767 and OCE 9726921
Temporally ordered collective creep and dynamic transition in the charge-density-wave conductor NbSe3
We have observed an unusual form of creep at low temperatures in the
charge-density-wave (CDW) conductor NbSe. This creep develops when CDW
motion becomes limited by thermally-activated phase advance past individual
impurities, demonstrating the importance of local pinning and related
short-length-scale dynamics. Unlike in vortex lattices, elastic collective
dynamics on longer length scales results in temporally ordered motion and a
finite threshold field. A first-order dynamic phase transition from creep to
high-velocity sliding produces "switching" in the velocity-field
characteristic.Comment: 4 pages, 4 eps figures; minor clarifications To be published in Phys.
Rev. Let
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