319 research outputs found
Fermiology and superconductivity studies on the non-tetrachalcogenafulvalene structured organic superconductor beta-(BDA-TTP)_2SbF_6
The quantum oscillatory effect and superconductivity in a
non-tetrachalcogenafulvalene (TCF) structure based organic superconductor
beta-(BDA-TTP)_2SbF_6 are studied. Here the Shubnikov-de Haas effect (SdH) and
angular dependent magnetoresistance oscillations (AMRO) are observed. The
oscillation frequency associated with a cylindrical Fermi surface is found to
be about 4050 tesla, which is also verified by the tunnel diode oscillator
(TDO) measurement. The upper critical field Hc2 measurement in a tilted
magnetic field and the TDO measurement in the mixed state reveal a highly
anisotropic superconducting nature in this material. We compared physical
properties of beta-(BDA-TTP)_2SbF_6 with typical TCF structure based quasi
two-dimensional organic conductors. A notable feature of beta-(BDA-TTP)_2SbF_6
superconductor is a large value of effective cyclotron mass m_c^*=12.4+/1.1
m_e, which is the largest yet found in an organic superconductor. A possible
origin of the enhanced effective mass and its relation to the superconductivity
are briefly discussed.Comment: 8 pages, 10 figure
Coherent vs incoherent interlayer transport in layered metals
The magnetic-field, temperature, and angular dependence of the interlayer
magnetoresistance of two different quasi-two-dimensional (2D) organic
superconductors is reported. For -(BEDT-TTF)I we find a
well-resolved peak in the angle-dependent magnetoresistance at (field parallel to the layers). This clear-cut proof for the coherent
nature of the interlayer transport is absent for
''-(BEDT-TTF)SFCHCFSO. This and the non-metallic
behavior of the magnetoresistance suggest an incoherent quasiparticle motion
for the latter 2D metal.Comment: 4 pages, 4 figures. Phys. Rev. B, in pres
Interplane Transport and Superfluid Density in Layered Superconductors
We report on generic trends in the behavior of the interlayer penetration
depth of several different classes of quasi two-dimensional
superconductors including cuprates, SrRuO, transition metal
dichalcogenides and organic materials of the -series. Analysis
of these trends reveals two distinct patterns in the scaling between the values
of and the magnitude of the DC conductivity: one realized in the
systems with a Fermi liquid (FL) ground state and the other seen in systems
with a marked deviation from the FL response. The latter pattern is found
primarily in under-doped cuprates and indicates a dramatic enhancement (factor
) of the energy scale associated with the formation of
the condensate compared to the data for the FL materials. We discuss
implications of these results for the understanding of pairing in high-
cuprates.Comment: 4 pages, 2 figure
Self-assembly of micelles into designed networks
The EO20PO70EO20(molecular weight 5800) amphiphile as a template is to form dispersed micelle structures. Silver nanoparticles, as inorganic precursors synthesized by a laser ablation method in pure water, are able to produce the highly ordered vesicles detected by TEM micrography. The thickness of the outer layer of a micelle, formed by the silver nanoparticles interacting preferentially with the more hydrophilic EO20block, was around 3.5 nm. The vesicular structure ensembled from micelles is due to proceeding to the mixture of cubic and hexagonal phases
Self-organization of stack-up block copolymers into polymeric supramolecules
Polyethylene oxide –b– polypropylene oxide -b- polyethylene oxide (EO106PO70EO106) block copolymer self-organizes into polymeric supramolecules, characterized by NMR as phase transition from the isotropic stack-up block structure to the ordered cubic polymeric supramolecular structure. Its dependence on both temperature and copolymer concentration is clearly shown by the changes in line shape and chemical shift of the PO70blockβ,γresonances
Structural Characterization of Mesoporous Silica Nanofibers Synthesized Within Porous Alumina Membranes
Mesoporous silica nanofibers were synthesized within the pores of the anodic aluminum oxide template using a simple sol–gel method. Transmission electron microscopy investigation indicated that the concentration of the structure-directing agent (EO20PO70EO20) had a significant impact on the mesostructure of mesoporous silica nanofibers. Samples with alignment of nanochannels along the axis of mesoporous silica nanofibers could be formed under the P123 concentration of 0.15 mg/mL. When the P123 concentration increased to 0.3 mg/mL, samples with a circular lamellar mesostructure could be obtained. The mechanism for the effect of the P123 concentration on the mesostructure of mesoporous silica nanofibres was proposed and discussed
Paramagnetic limiting of the upper critical field of the layered organic superconductor
We report detailed measurements of the interlayer magnetoresistance of the
layered organic superconductor for temperatures
down to 0.5 K and fields up to 30 tesla. The upper critical field is determined
from the resistive transition for a wide range of temperatures and field
directions. For magnetic fields parallel to the layers, the upper critical
field increases approximately linearly with decreasing temperature. The upper
critical field at low temperatures is compared to the Pauli paramagnetic limit,
at which singlet superconductivity should be destroyed by the Zeeman splitting
of the electron spins. The measured value is comparable to a value for the
paramagnetic limit calculated from thermodynamic quantities but exceeds the
limit calculated from BCS theory. The angular dependence of the upper critical
field shows a cusp-like feature for fields close to the layers, consistent with
decoupled layers.Comment: 16 pages 5 figure
Self-Assembly in Monoelaidin Aqueous Dispersions: Direct Vesicles to Cubosomes Transition
Background: In the present study, synchrotron small-angle X-ray scattering (SAXS) and Cryo-TEM were used to characterize the temperature-induced structural transitions of monoelaidin (ME) aqueous dispersion in the presence of the polymeric stabilizer F127. We prove that the direct transition from vesicles to cubosomes by heating this dispersion is possible. The obtained results were compared with the fully hydrated bulk ME phase. Methodology/principal findings: Our results indicate the formation of ME dispersion, which is less stable than that based on the congener monoolein (MO). In addition, the temperature-dependence behavior significantly differs from the fully hydrated bulk phase. SAXS findings indicate a direct L(alpha)-V(2) internal transition in the dispersion. While the transition temperature is conserved in the dispersion, the formed cubosomes with internal Im3m symmetry clearly contain more water and this ordered interior is retained over a wider temperature range as compared to its fully hydrated bulk system. At 25 degrees C, Cryo-TEM observations reveal the formation of most likely closely packed onion-like vesicles. Above the lamellar to non-lamellar phase transition at 65 degrees C, flattened cubosomes with an internal nanostructure are observed. However, they have only arbitrary shapes and thus, their morphology is significantly different from that of the well-shaped analogous MO cubosome and hexosome particles. Conclusions/significance: Our study reveals a direct liposomes-cubosomes transition in ME dispersion. The obtained results suggest that the polymeric stabilizer F127 especially plays a significant role in the membrane fusion processes. F127 incorporates in considerable amount into the internal nanostructure and leads to the formation of a highly swollen Im3m phase
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