From Ark to Art : The 20-year Journey of the Civic, Cleveland Heights, Ohio, from Jewish Temple to Multi-purpose Community Facility

The Civic is a former Jewish temple located in Cleveland Heights, Ohio, an inner-ring suburb of Cleveland, Ohio. The building was close to being abandoned and possibly torn down after its former congregation built a new facility farther out in the suburbs. This study describes how a former temple came to serve the community in a new and different way in the secular world. This study will chronicle the Civic as a historical building; describe the efforts to remake it into a multi-purpose building that is a community asset; and serve as a model to other communities interested in adapting houses of worship to secular purposes. While other government regulations, the basic tools are the same everywhere. there are differences between states in terms of the details of this kind of preservation work, such as tax codes and to provide the capital necessary to perform the retrofit. People responsible for the stewardship of older buildings that must be extensively retrofitted, as the Civic was, find it almost impossible to generate enough revenue to both sustain the operations of the building.https://engagedscholarship.csuohio.edu/clevmembks/1002/thumbnail.jp

From Ark to Art : The 20-year Journey of the Civic, Cleveland Heights, Ohio, from Jewish Temple to Multi-purpose Community Facility

The Civic is a former Jewish temple located in Cleveland Heights, Ohio, an inner-ring suburb of Cleveland, Ohio. The building was close to being abandoned and possibly torn down after its former congregation built a new facility farther out in the suburbs. This study describes how a former temple came to serve the community in a new and different way in the secular world. This study will chronicle the Civic as a historical building; describe the efforts to remake it into a multi-purpose building that is a community asset; and serve as a model to other communities interested in adapting houses of worship to secular purposes. While other government regulations, the basic tools are the same everywhere. there are differences between states in terms of the details of this kind of preservation work, such as tax codes and to provide the capital necessary to perform the retrofit. People responsible for the stewardship of older buildings that must be extensively retrofitted, as the Civic was, find it almost impossible to generate enough revenue to both sustain the operations of the building. Original publication date 2000.https://engagedscholarship.csuohio.edu/clevmembks/1002/thumbnail.jp

The Phosphorus Puzzle: Why Metal Phosphites Could Be the Missing Piece

It is well understood that phosphorylation of organic molecules is a keystone mechanism toward developing early cell function. However, the source of phosphorous in prebiotic chemistry is under debate. Phosphate minerals were abundant on the early Earth, but they are highly insoluble. In comparison, metal phosphites are significantly more soluble. While they may not have been preserved in the geological record, there are several plausible pathways for their formation under prebiotic conditions. We hypothesize that metal phosphites were a major source of phosphorus. To test our hypothesis, we synthesized and characterized metal phosphites, containing the most abundant cations on the early Earth (Mg2+, Ca2+, Fe2+, Fe3+). Then we reacted the metal phosphites with glycerol or propanol and looked for phosphonylated organic molecules. (n.b., Phosphonylated molecules contain a phosphite (PO33-), and phosphorylated molecules contain a phosphate (PO43-).) In nuclear magnetic resonance (NMR) experiments, we observe the formation of glycerol-a-phosphite and glycerol-b-phosphite when CaHPO3 and glycerol react at 60oC. Experiments investigating the reactivity of iron (II or III) phosphite and magnesium phosphite are ongoing

Trace Complexity of Chaotic Reversible Cellular Automata

Delvenne, K\r{u}rka and Blondel have defined new notions of computational complexity for arbitrary symbolic systems, and shown examples of effective systems that are computationally universal in this sense. The notion is defined in terms of the trace function of the system, and aims to capture its dynamics. We present a Devaney-chaotic reversible cellular automaton that is universal in their sense, answering a question that they explicitly left open. We also discuss some implications and limitations of the construction.Comment: 12 pages + 1 page appendix, 4 figures. Accepted to Reversible Computation 2014 (proceedings published by Springer

