64 research outputs found

    4d-inner-shell ionization of Xe+ ions and subsequent Auger decay

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    We have studied Xe+4d inner-shell photoionization in a direct experiment on Xe+ ions, merging an ion and a photon beam and detecting the ejected electrons with a cylindrical mirror analyzer. The measured 4d photoelectron spectrum is compared to the 4d core valence double ionization spectrum of the neutral Xe atom, obtained with a magnetic bottle spectrometer. This multicoincidence experiment gives access to the spectroscopy of the individual Xe2+4d−15p−1 states and to their respective Auger decays, which are found to present a strong selectivity. The experimental results are interpreted with the help of ab initio calculations.1\. Auflag

    Auger shake-up assisted electron recapture

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    The presence of doubly excited states (DESs) above the core-hole ionization threshold nontrivially modulates the x-ray absorption because the participator Auger decay couples DESs to the underlying low-energy core-hole continuum. We show that coupling also affects the high-energy continuum populated by the spectator Auger decay of DESs. For the K−L223 Auger decay of the 1s−13p−14s21P state in argon, the competing nonresonant path is assigned to the recapture of the 1s photoelectron caused by emission of the fast electron from the shake-up K−L223 decay of the 1s−1 ion

    Radiometric Analysis of Silver Iodide Sols

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    With the ultimate goal to investigate (a) the formation of the solid phase by precipitation from electrolytic solutions, and (b) processes characteristic of the interaction between the solid phase and the electrolytic solution, the well-known radiometric methods of analyses have been applied, as well as new radiometric methods for the analysis of colloidal system developed. The methods applied are extremely sensitive, selective, and accurate. The new methods have been checked up by comparison of the obtained results with the standard classical methods, such as X-ray diffraction, turbidimetry, conductometry, differential thermic analysis, and also by published data

    The effect of photoemission on nanosecond helium microdischarges at atmospheric pressure

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    Atmospheric-pressure microdischarges excited by nanosecond high-voltage pulses are investigated in helium-nitrogen mixtures by first-principles particle-based simulations, which include VUV resonance radiation transport via the tracing of photon trajectories. The VUV photons, of which the frequency redistribution in the emission processes is included in some detail, are found to modify the computed discharge characteristics remarkably, due to their ability to induce electron emission from the cathode surface. Electrons created this way enhance the plasma density, and a significant increase of the transient current pulse amplitude is observed. The simulations allow the computation of the density of helium atoms in the 21P resonant state, as well as the density of photons in the plasma and the line shape of the resonant VUV radiation reaching the electrodes. These indicate the presence of significant radiation trapping in the plasma and photon escape times longer than the duration of the excitation pulses are found
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