Ordered low-temperature structure in K4C60 detected by infrared spectroscopy

Infrared spectra of a K4C60 single-phase thin film have been measured between room temperature and 20 K. At low temperatures, the two high-frequency T1u modes appear as triplets, indicating a static D2h crystal-field stabilized Jahn-Teller distortion of the (C60)4- anions. The T1u(4) mode changes into the known doublet above 250 K, a pattern which could have three origins: a dynamic Jahn-Teller effect, static disorder between "staggered" anions, or a phase transition from an orientationally-ordered phase to one where molecular motion is significant.Comment: 4 pages, 2 figures submitted to Phys. Rev.

Optimized unconventional superconductivity in a molecular Jahn-Teller metal

Understanding the relationship between the superconducting, the neighboring insulating, and the normal metallic state above Tc is a major challenge for all unconventional superconductors. The molecular A3C60 fulleride superconductors have a parent antiferromagnetic insulator in common with the atom-based cuprates, but here, the C603– electronic structure controls the geometry and spin state of the structural building unit via the on-molecule Jahn-Teller effect. We identify the Jahn-Teller metal as a fluctuating microscopically heterogeneous coexistence of both localized Jahn-Teller–active and itinerant electrons that connects the insulating and superconducting states of fullerides. The balance between these molecular and extended lattice features of the electrons at the Fermi level gives a dome-shaped variation of Tc with interfulleride separation, demonstrating molecular electronic structure control of superconductivity

Polar phonons in some compressively stressed epitaxial and polycrystalline SrTiO3 thin films

Several SrTiO3 (STO) thin films without electrodes processed by pulsed laser deposition, of thicknesses down to 40 nm, were studied using infrared transmission and reflection spectroscopy. The complex dielectric responses of polar phonon modes, particularly ferroelectric soft mode, in the films were determined quantitatively. The compressed epitaxial STO films on (100) La0.18Sr0.82Al0.59-Ta0.41O3 substrates (strain 0.9%) show strongly stiffened phonon responses, whereas the soft mode in polycrystalline film on (0001) sapphire substrate shows a strong broadening due to grain boundaries and/or other inhomogeneities and defects. The stiffened soft mode is responsible for a much lower static permittivity in the plane of the compressed film than in the bulk samples.Comment: 11 page

Mott localization in the correlated superconductor Cs3C60 resulting from the molecular Jahn-Teller effect

Cs3C60 is a correlated superconductor under pressure, but an insulator under ambient conditions. The mechanism causing this insulating behavior is the combination of Mott localization and the dynamic Jahn-Teller effect. We show evidence from infrared spectroscopy for the dynamic Jahn-Teller distortion. The continuous change with temperature of the splitting of infrared lines is typical Jahn-Teller behavior, reflecting the change in population of solid-state conformers. We conclude that the electronic and magnetic solid-state properties of the insulating state are controlled by molecular phenomena. We estimate the time scale of the dynamic Jahn-Teller effect to be above 10^(-11) s and the energy difference between the conformers less than 20 cm-1

Measurement of the Far Infrared Magneto-Conductivity Tensor of Superconducting YBa2_2Cu3_3O7−δ_{7-\delta } Thin Films

We report measurements of the far infrared transmission of superconducting YBa$_2$Cu$_3$O$_{7-\delta }$ thin films from 5 cm$^{-1}$ to 200 cm$^{-1}$ in fields up to 14$T$. A Kramers-Kronig analysis of the magneto-transmission spectrum yields the magneto-conductivity tensor. The result shows that the magneto-conductivity of YBa$_2$Cu$_3$O$_{7-\delta }$ is dominated by three terms: a London term, a low frequency Lorentzian ($\omega _1\approx$ 3 cm$^{-1}$) of width $\Gamma _1=$ 10 cm$^{-1}$ and a finite frequency Lorentzian of width $\Gamma _2=$ 17 cm$^{-1}$ at $\omega _2=$ 24 cm$^{-1}$ in the hole cyclotron resonance active mode of circular polarization.\\Comment: Revised LaTex file (12 pages) + 4 Postscript figures, uuencoded. In response to referees' comments, we refined the paper a lot; we encourage you to download this revised versio

Infrared conductivity of a d_{x^2-y^2}-wave superconductor with impurity and spin-fluctuation scattering