New Constraint on Open Cold-Dark-Matter Models

We calculate the large-angle cross-correlation between the cosmic-microwave-background (CMB) temperature and the x-ray-background (XRB) intensity expected in an open Universe with cold dark matter (CDM) and a nearly scale-invariant spectrum of adiabatic density perturbations. Results are presented as a function of the nonrelativistic-matter density $\Omega_0$ (in units of the critical density) and the x-ray bias $b_x$ (evaluated at a redshift $z\simeq1$ in evolving-bias models) for both an open Universe and a flat cosmological-constant Universe. Recent experimental upper limits to the amplitude of this cross-correlation provide a new constraint to the $\Omega_0$-$b_x$ parameter space that open-CDM models (and the open-inflation models that produce them) must satisfy.Comment: 4 pages, LaTeX. Revised version contains additional figure that clarifies new constraint. (To appear in PRL.

First direct measurements of formaldehyde flux via eddy covariance: implications for missing in-canopy formaldehyde sources

We report the first observations of formaldehyde (HCHO) flux measured via eddy covariance, as well as HCHO concentrations and gradients, as observed by the Madison Fiber Laser-Induced Fluorescence Instrument during the BEACHON-ROCS 2010 campaign in a rural, Ponderosa Pine forest northwest of Colorado Springs, CO. A median noon upward flux of ~80 μg m<sup>−2</sup> h<sup>−1</sup> (~24 ppt<sub>v</sub> m s<sup>−1</sup>) was observed with a noon range of 37 to 131 μg m<sup>−2</sup> h<sup>−1</sup>. Enclosure experiments were performed to determine the HCHO branch (3.5 μg m<sup>-2</sup> h<sup>−1</sup>) and soil (7.3 μg m<sup>−2</sup> h<sup>−1</sup>) direct emission rates in the canopy. A zero-dimensional canopy box model, used to determine the apportionment of HCHO source and sink contributions to the flux, underpredicted the observed HCHO flux by a factor of 6. Simulated increases in concentrations of species similar to monoterpenes resulted in poor agreement with measurements, while simulated increases in direct HCHO emissions and/or concentrations of species similar to 2-methyl-3-buten-2-ol best improved model/measurement agreement. Given the typical diurnal variability of these BVOC emissions and direct HCHO emissions, this suggests that the source of the missing flux is a process with both a strong temperature and radiation dependence

On the cosmic ray bound for models of extragalactic neutrino production

We obtain the maximum diffuse neutrino intensity predicted by hadronic photoproduction models of the type which have been applied to the jets of active galactic nuclei or gamma ray bursts. For this, we compare the proton and gamma ray fluxes associated with hadronic photoproduction in extragalactic neutrino sources with the present experimental upper limit on cosmic ray protons and the extragalactic gamma ray background, employing a transport calculation of energetic protons traversing cosmic photon backgrounds. We take into account the effects of the photon spectral shape in the sources on the photoproduction process, cosmological source evolution, the optical depth for cosmic ray ejection, and discuss the possible effects of magnetic fields in the vicinity of the sources. For photohadronic neutrino sources which are optically thin to the emission of neutrons we find that the cosmic ray flux imposes a stronger bound than the extragalactic gamma ray background in the energy range between 10^5 GeV and 10^11 GeV, as previously noted by Waxman & Bahcall (1999). We also determine the maximum contribution from the jets of active galactic nuclei, using constraints set to their neutron opacity by gamma-ray observations. This present upper limit is consistent with the jets of active galactic nuclei producing the extragalactic gamma ray background hadronically, but we point out future observations in the GeV-to-TeV regime could lower this limit. We also briefly discuss the contribution of gamma ray bursts to ultra-high energy cosmic rays as it can be inferred from possible observations or limits on their correlated neutrino fluxes.Comment: 16 pages, includes 7 figures, using REVtex3.1, accepted for publication in Phys.Rev.D after minor revision

