136 research outputs found
Electronic Structure and Heavy Fermion Behavior in LiV_2O_4
First principles density functional calculations of the electronic and
magnetic properties of spinel-structure LiVO have been performed
using the full potential linearized augmented planewave method. The
calculations show that the electronic structure near the Fermi energy consists
of a manifold of 12 bands derived from V states, weakly hybridized
with O p states. While the total width of this active manifold is approximately
2 eV, it may be roughly decomposed into two groups: high velocity bands and
flatter bands, although these mix in density functional calculations. The flat
bands, which are the more atomic-like lead to a high density of states and
magnetic instability of local moment character. The value of the on-site
exchange energy is sensitive to the exact exchange correlation parameterization
used in the calculations, but is much larger than the interaction between
neighboring spins, reflecting the weak coupling of the magnetic system with the
high velocity bands. A scenario for the observed heavy fermion behavior is
discussed in which conduction electrons in the dispersive bands are weakly
scattered by local moments associated with strongly correlated electrons in the
heavy bands.This is analogous to that in conventional Kondo type heavy
fermions, but is unusual in that both the local moments and conduction
electrons come from the same d-manifold.Comment: 6 Revtex pages, Postscript figs embedded. Revision: figure 4 replaced
with a better version, showing the band character explicitel
Magnetism of PdNi alloys near the critical concentration for ferromagnetism
We report results of a muon spin rotation and relaxation (SR) study of
dilute PdNi alloys, with emphasis on Ni concentrations 0.0243
and 0.025. These are close to the critical value for the onset
of ferromagnetic long-range order (LRO), which is a candidate for a quantum
critical point. The 2.43 and 2.5 at.% Ni alloys exhibit similar SR
properties. Both samples are fully magnetic, with average muon local fields
2.0 and 3.8 mT and Curie temperatures
1.0 and 2.03 K for 2.43 and 2.5 at.% Ni, respectively, at . The
temperature dependence of suggests ordering of
Ni spin clusters rather than isolated spins. Just above a two-phase
region is found with separate volume fractions of quasistatic short-range order
(SRO) and paramagnetism. The SRO fraction decreases to zero with increasing
temperature a few kelvin above . This mixture of SRO and paramagnetism is
consistent with the notion of an inhomogeneous alloy with Ni clustering. The
measured values of extrapolate to = 0.0236 0.0027.
The dynamic muon spin relaxation in the vicinity of differs for the two
samples: a relaxation-rate maximum at is observed for = 0.0243,
reminiscent of critical slowing down, whereas for 0.025 no dynamic
relaxation is observed within the SR time window. The data suggest a
mean-field-like transition in this alloy.Comment: 15 pages, 15 figures, to be published in Phys. Rev.
Staggered Pairing Phenomenology for UPd_2Al_3 and UNi_2Al_3
We apply the staggered-pairing Ginzburg-Landau phenomenology to describe
superconductivity in UPd_2Al_3 and UNi_2Al_3. The phenomenology was applied
successfully to UPt_3 so it explains why these materials have qualitatively
different superconducting phase diagrams although they have the same
point-group symmetry. UPd_2Al_3 and UNi_2Al_3 have a two-component
superconducting order parameter transforming as an H-point irreducible
representation of the space group. Staggered superconductivity can induce
charge-density waves characterized by new Bragg peaks suggesting experimental
tests of the phenomenology.Comment: 4 pages, REVTeX, 2 Postscript figure
Surface critical behavior of bcc binary alloys
The surface critical behavior of bcc binary alloys undergoing a continuous
B2-A2 order-disorder transition is investigated in the mean-field (MF)
approximation. Our main aim is to provide clear evidence for the fact that
surfaces which break the two-sublattice symmetry generically display the
critical behavior of the NORMAL transition, whereas symmetry-preserving
surfaces exhibit ORDINARY surface critical behavior. To this end we analyze the
lattice MF equations for both types of surfaces in terms of nonlinear
symplectic maps and derive a Ginzburg-Landau model for the symmetry-breaking
(100) surface. The crucial feature of the continuum model is the emergence of
an EFFECTIVE ORDERING (``staggered'') SURFACE FIELD, which depends on
temperature and the other lattice model parameters, and which explains the
appearance of NORMAL critical behavior for symmetry-breaking surfaces.Comment: 16 pages, REVTeX 3.0, 13 EPSF figures, submitted to Phys. Rev.