Calculations are presented of the in-plane far-infrared conductivity of a d_{x^2-y^2}-wave superconductor, incorporating elastic scattering due to impurities and inelastic scattering due to spin fluctuations. The impurity scattering is modeled by short-range potential scattering with arbitrary phase shift, while scattering due to spin fluctuations is calculated within a weak-coupling Hubbard model picture. The conductivity is characterized by a low-temperature residual Drude feature whose height and weight are controlled by impurity scattering, as well as a broad peak centered at 4 Delta_0 arising from clean-limit inelastic processes. Results are in qualitative agreement with experiment despite missing spectral weight at high energies.Comment: 29 pages (11 tar-compressed-uuencoded Postscript figures), REVTeX 3.0 with epsf macro

Infrared Hall effect in high Tc superconductors: Evidence for non-Fermi liquid Hall scattering

Infrared (20-120 cm-1 and 900-1100 cm-1) Faraday rotation and circular dichroism are measured in high Tc superconductors using sensitive polarization modulation techniques. Optimally doped YBCO thin films are studied at temperatures down to 15 K and magnetic fields up to 8 T. At 1000 cm-1 the Hall conductivity varies strongly with temperature in contrast to the longitudinal conductivity which is nearly independent of temperature. The Hall scattering rate has a T^2 temperature dependence but, unlike a Fermi liquid, depends only weakly on frequency. The experiment puts severe constraints on theories of transport in the normal state of high Tc superconductors.Comment: 8 pages, 3 figure

Gaps and excitations in fullerides with partially filled bands : NMR study of Na2C60 and K4C60

We present an NMR study of Na2C60 and K4C60, two compounds that are related by electron-hole symmetry in the C60 triply degenerate conduction band. In both systems, it is known that NMR spin-lattice relaxation rate (1/T1) measurements detect a gap in the electronic structure, most likely related to singlet-triplet excitations of the Jahn-Teller distorted (JTD) C60^{2-} or C60^{4-}. However, the extended temperature range of the measurements presented here (10 K to 700 K) allows to reveal deviations with respect to this general trend, both at high and low temperatures. Above room temperature, 1/T1 deviates from the activated law that one would expect from the presence of the gap and saturates. In the same temperature range, a lowering of symmetry is detected in Na2C60 by the appearance of quadrupole effects on the 23Na spectra. In K4C60, modifications of the 13C spectra lineshapes also indicate a structural modification. We discuss this high temperature deviation in terms of a coupling between JTD and local symmetry. At low temperatures, 1/T$_1$T tends to a constant value for Na2C60, both for 13C and 23Na NMR. This indicates a residual metallic character, which emphasizes the proximity of metallic and insulting behaviors in alkali fullerides.Comment: 12 pages, 13 figure

Reversible Pressure-Induced Amorphization in Solid C70 : Raman and Photoluminescence Study

We have studied single crystals of $C_{70}$ by Raman scattering and photoluminescence in the pressure range from 0 to 31.1 GPa. The Raman spectrum at 31.1 GPa shows only a broad band similar to that of the amorphous carbon without any trace of the Raman lines of $C_{70}$. After releasing the pressure from 31.1 GPa, the Raman and the photoluminescence spectra of the recovered sample are that of the starting $C_{70}$ crystal. These results indicate that the $C_{70}$ molecules are stable upto 31.1 GPa and the amorphous carbon high pressure phase is reversible, in sharp contrast to the results on solid $C_{60}$. A qualitative explaination is suggested in terms of inter- versus intra-molecular interactions.Comment: To appear in Phys. Rev. Lett., 12 pages, RevTeX (preprint format), 3 figures available upon reques

Mapping of functionalized regions on carbon nanotubes by scanning tunneling microscopy

Scanning tunneling microscopy (STM) gives us the opportunity to map the surface of functionalized carbon nanotubes in an energy resolved manner and with atomic precision. But this potential is largely untapped, mainly due to sample stability issues which inhibit reliable measurements. Here we present a simple and straightforward solution that makes away with this difficulty, by incorporating the functionalized multiwalled carbon nanotubes (MWCNT) into a few layer graphene - nanotube composite. This enabled us to measure energy resolved tunneling conductance maps on the nanotubes, which shed light on the level of doping, charge transfer between tube and functional groups and the dependence of defect creation or functionalization on crystallographic orientation.Comment: Keywords: functionalization, carbon nanotubes, few layer graphene, STM, CITS, ST