505 research outputs found
Molecular Hydrogen Formation on Low Temperature Surfaces in Temperature Programmed Desorption Experiments
The study of the formation of molecular hydrogen on low temperature surfaces
is of interest both because it allows to explore elementary steps in the
heterogeneous catalysis of a simple molecule and because of the applications in
astrochemistry. Here we report results of experiments of molecular hydrogen
formation on amorphous silicate surfaces using temperature-programmed
desorption (TPD). In these experiments beams of H and D atoms are irradiated on
the surface of an amorphous silicate sample. The desorption rate of HD
molecules is monitored using a mass spectrometer during a subsequent TPD run.
The results are analyzed using rate equations and the activation energies of
the processes leading to molecular hydrogen formation are obtained from the TPD
data. We show that a model based on a single isotope provides the correct
results for the activation energies for diffusion and desorption of H atoms.
These results can thus be used to evaluate the formation rate of H_2 on dust
grains under the actual conditions present in interstellar clouds.Comment: 30 pages, 1 table, 6 figures. Published versio
Formation of molecular hydrogen on analogues of interstellar dust grains: experiments and modelling
Molecular hydrogen has an important role in the early stages of star
formation as well as in the production of many other molecules that have been
detected in the interstellar medium. In this review we show that it is now
possible to study the formation of molecular hydrogen in simulated
astrophysical environments. Since the formation of molecular hydrogen is
believed to take place on dust grains, we show that surface science techniques
such as thermal desorption and time-of-flight can be used to measure the
recombination efficiency, the kinetics of reaction and the dynamics of
desorption. The analysis of the experimental results using rate equations gives
useful insight on the mechanisms of reaction and yields values of parameters
that are used in theoretical models of interstellar cloud chemistry.Comment: 23 pages, 7 figs. Published in the J. Phys.: Conf. Se
Use of Laboratory Data to Model Interstellar Chemistry
Our laboratory research program is about the formation of molecules on dust grains analogues in conditions mimicking interstellar medium environments. Using surface science techniques, in the last ten years we have investigated the formation of molecular hydrogen and other molecules on different types of dust grain analogues. We analyzed the results to extract quantitative information on the processes of molecule formation on and ejection from dust grain analogues. The usefulness of these data lies in the fact that these results have been employed by theoreticians in models of the chemical evolution of ISM environments
Measurement of the Kinetic Energy of Hydrogen Molecules Desorbing from Amorphous Water Ice
A hydrogen molecule that is formed on an interstellar grain might retain some of the 4.48 eV of energy that is released in the recombination reaction of two hydrogen atoms. We set up an experiment to measure the translational (kinetic) energy of hydrogen molecules after they are formed on and are ejected from the surface of an interstellar dust grain analog. Here we report the first measurements of the kinetic energy of molecular deuterium as it leaves the surface of an amorphous water sample. The astrophysical implications of such measurements are discussed
Formation of Molecular Hydrogen on Amorphous Water Ice: Influence of Morphology and Ultraviolet Exposure
In this paper, we report on the formation of molecular hydrogen on different types of amorphous water ice. We show that mass spectra of desorbing molecules upon formation are sensitive to the way in which ice is deposited on a cold substrate, to its thermal history, and to the action of UV photons. Implications that these results bear on H2 formation in dense quiescent clouds are presented and discussed
Scaling of Island Growth in Pb Overlayers on Cu(001)
The growth and ordering of a Pb layer deposited on Cu(001) at 150 K has been
studied using atom beam scattering. At low coverage, ordered Pb islands with a
large square unit cell and nearly hexagonal internal structure are formed. This
is a high order commensurate phase with 30 atoms in the unit cell. From the
measurement of the island diffraction peak profiles we find a power law for the
mean island - size versus coverage with an exponent . A
scaling behavior of growth is confirmed and a simple model describing island
growth is presented. Due to the high degeneracy of the monolayer phase,
different islands do not diffract coherently. Therefore, when islands merge
they still diffract as separate islands and coalescence effects are thus
negligible. From the result for we conclude that the island density is
approximately a constant in the coverage range where the
ordered islands are observed. We thus conclude that most islands nucleate at
and then grow in an approximately self similar fashion as
increases.Comment: 23 pages, 10 Figures (available upon request). SU-PHYS-93-443-375
Effects of Defects on Friction for a Xe Film Sliding on Ag(111)
The effects of a step defect and a random array of point defects (such as
vacancies or substitutional impurities) on the force of friction acting on a
xenon monolayer film as it slides on a silver (111) substrate are studied by
molecular dynamic simulations and compared with the results of lowest order
perturbation theory in the substrate corrugation potential. For the case of a
step, the magnitude and velocity dependence of the friction force are strongly
dependent on the direction of sliding respect to the step and the corrugation
strength. When the applied force F is perpendicular to the step, the film is
pinned forF less than a critical force Fc. Motion of the film along the step,
however, is not pinned. Fluctuations in the sliding velocity in time provide
evidence of both stick-slip motion and thermally activated creep. Simulations
done with a substrate containing a 5 percent concentration of random point
defects for various directions of the applied force show that the film is
pinned for the force below a critical value. The critical force, however, is
still much lower than the effective inertial force exerted on the film by the
oscillations of the substrate in experiments done with a quartz crystal
microbalance (QCM). Lowest order perturbation theory in the substrate potential
is shown to give results consistent with the simulations, and it is used to
give a physical picture of what could be expected for real surfaces which
contain many defects.Comment: 13 pages, 17 figures, latex plus postscript files for figure
Buffer gas cooling and trapping of atoms with small magnetic moments
Buffer gas cooling was extended to trap atoms with small magnetic moment
(mu). For mu greater than or equal to 3mu_B, 1e12 atoms were buffer gas cooled,
trapped, and thermally isolated in ultra high vacuum with roughly unit
efficiency. For mu < 3mu_B, the fraction of atoms remaining after full thermal
isolation was limited by two processes: wind from the rapid removal of the
buffer gas and desorbing helium films. In our current apparatus we trap atoms
with mu greater than or equal to 1.1mu_B, and thermally isolate atoms with mu
greater than or equal to 2mu_B. Extrapolation of our results combined with
simulations of the loss processes indicate that it is possible to trap and
evaporatively cool mu = 1mu_B atoms using buffer gas cooling.Comment: 17 pages, 4 figure
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