Inertial measurement unit pre-processors and post-flight STS-1 comparisons

The flight results show that the relative tri-redundant Inertial Measurement Unit IMU performance throughout the entire entry flight was within the expected accuracy. Comparisons are presented which show differences in the accumulated sensed velocity changes as measured by the tri-redundant IMUs (in Mean Equator and Equinox of 1950.0), differences in the equivalent inertial Euler angles as measured with respect to the M50 system, and finally, preliminary instrument calibrations determined relative to the ensemble average measurement set. Also, differences in the derived body axes rates and accelerations are presented. Because of the excellent performance of the IMUs during the STS-1 entry, the selection as to which particular IMU would best serve as the dynamic data source for entry reconstruction is arbitrary

Estimating the demand for union-led learning in Scotland

The evidence contained here is the first comprehensive and formal statistical analysis of demand for union-led learning in Scotland or the UK. A high degree of consistency of outcome resulted from each of the data sources used. This provides reliable evidence that there is considerable current demand and latent demand for union-led learning in Scotland, and that increased union activity in this area is likely to further stimulate demand. Any expansion of union-led learning would, of course, place additional learning demands on ULRs and would highlight further the need for them to be appropriately supported by unions and employers

Evidence that indirect inhibition of saccade initiation improves saccade accuracy

Saccadic eye-movements to a visual target are less accurate if there are distracters close to its location (local distracters). The addition of more distracters, remote from the target location (remote distracters), invokes an involuntary increase in the response latency of the saccade and attenuates the effect of local distracters on accuracy. This may be due to the target and distracters directly competing (direct route) or to the remote distracters acting to impair the ability to disengage from fixation (indirect route). To distinguish between these we examined the development of saccade competition by recording saccade latency and accuracy responses made to a target and local distracter compared with those made with an addition of a remote distracter. The direct route would predict that the remote distracter impacts on the developing competition between target and local distracter, while the indirect route would predict no change as the accuracy benefit here derives from accessing the same competitive process but at a later stage. We found that the presence of the remote distracter did not change the pattern of accuracy improvement. This suggests that the remote distracter was acting along an indirect route that inhibits disengagement from fixation, slows saccade initiation, and enables more accurate saccades to be made

Scale-up chemical synthesis of thermally-activated delayed fluorescence emitters based on the dibenzothiophene-S,S-dioxide core

We report a procedure to linearly scale-up the synthesis of 2,8-bis(3,6-di-tert-butyl-9H-carbazol-9-yl)dibenzothiophene-S,S-dioxide (compound 4) and 2,8-bis(10H-phenothiazin-10-yl)dibenzothiophene-S,S-dioxide (compound 5) using Buchwald-Hartwig cross-coupling reaction conditions. In addition, we demonstrate a scaled-up synthesis of all non-commercially available starting materials that are required for the amination crosscoupling reaction. In the present article, we provide the detailed synthetic procedures for all of the described compounds, alongside their spectral characterization. This work shows the possibility to produce organic molecules for optoelectronic applications on a large scale, which facilitates their implementation into real world devices

Polythiophene and oligothiophene systems modified by TTF electroactive units for organic electronics

The aim of this review is to give an update on current progress in the synthesis, properties and applications of thiophene-based conjugated systems bearing tetrathiafulvalene (TTF) units. We focus mostly on the synthesis of poly- and oligothiophenes with TTF moieties fused to the thiophene units of the conjugated backbone either directly or via a dithiin ring. The electrochemical behaviour of these materials and structure–property relationships are discussed. The study is directed towards the development of a new type of organic semiconductors based on these hybrid materials for application in organic field effect transistors and solar cells

The evolution of electron density and temperature distributions in the topside ionosphere during magnetic storms

The latitudinal distributions of electron density and temperature during geomagnetic storms in the mid-latitude topside ionosphere are observed to change in a manner than can be related to the evolution of ring current particle populations. The region of auroral precipitation is characterized by correlated increases in electron temperature and density. Equatorwards of this region, there is a broad belt of elevated electron temperatures and depressed electron densities which is usually much broader than any stable auroral red arc distinguishable from the ground, but which is nevertheless the same basic physical phenomenon. The changes of position of this belt can be related to prior bursts of geomagnetic activity and injection of ring current particles into the magnetosphere

Formulation of additional observables for ENTREE

The S-band X and Y angles, SAMS, and TACAN range and bearing were incorporated into the ENTREE software for use by experimenters at LaRC for entry trajectory reconstruction purposes. Background discussions present the need for this added capability. Formulations for the various observables are presented. Both north-south and east-west antenna mounts were provided for in the S-band angle computations. Sub-vehicle terrain height variations are included in the SAMS model. Local magnetic variations were incorporated for the TACAN bearing computations. Observable formulations are discussed in detail along with the partial computations

Shuttle derived atmospheric density model. Part 2: STS atmospheric implications for AOTV trajectory analysis, a proposed GRAM perturbation density model

A perturbation model to the Marshall Space Flight Center (MSFC) Global Reference Atmosphere Model (GRAM) was developed for use in the Aeroassist Orbital Transfer Vehicle (AOTV) trajectory and analysis. The model reflects NASA Space Shuttle experience over the first twelve entry flights. The GRAM was selected over the Air Force 1978 Reference Model because of its more general formulation and wider use throughout NASA. The add-on model, a simple scaling with altitude to reflect density structure encountered by the Shuttle Orbiter was selected principally to simplify implementation. Perturbations, by season, can be utilized to minimize the number of required simulations, however, exact Shuttle flight history can be exercised using the same model if desired. Such a perturbation model, though not meteorologically motivated, enables inclusion of High Resolution Accelerometer Package (HiRAP) results in the thermosphere. Provision is made to incorporate differing perturbations during the AOTV entry and exit phases of the aero-asist maneuver to account for trajectory displacement (geographic) along the ground track

Shuttle derived atmospheric density model. Part 1: Comparisons of the various ambient atmospheric source data with derived parameters from the first twelve STS entry flights, a data package for AOTV atmospheric development

The ambient atmospheric parameter comparisons versus derived values from the first twelve Space Shuttle Orbiter entry flights are presented. Available flights, flight data products, and data sources utilized are reviewed. Comparisons are presented based on remote meteorological measurements as well as two comprehensive models which incorporate latitudinal and seasonal effects. These are the Air Force 1978 Reference Atmosphere and the Marshall Space Flight Center Global Reference Model (GRAM). Atmospheric structure sensible in the Shuttle flight data is shown and discussed. A model for consideration in Aero-assisted Orbital Transfer Vehicle (AOTV) trajectory analysis, proposed to modify the GRAM data to emulate Shuttle experiments

Forecasting environmental migration to the United Kingdom, 2010 - 2060: an exploration using Bayesian models

Over the next fifty years the potential impact on human livelihoods of environmental change could be considerable. One possible response may be increased levels of human mobility. This paper offers a first quantification of the levels of environmental migration to the United Kingdom that might be expected. The authors apply Bijak and Wi?niowski’s (2010) methodology for forecasting migration using Bayesian models. They seek to advance the conceptual understanding of forecasting in three ways. First, the paper is believed to be the first time that the Bayesian modelling approach has been attempted in relation to environmental mobility. Second, the paper examines the plausibility of Bayesian modelling of UK immigration by cross-checking expert responses to a Delphi survey with the expectations about environmental mobility evident in the recent research literature. Third, the values and assumptions of the expert evidence provided in the Delphi survey are interrogated to illustrate the limited set of conditions under which the forecasts of environmental mobility, as set out in this paper, are likely to hold