Acoustic and thermal transport properties of hard carbon formed from C_60 fullerene

We report on extended investigation of the thermal transport and acoustical properties on hard carbon samples obtained by pressurization of C60 fullerene. Structural investigations performed by different techniques on the same samples indicate a very inhomogeneous structure at different scales, based on fractal-like amorphous clusters on the micrometer to submillimeter scale, which act as strong acoustic scatterers, and scarce microcrystallites on the nanometer scale. Ultrasonic experiments show a rapid increase in the attenuation with frequency, corresponding to a decrease in the localization length for vibrations. The data give evidence for a crossover from extended phonon excitations to localized fracton excitations. The thermal conductivity is characterized by a monotonous increase versus temperature, power law T1.4, for T ranging from 0.1 to 10 K, without any well-defined plateau, and a strictly linear-in-T variation between 20 and 300 K. The latter has to be related to the linear-in-T decrease of the sound velocity between 4 and 100 K, both linear regimes being characteristic of disordered or generally aperiodic structures, which can be analyzed by the “phonon-fracton hopping” model developed for fractal and amorphous structures

Nanosized Sodium-Doped Lanthanum Manganites: Role of the Synthetic Route on their Physical Properties

In this paper we present the results of the synthesis and characterisation of nanocrystalline La1-xNaxMnO3+delta samples. Two synthetic routes were employed: polyacrylamide-based sol-gel and propellant synthesis. Pure, single phase materials were obtained with grain size around 35 nm for the sol-gel samples and around 55 nm for the propellant ones, which moreover present a more broaden grain size distribution. For both series a superparamagnetic behaviour was evidenced by means of magnetisation and EPR measurements with peculiar features ascribable to the different grain sizes and morphology. Preliminary magnetoresistivity measurements show enhanced low-field (< 1 T) magnetoresistance values which suggest an interesting applicative use of these manganites.Comment: 31 Pages 10 Figures to appear in Chem. Mate

Mechanical Activation of Al-Oxyhydroxide Minerals – Physicochemical Changes, Reactivity and Relevance to Bayer Process

Overview of our research on ‘structure and reactivity’ of gibbsite and boehmite under varied conditions of mechanical activation, e.g. milling energy and presence of a second phase is presented. Bulk and surface changes induced in the solids by milling are characterized in terms of morphology, particle size distribution, specific surface area and nature of porosity, crystallite size and zeta potential. Results on enhanced amorphisation of gibbsite in presence of a second phase (quartz, hematite etc), changes in zeta potential of gibbsite due to loss of texture during milling and anomalous decrease in surface area of boehmite during milling are reported. Reactivity of the activated solids in sodium hydroxide and variation in thermal transformation temperatures is correlated with physicochemical characteristics of the samples and plausible explanation for the observed correlations presented. Significance of the results with specific reference to bauxite and alumina processing in Bayer process is highlighted

Covert channel-internal control protocols: attacks and defense

Network covert channels have become a sophisticated means for transferring hidden information over the network. Covert channel-internal control protocols, also called micro protocols, have been introduced in the recent years to enhance capabilities of the network covert channels. Micro protocols are usually placed within the hidden bits of a covert channel's payload and enable features such as reliable data transfer, session management, and dynamic routing for network covert channels. These features provide adaptive and stealthy covert communication channels. Some of the micro protocol based tools exhibit vulnerabilities and are susceptible to attacks. In this paper, we demonstrate some possible attacks on micro protocols, which are capable of breaking the sophisticated covert channel communication or jeopardizing the identity of peers in such a network. These attacks are based on the attacker's interaction with the micro protocol

Role inference + anomaly detection = situational awareness in bacnet networks

In smart buildings, cyber-physical components (e.g., controllers, sensors, and actuators) communicate with each other using network protocols such as BACnet. Many of these devices are now connected to the Internet, enabling attackers to exploit vulnerabilities on protocols and devices to attack buildings. Situational awareness and intrusion detection are thus critical to provide operators with a clear and dynamic picture of their network, and to allow them to react to threats and attacks. Due to Smart Buildings being relatively dynamic and heterogeneous environments, situational awareness further needs to rapidly adapt to the appearance of new devices, and to provide enough context and information to understand a device’s behavior. In this paper, we propose a novel approach to situational awareness that leverages a combination of learning and knowledge of possible role devices. Specifically, we introduce a role-based situational awareness and intrusion detection system to monitor BACnet building automation networks. The system discovers devices, classifies them according to functional roles and detects deviations from the assigned roles. To validate our approach, we use a simulated dataset generated from a BACnet testbed, as well as a real-world dataset coming from the building network of a Dutch university.</p