Point And Line Disclinations In Models Of The Blue Phases

The model of the liquid crystalline blue phases proposed by Alfred Saupe in 1969 is examined in light of the recent, successful theoretical models for these phases. Such an analysis demonstrates that Saupe\u27s model captures all of the important features of the recent models, differing only in the density of line disclinations. The fact that Saupe proposed this model over ten years before the more recent work and without the benefit of a significant amout of new experimental evidence is testimony for his keen physical insight. Such models continue to be useful as researchers direct their attention to the less understood third blue phase and the transition between it and the isotropic phase

Order Parameter Measurements Of Dichroic Dyes Dissolved In Smectic Liquid Crystals That Tilt Without Layer Contraction

Measurements of the orientational order parameter of dissolved dichroic dyes are reported for two smectic-A liquid crystals that tilt in the presence of an in-plane electric field without any decrease in the layer spacing. The dye order parameter is determined by measuring the anisotropic absorption of linearly polarized light. Different dyes are used and measurements are also performed on a smectic liquid crystal that tilts with the expected layer contraction to check how closely the measurements reflect the order parameter of the liquid crystal. The variation of the dye order parameter with electric field is in accordance with the recently proposed model of azimuthal disorder of the tilt angle direction, but the surprising finding is that the local dye orientational order parameter is significantly lower than for the smectic liquid crystal that tilts with the expected layer contraction. This suggests that another mechanism might be contributing significantly to the smectic order, one possibility of which is the tendency for different parts of these siloxane-containing molecules to segregate within each layer. Another possible explanation is that the azimuthal disorder is due to a modulated phase with a high enough density of defects to decrease the value of the local order parameter

Phase Diagrams For The Blue Phases Of Highly Chiral Liquid Crystals

Polarizing microscopy and optical-activity measurements are used to determine the phase diagram for the blue phases of chiral-racemic mixtures of terephthaloyloxy-bis-4-(2\u27-methylbutyl) benzoate. Contrary to an earlier report, it is the second blue phase (BP II) rather than the first blue phase (BP 1) that is not stable relative to the other blue phases at high chirality. With this development, all phase diagrams for the blue phases reported to date have the same topology. Using similar data for two other highly chiral systems, it is found that a simple scaling of the temperature and chiral-fraction axes produces phase diagrams in quantitative agreement with the present results. Thus, in spite of differences in molecular structure, the number of chiral centers, and phase-transition temperatures, these three systems possess remarkably similar phase diagrams and lend evidence for a universal phase diagram for the blue phases

Supercritical Conversion Of The 3rd Blue Phase To The Isotropic-Phase In A Highly Chiral Liquid-Crystal

The results of two independent experiments in the vicinity of the “transition” from the third blue phase ( BPIII) to isotropic phase ( I) are reported for a highly chiral liquid crystal. Heat capacity measurements using a high-resolution calorimeter and dynamic light-scattering measurements using circularly polarized light have been performed. The data show a continuous evolution of BPIII into I with no critical fluctuations. This is strong evidence that the BPIII-I transition in this compound is supercritical, indicating that the BPIII and I phases possess the same macroscopic symmetry