12,536 research outputs found
Orbital-Peierls State in NaTiSi2O6
Does the quasi one-dimensional titanium pyroxene NaTiSi2O6 exhibit the novel
{\it orbital-Peierls} state? We calculate its groundstate properties by three
methods: Monte Carlo simulations, a spin-orbital decoupling scheme and a
mapping onto a classical model. The results show univocally that for the spin
and orbital ordering to occur at the same temperature --an experimental
observation-- the crystal field needs to be small and the orbitals are active.
We also find that quantum fluctuations in the spin-orbital sector drive the
transition, explaining why canonical bandstructure methods fail to find it. The
conclusion that NaTiSi2O6 shows an orbital-Peierls transition is therefore
inevitable.Comment: 4 pages, 3 figure
Determining the Electron-Phonon Coupling Strength in Correlated Electron Systems from Resonant Inelastic X-ray Scattering
We show that high resolution Resonant Inelastic X-ray Scattering (RIXS)
provides direct, element-specific and momentum-resolved information on the
electron-phonon (e-p) coupling strength. Our theoretical analysis demonstrates
that the e-p coupling can be extracted from RIXS spectra by determining the
differential phonon scattering cross section. An alternative, very direct
manner to extract the coupling is to use the one and two-phonon loss ratio,
which is governed by the e-p coupling strength and the core-hole life-time.
This allows measurement of the e-p coupling on an absolute energy scale.Comment: 4 pages, 3 figure
The essay film.
This thesis on the essay film is written from the film maker's point of view, following the production of the film The Man Who Couldn't Feel and Other Tales, (54 min, 16mm). The film and the thesis together form the PhD submission. Examination of the completed film led to the definition of the essay film as an avantgarde, non-fiction film genre. The thesis rejects the current positioning of the essay film as a part of the documentary genre. The essay film creates an aesthetic coherence through the use of image and sound fragments, narrative and nonnarrative structures, 'methodically unmethodically' edited together. The essay film follows Vertov's and Astruc's steps in 'writing' fragments as they occur to the film maker, which are in turn put together using the editing traditions of the film avantgarde and modernist poetry. The film maker's presence in the essay film results in the cinematic 'text' becoming the 'reflective text' - the mediating medium between the film maker and the spectator. Beside its avant-garde roots, the genre owes much to the literary essay tradition established since Michel de Montaigne. Many of the literary essay's aesthetic, thematic and structural elements are to be found in the essay film genre. Each and every essay film is unique in its structure, and the genre as a whole does not conform to a pre-determined cinematic construction. Nevertheless, the thesis charts some useful characteristics and definitions for the establishment of an independent essay film genre
KCrF_3: Electronic Structure, Magnetic and Orbital Ordering from First Principles
The electronic, magnetic and orbital structures of KCrF_3 are determined in
all its recently identified crystallographic phases (cubic, tetragonal, and
monoclinic) with a set of {\it ab initio} LSDA and LSDA+U calculations. The
high-temperature undistorted cubic phase is metallic within the LSDA, but at
the LSDA+U level it is a Mott insulator with a gap of 1.72 eV. The tetragonal
and monoclinic phases of KCrF_3 exhibit cooperative Jahn-Teller distortions
concomitant with staggered 3x^2-r^2/3y^2-r^2 orbital order. We find that the
energy gain due to the Jahn-Teller distortion is 82/104 meV per chromium ion in
the tetragonal/monoclinic phase, respectively. These phases show A-type
magnetic ordering and have a bandgap of 2.48 eV. In this Mott insulating state
KCrF_3 has a substantial conduction bandwidth of 2.1 eV, leading to the
possibility for the kinetic energy of charge carriers in electron- or
hole-doped derivatives of KCrF_3 to overcome the polaron localization at low
temperatures, in analogy with the situation encountered in the colossal
magnetoresistive manganites.Comment: 7 pages, 11 figure
Non conventional screening of the Coulomb interaction in low dimensional and finite size system
We study the screening of the Coulomb interaction in non polar systems by
polarizable atoms. We show that in low dimensions and small finite size systems
this screening deviates strongly from that conventionally assumed. In fact in
one dimension the short range interaction is strongly screened and the long
range interaction is anti-screened thereby strongly reducing the gradient of
the Coulomb interaction and therefore the correlation effects. We argue that
this effect explains the success of mean field single particle theories for
large molecules.Comment: 4 pages, 5 figure
Optical conductivity in A3C60 (A=K, Rb)
We study the optical conductivity in A3C60 (A =K, Rb). The effects of the
electron-phonon interaction is included to lowest order in the coupling
strength lambda. It is shown that this leads to a narrowing of the Drude peak
by a factor 1+lambda and a transfer of weight to a mid-infrared peak at
somewhat larger energies than the phonon energy. Although this goes in the
right direction, it is not sufficient to describe experiment.Comment: 5 pages, revtex, 2 figures more information at
http://librix.mpi-stuttgart.mpg.de/docs/ANDERSEN/fullerene
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