Uniform semiclassical approximations on a topologically non-trivial configuration space: The hydrogen atom in an electric field

Semiclassical periodic-orbit theory and closed-orbit theory represent a quantum spectrum as a superposition of contributions from individual classical orbits. Close to a bifurcation, these contributions diverge and have to be replaced with a uniform approximation. Its construction requires a normal form that provides a local description of the bifurcation scenario. Usually, the normal form is constructed in flat space. We present an example taken from the hydrogen atom in an electric field where the normal form must be chosen to be defined on a sphere instead of a Euclidean plane. In the example, the necessity to base the normal form on a topologically non-trivial configuration space reveals a subtle interplay between local and global aspects of the phase space structure. We show that a uniform approximation for a bifurcation scenario with non-trivial topology can be constructed using the established uniformization techniques. Semiclassical photo-absorption spectra of the hydrogen atom in an electric field are significantly improved when based on the extended uniform approximations

Photoabsorption spectra of the diamagnetic hydrogen atom in the transition regime to chaos: Closed orbit theory with bifurcating orbits

With increasing energy the diamagnetic hydrogen atom undergoes a transition from regular to chaotic classical dynamics, and the closed orbits pass through various cascades of bifurcations. Closed orbit theory allows for the semiclassical calculation of photoabsorption spectra of the diamagnetic hydrogen atom. However, at the bifurcations the closed orbit contributions diverge. The singularities can be removed with the help of uniform semiclassical approximations which are constructed over a wide energy range for different types of codimension one and two catastrophes. Using the uniform approximations and applying the high-resolution harmonic inversion method we calculate fully resolved semiclassical photoabsorption spectra, i.e., individual eigenenergies and transition matrix elements at laboratory magnetic field strengths, and compare them with the results of exact quantum calculations.Comment: 26 pages, 9 figures, submitted to J. Phys.

Semiclassical quantization of the hydrogen atom in crossed electric and magnetic fields

The S-matrix theory formulation of closed-orbit theory recently proposed by Granger and Greene is extended to atoms in crossed electric and magnetic fields. We then present a semiclassical quantization of the hydrogen atom in crossed fields, which succeeds in resolving individual lines in the spectrum, but is restricted to the strongest lines of each n-manifold. By means of a detailed semiclassical analysis of the quantum spectrum, we demonstrate that it is the abundance of bifurcations of closed orbits that precludes the resolution of finer details. They necessitate the inclusion of uniform semiclassical approximations into the quantization process. Uniform approximations for the generic types of closed-orbit bifurcation are derived, and a general method for including them in a high-resolution semiclassical quantization is devised

The hydrogen atom in an electric field: Closed-orbit theory with bifurcating orbits

Closed-orbit theory provides a general approach to the semiclassical description of photo-absorption spectra of arbitrary atoms in external fields, the simplest of which is the hydrogen atom in an electric field. Yet, despite its apparent simplicity, a semiclassical quantization of this system by means of closed-orbit theory has not been achieved so far. It is the aim of this paper to close that gap. We first present a detailed analytic study of the closed classical orbits and their bifurcations. We then derive a simple form of the uniform semiclassical approximation for the bifurcations that is suitable for an inclusion into a closed-orbit summation. By means of a generalized version of the semiclassical quantization by harmonic inversion, we succeed in calculating high-quality semiclassical spectra for the hydrogen atom in an electric field

Uniform approximations for non-generic bifurcation scenatios including bifurcations of ghost orbits

Gutzwiller's trace formula allows interpreting the density of states of a classically chaotic quantum system in terms of classical periodic orbits. It diverges when periodic orbits undergo bifurcations, and must be replaced with a uniform approximation in the vicinity of the bifurcations. As a characteristic feature, these approximations require the inclusion of complex ``ghost orbits''. By studying an example taken from the Diamagnetic Kepler Problem, viz. the period-quadrupling of the balloon-orbit, we demonstrate that these ghost orbits themselves can undergo bifurcations, giving rise to non-generic complicated bifurcation scenarios. We extend classical normal form theory so as to yield analytic descriptions of both bifurcations of real orbits and ghost orbit bifurcations. We then show how the normal form serves to obtain a uniform approximation taking the ghost orbit bifurcation into account. We find that the ghost bifurcation produces signatures in the semiclassical spectrum in much the same way as a bifurcation of real orbits does.Comment: 56 pages, 21 figure, LaTeX2e using amsmath, amssymb, epsfig, and rotating packages. To be published in Annals of Physic

Symmetry-breaking thermally induced collapse of dipolar Bose-Einstein condensates

We investigate a Bose-Einstein condensate with additional long-range dipolar interaction in a cylindrically symmetric trap within a variational framework. Compared to the ground state of this system, little attention has as yet been payed to its unstable excited states. For thermal excitations, however, the latter is of great interest, because it forms the "activated complex" that mediates the collapse of the condensate. For a certain value of the s-wave scatting length our investigations reveal a bifurcation in the transition state, leading to the emergence of two additional and symmetry-breaking excited states. Because these are of lower energy than their symmetric counterpart, we predict the occurrence of a symmetry-breaking thermally induced collapse of dipolar condensates. We show that its occurrence crucially depends on the trap geometry and calculate the thermal decay rates of the system within leading order transition state theory with the help of a uniform rate formula near the rank-2 saddle which allows to smoothly pass the bifurcation.Comment: 6 pages, 3 figure