Mitochondrial Hâ‚‚Oâ‚‚ emission and cellular redox state link excess fat intake to insulin resistance in both rodents and humans

High dietary fat intake leads to insulin resistance in skeletal muscle, and this represents a major risk factor for type 2 diabetes and cardiovascular disease. Mitochondrial dysfunction and oxidative stress have been implicated in the disease process, but the underlying mechanisms are still unknown. Here we show that in skeletal muscle of both rodents and humans, a diet high in fat increases the Hâ‚‚Oâ‚‚-emitting potential of mitochondria, shifts the cellular redox environment to a more oxidized state, and decreases the redox-buffering capacity in the absence of any change in mitochondrial respiratory function. Furthermore, we show that attenuating mitochondrial Hâ‚‚Oâ‚‚ emission, either by treating rats with a mitochondrial-targeted antioxidant or by genetically engineering the overexpression of catalase in mitochondria of muscle in mice, completely preserves insulin sensitivity despite a high-fat diet. These findings place the etiology of insulin resistance in the context of mitochondrial bioenergetics by demonstrating that mitochondrial Hâ‚‚Oâ‚‚ emission serves as both a gauge of energy balance and a regulator of cellular redox environment, linking intracellular metabolic balance to the control of insulin sensitivity. Original version available at http://www.jci.org/articles/view/3704

CSI: Dognapping workshop : an outreach experiment designed to produce students that are hooked on science.

The CSI: Dognapping Workshop is a culmination of the more than 65 Sandian staff and intern volunteers dedication to exciting and encouraging the next generation of scientific leaders. This 2 hour workshop used a 'theatrical play' and 'hands on' activities that was fun, exciting and challenging for 3rd-5th graders while meeting science curriculum standards. In addition, new pedagogical methods were developed in order to introduce nanotechnology to the public. Survey analysis indicated that the workshop had an overall improvement and positive impact on helping the students to understand concepts from materials science and chemistry as well as increased our interaction with the K-5 community. Anecdotal analyses showed that this simple exercise will have far reaching impact with the results necessary to maintain the United States as the scientific leader in the world. This experience led to the initiation of over 100 Official Junior Scientists

Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry

We present simultaneous fast, in-situ measurements of formaldehyde and glyoxal from two rural campaigns, BEARPEX 2009 and BEACHON-ROCS, both located in Pinus Ponderosa forests with emissions dominated by biogenic volatile organic compounds (VOCs). Despite considerable variability in the formaldehyde and glyoxal concentrations, the ratio of glyoxal to formaldehyde, R<sub>GF</sub>, displayed a very regular diurnal cycle over nearly 2 weeks of measurements. The only deviations in R<sub>GF</sub> were toward higher values and were the result of a biomass burning event during BEARPEX 2009 and very fresh anthropogenic influence during BEACHON-ROCS. Other rapid changes in glyoxal and formaldehyde concentrations have hardly any affect on R<sub>GF</sub> and could reflect transitions between low and high NO regimes. The trend of increased R<sub>GF</sub> from both anthropogenic reactive VOC mixtures and biomass burning compared to biogenic reactive VOC mixtures is robust due to the short timescales over which the observed changes in R<sub>GF</sub> occurred. Satellite retrievals, which suggest higher R<sub>GF</sub> for biogenic areas, are in contrast to our observed trends. It remains important to address this discrepancy, especially in view of the importance of satellite retrievals and in situ measurements for model comparison. In addition, we propose that R<sub>GF</sub> represents a useful metric for biogenic or anthropogenic reactive VOC mixtures and, in combination with absolute concentrations of glyoxal and formaldehyde, furthermore represents a useful metric for the extent of anthropogenic influence on overall reactive VOC processing via NO<sub>x</sub>. In particular, R<sub>GF</sub> yields information about not simply the VOCs dominating reactivity in an airmass, but the VOC processing itself that is directly coupled to ozone and secondary organic aerosol production