Poly(acrylic acid)-coated iron oxide nanoparticles : quantitative evaluation of the coating properties and applications for the removal of a pollutant dye

In this work, 6 to 12 nm iron oxide nanoparticles were synthesized and coated with poly(acrylic acid) chains of molecular weight 2100 g/mol. Based on a quantitative evaluation of the dispersions, the bare and coated particles were thoroughly characterized. The number densities of polymers adsorbed at the particle surface and of available chargeable groups were found to be 1.9 +/- 0.3 nm-2 and 26 +/- 4 nm-2, respectively. Occurring via a multi-site binding mechanism, the electrostatic coupling leads to a solid and resilient anchoring of the chains. To assess the efficacy of the particles for pollutant remediation, the adsorption isotherm of methylene blue molecules, a model of pollutant, was determined. The excellent agreement between the predicted and measured amounts of adsorbed dyes suggests that most carboxylates participate to the complexation and adsorption mechanisms. An adsorption of 830 mg/g was obtained. This quantity compares well with the highest values available for this dye.Comment: 14 pages 5 figures, accepted 06-Dec-2012; Journal of Colloid and Interface Science (2013

Detection of genuinely entangled and non-separable nn-partite quantum states

We investigate the detection of entanglement in $n$-partite quantum states. We obtain practical separability criteria to identify genuinely entangled and non-separable mixed quantum states. No numerical optimization or eigenvalue evaluation is needed, and our criteria can be evaluated by simple computations involving components of the density matrix. We provide examples in which our criteria perform better than all known separability criteria. Specifically, we are able to detect genuine $n$-partite entanglement which has previously not been identified. In addition, our criteria can be used in today's experiment.Comment: 8 pages, one figur

Study of Interplanetary Magnetic Field with Ground State Alignment

We demonstrate a new way of studying interplanetary magnetic field -- Ground State Alignment (GSA). Instead of sending thousands of space probes, GSA allows magnetic mapping with any ground telescope facilities equipped with spectropolarimeter. The polarization of spectral lines that are pumped by the anisotropic radiation from the Sun is influenced by the magnetic realignment, which happens for magnetic field (<1G). As a result, the linear polarization becomes an excellent tracer of the embedded magnetic field. The method is illustrated by our synthetic observations of the Jupiter's Io and comet Halley. Polarization at each point was constructed according to the local magnetic field detected by spacecrafts. Both spatial and temporal variations of turbulent magnetic field can be traced with this technique as well. The influence of magnetic field on the polarization of scattered light is discussed in detail. For remote regions like the IBEX ribbons discovered at the boundary of interstellar medium, GSA provides a unique diagnostics of magnetic field.Comment: 11 pages, 19 figures, published in Astrophysics and Space Scienc

Anisotropic Polarizability of Ultracold Polar 40^{40}K87^{87}Rb Molecules

We report the measurement of the anisotropic AC polarizability of ultracold polar $^{40}$K$^{87}$Rb molecules in the ground and first rotationally excited states. Theoretical analysis of the polarizability agrees well with experimental findings. Although the polarizability can vary by more than 30%, a "magic" angle between the laser polarization and the quantization axis is found where the polarizability of the $|N=0,m_N=0>$ and the $|N=1,m_N=0>$ states match. At this angle, rotational decoherence due to the mismatch in trapping potentials is eliminated, and we observe a sharp increase in the coherence time. This paves the way for precise spectroscopic measurements and coherent manipulations of rotational states as a tool in the creation and probing of novel quantum many-body states of polar molecules.Comment: 4 pages for main text, 4 figures, 2 pages for supplementary informatio

Probing Very Bright End of Galaxy Luminosity Function at z >~ 7 Using Hubble Space Telescope Pure Parallel Observations

We report the first results from the Hubble Infrared Pure Parallel Imaging Extragalactic Survey, which utilizes the pure parallel orbits of the Hubble Space Telescope to do deep imaging along a large number of random sightlines. To date, our analysis includes 26 widely separated fields observed by the Wide Field Camera 3, which amounts to 122.8 sq.arcmin in total area. We have found three bright Y098-dropouts, which are candidate galaxies at z >~ 7.4. One of these objects shows an indication of peculiar variability and its nature is uncertain. The other two objects are among the brightest candidate galaxies at these redshifts known to date L>2L*. Such very luminous objects could be the progenitors of the high-mass Lyman break galaxis (LBGs) observed at lower redshifts (up to z~5). While our sample is still limited in size, it is much less subject to the uncertainty caused by "cosmic variance" than other samples because it is derived using fields along many random sightlines. We find that the existence of the brightest candidate at z~7.4 is not well explained by the current luminosity function (LF) estimates at z~8. However, its inferred surface density could be explained by the prediction from the LFs at z~7 if it belongs to the high-redshift tail of the galaxy population at z~7.Comment: ApJL in press (accepted Dec. 27, 2010); minor corrections and one figure added to address referee's comment

Higher order net-proton number cumulants dependence on the centrality definition and other spurious effects

We study the dependence of the normalized moments of the net-proton multiplicity distributions on the definition of centrality in relativistic nuclear collisions at a beam energy of $\sqrt{s_{\mathrm{NN}}}= 7.7$ GeV. Using the UrQMD model as event generator we find that the centrality definition has a large effect on the extracted cumulant ratios. Furthermore we find that the finite efficiency for the determination of the centrality introduces an additional systematic uncertainty. Finally, we quantitatively investigate the effects of event-pile up and other possible spurious effects which may change the measured proton number. We find that pile-up alone is not sufficient to describe the data and show that a random double counting of events, adding significantly to the measured proton number, affects mainly the higher order cumulants in most central collisions.Comment: 10 pages 13 figures, version accepted by JP

Kosterlitz-Thouless and Potts transitions in a generalized XY model

We present extensive numerical simulations of a generalized XY model with nematic-like terms recently proposed by Poderoso {\it et al} [PRL 106(2011)067202]. Using finite size scaling and focusing on the $q=3$ case, we locate the transitions between the paramagnetic (P), the nematic-like (N) and the ferromagnetic (F) phases. The results are compared with the recently derived lower bounds for the P-N and P-F transitions. While the P-N transition is found to be very close to the lower bound, the P-F transition occurs significantly above the bound. Finally, the transition between the nematic-like and the ferromagnetic phases is found to belong to the 3-states Potts universality class.Comment: Extended and updated version of arXiv:1207.3447v