Fiber Optic Detection of Ammonia Gas

Bathochromic shifts accompanying the formation of several bivalent metallic complexes containing 5-(4’-dimethylaminophenylimino) quinolin-8-one (L1), and 7-chlore-5(4’-diethylamino-2-methylphenylimino) quinolin-8-one (L2) ligands in ethanol solutions were evaluated by VIS-NIR spectroscopy. The [L1-Cu-L1] sulphide complex was selected as a reagent for further tests on optical fibres. Samples of multimode siloxane-clad fused-silica fibre were sensitized by diffusing an ethanol/chloroform solution of the dye into the cladding polymer, and tested by VIS-NIR optical spectroscopy (12 cm long fibre sections), and optical time domain reflectometry (OTDR; 20 ns laser pulses, wavelength 850 nm, 120 m long fibre sensitized within the interval 104–110 m). A well-resolved absorption band of the reagent could be identified in the absorption spectra of the fibres. After exposure to dry ammonia/nitrogen gas with increasing ammonia concentration (0–4000 ppm), the short fibre samples showed subsequent decay of NIR optical absorption; saturation was observed for higher ammonia levels. The concentration resolution r ? 50 ppm and forward response time t90 ? 30 sec were obtained within the interval 0–1000 ppm. The OTDR courses showed an enhancement of the back-scattered light intensity coming from the sensitized region after diffusion of the initial reagent, and decay after exposure to concentrated ammonia/nitrogen gas (10000 ppm)

Modelling of Radiative Transfer in Air Arc Plasma

The objective of this work is to compare the accuracy of several approximate models of radiative properties for the prediction of radiative transfer in air arc plasma at the temperatures in the range of 300 - 25 000 K and the pressure of 0.1 MPa. Calculated absorption coefficients are used to generate the parameters of different models. The radiative transfer inside the cylindrically symmetrical air plasma with prescribed temperature profile was studied. The equation of radiative transfer was solved using the P1 and SP3 approximations, calculated radiative source term in the energy equation (net emission) was compared with results obtained by spectral integration

Discrete breathers in nonlinear lattices: Experimental detection in a Josephson array

We present an experimental study of discrete breathers in an underdamped Josephson-junction array. Breathers exist under a range of dc current biases and temperatures, and are detected by measuring dc voltages. We find the maximum allowable bias current for the breather is proportional to the array depinning current while the minimum current seems to be related to a junction retrapping mechanism. We have observed that this latter instability leads to the formation of multi-site breather states in the array. We have also studied the domain of existence of the breather at different values of the array parameters by varying the temperature.Comment: 5 pages, 5 figures, submitted to Physical Revie

Enhancing spatial accuracy of mobile phone data using multi-temporal dasymetric interpolation

Novel digital data sources allow us to attain enhanced knowledge about locations and mobilities of people in space and time. Already a fast-growing body of literature demonstrates the applicability and feasibility of mobile phone-based data in social sciences for considering mobile devices as proxies for people. However, the implementation of such data imposes many theoretical and methodological challenges. One major issue is the uneven spatial resolution of mobile phone data due to the spatial configuration of mobile network base stations and its spatial interpolation. To date, different interpolation techniques are applied to transform mobile phone data into other spatial divisions. However, these do not consider the temporality and societal context that shapes the human presence and mobility in space and time. The paper aims, first, to contribute to mobile phone-based research by addressing the need to give more attention to the spatial interpolation of given data, and further by proposing a dasymetric interpolation approach to enhance the spatial accuracy of mobile phone data. Second, it contributes to population modelling research by combining spatial, temporal and volumetric dasymetric mapping and integrating it with mobile phone data. In doing so, the paper presents a generic conceptual framework of a multi-temporal function-based dasymetric (MFD) interpolation method for mobile phone data. Empirical results demonstrate how the proposed interpolation method can improve the spatial accuracy of both night-time and daytime population distributions derived from different mobile phone data sets by taking advantage of ancillary data sources. The proposed interpolation method can be applied for both location- and person-based research, and is a fruitful starting point for improving the spatial interpolation methods for mobile phone data. We share the implementation of our method in GitHub as open access Python code.Peer reviewe

PES fabric modification with a corona discharge

Paper presents results of experiments with polyethylene terephtalate (PET) focused on the applicability of atmospheric corona discharge for polyester fabric (PES) modification, mainly on the relation between corona discharge input power and the fabric’s hydrophobicity and modification efficiency. Modification effect strongly grew according to the discharge input power, but the growth was limited by the corona discharge conversion into the spark discharge. Modification effect aging expressed in the feathering spot size time changes sharply diminished in time. Results of corona discharge modification were compared with those of the RF discharge modificationВ роботі подаються результати експериментів з поліетилен-терфталатом (РЕТ), метою яких було виявлення можливості вживання атмосферного коронного розряду для модифікації поліефірного матеріалів (PES), головним чином, залежності гідрофобності матеріалів та ефективності їх модифікації від споживаної потужності коронного розряду. Ефект модифікації помітно зростав з споживаною потужністю, проте цей зріст обмежувався переходом коронного розряду в іскровий. Результати модифікації коронним розрядом порівнюються з результатами, які були одержані з застосуванням ВЧ розряду.В работе представлены результаты экспериментов с полиэтилен-терфталатом (РЕТ), целью которых было выяснение возможности применения атмосферного коронного разряда для модификации полиэфирного материалов (PES), главным образом, зависимости гидрофобности материалов и эффективности их модификации от потребляемой мощности коронного разряда. Эффект модификации заметно возрастал с потребляемой мощностью, но это возрастание ограничивалось переходом коронного разряда в искровой разряд. Результаты модификации коронным разрядом сравниваются с результатами, полученными при использовании ВЧ разряда

Consistency tests of AMPCALCULATOR and chiral amplitudes in SU(3) Chiral Perturbation Theory: A tutorial based approach

Ampcalculator is a Mathematica based program that was made publicly available some time ago by Unterdorfer and Ecker. It enables the user to compute several processes at one-loop (upto $O(p^4)$) in SU(3) chiral perturbation theory. They include computing matrix elements and form factors for strong and non-leptonic weak processes with at most six external states. It was used to compute some novel processes and was tested against well-known results by the original authors. Here we present the results of several thorough checks of the package. Exhaustive checks performed by the original authors are not publicly available, and hence the present effort. Some new results are obtained from the software especially in the kaon odd-intrinsic parity non-leptonic decay sector involving the coupling $G_{27}$. Another illustrative set of amplitudes at tree level we provide is in the context of $\tau$-decays with several mesons including quark mass effects, of use to the BELLE experiment. All eight meson-meson scattering amplitudes have been checked. Kaon-Compton amplitude has been checked and a minor error in published results has been pointed out. This exercise is a tutorial based one, wherein several input and output notebooks are also being made available as ancillary files on the arXiv. Some of the additional notebooks we provide contain explicit expressions that we have used for comparison with established results. The purpose is to encourage users to apply the software to suit their specific needs. An automatic amplitude generator of this type can provide error-free outputs that could be used as inputs for further simplification, and used in varied scenarios such as applications of chiral perturbation theory at finite temperature, density and volume. This can also be used by students as a learning aid in low-energy hadron dynamics.Comment: 25 pages, plain latex, corresponds to version to appear in EPJA, additional ancillary files adde