Formation of heavy quasiparticle state in two-band Hubbard model
A realization of heavy fermion state is investigated on the basis of two-band
Hubbard model. By means of the slave-boson mean-field approximation, it is
shown that for the intermediate electron density, n_e=1.5, the inter-band
Coulomb repulsion U strongly emphasizes initially small difference between
bands, and easily stabilizes integral valence in the lower band. As a result, a
strong renormalization takes place in the lower band and the mixing strength
between two bands. It gives rise to a sharp peak at the Fermi level in the
quasiparticle density of states, as that obtained in the periodic Anderson
model. In contrast to a simple insight that the Hund's-rule coupling J reduces
the characteristic energy, it turns out to be almost irrelevant to the
renormalization for J<U. The required conditions are suitable for LiV_2O_4, the
first observed heavy fermion compound in transition metal oxide.Comment: 5 pages, 4 figures, to be published in Phys. Rev.
Spiral spin-liquid and the emergence of a vortex-like state in MnScS
Spirals and helices are common motifs of long-range order in magnetic solids,
and they may also be organized into more complex emergent structures such as
magnetic skyrmions and vortices. A new type of spiral state, the spiral
spin-liquid, in which spins fluctuate collectively as spirals, has recently
been predicted to exist. Here, using neutron scattering techniques, we
experimentally prove the existence of a spiral spin-liquid in MnScS by
directly observing the 'spiral surface' - a continuous surface of spiral
propagation vectors in reciprocal space. We elucidate the multi-step ordering
behavior of the spiral spin-liquid, and discover a vortex-like triple-q phase
on application of a magnetic field. Our results prove the effectiveness of the
- Hamiltonian on the diamond lattice as a model for the spiral
spin-liquid state in MnScS, and also demonstrate a new way to realize a
magnetic vortex lattice.Comment: 10 pages, 11 figure
Orbital state and magnetic properties of LiV_2 O_4
LiV_2 O_4 is one of the most puzzling compounds among transition metal oxides
because of its heavy fermion like behavior at low temperatures. In this paper
we present results for the orbital state and magnetic properties of LiV_2 O_4
obtained from a combination of density functional theory within the local
density approximation and dynamical mean-field theory (DMFT). The DMFT
equations are solved by quantum Monte Carlo simulations. The trigonal crystal
field splits the V 3d orbitals such that the a_{1g} and e_{g}^{pi} orbitals
cross the Fermi level, with the former being slightly lower in energy and
narrower in bandwidth. In this situation, the d-d Coulomb interaction leads to
an almost localization of one electron per V ion in the a_{1g} orbital, while
the e_{g}^{pi} orbitals form relatively broad bands with 1/8 filling. 2The
theoretical high-temperature paramagnetic susceptibility chi(T) follows a
Curie-Weiss law with an effective paramagnetic moment p_{eff}=1.65 in agreement
with the experimental results.Comment: 11 pages, 10 figures, 2 table
Small herbaria contribute unique biogeographic records to county, locality, and temporal scales
With digitization and data sharing initiatives underway over the last 15 years, an important need has been prioritizing specimens to digitize. Because duplicate specimens are shared among herbaria in exchange and gift programs, we investigated the extent to which unique biogeographic data are held in small herbaria vs. these data being redundant with those held by larger institutions. We evaluated the unique specimen contributions that small herbaria make to biogeographic understanding at county, locality, and temporal scales
Spin-fluctuations in the quarter-filled Hubbard ring : significances to LiVO
Using the quantum Monte Carlo method, we investigate the spin dynamics of
itinerant electrons in the one-dimensional Hubbard system. Based on the model
calculation, we have studied the spin-fluctuations in the quarter-filled
metallic Hubbard ring, which is aimed at the vanadium ring or chain defined
along corner-sharing tetrahedra of LiVO, and found the dramatic changes
of magnetic responses and spin-fluctuation characteristics with the
temperature. Such results can explain the central findings in the recent
neutron scattering experiment for LiVO.Comment: 5 pages, 3 figure
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