Nuclear Magnetic Resonance Imaging of Li-ion Battery

Nuclear magnetic resonance (NMR) imaging has high sensitivity to proton (1H) and lithium (7Li). It is a useful measurement for electrolyte in Li-ion battery. 1H NMR images of lithium ion battery which is composed of LiMn2O4 / LiClO4 + propylene carbonate (PC) / Li-metal have been studied. 1H NMR images of electrolyte near cathode material (LiMn2O4) showed anomalous intensity distribution, which was quite inhomogeneous. From NMR images as a function of repetition time (TR), it was concluded that the anomalous intensity distribution was not due to change of relaxation time but an indirect (spatial) para-magnetization effect from cathode material. The paramagnetization induced by high magnetic field distorts linearity of magnetic gradient field, leading to apparent intensity variance. This functional image is an easy diagnostic measurement for magnetization of cathode material, which allows the possibility to check uniformity of cathode material and change of magnetization under electrochemical process. Received: 7 October 2010; Revised: 1 December 2010; Accepted: 17 December 201

Nuclear Magnetic Resonance Imaging of Li-ion Battery

Nuclear magnetic resonance (NMR) imaging has high sensitivity to proton (1H) and lithium (7Li). It is a useful measurement for electrolyte in Li-ion battery. 1H NMR images of lithium ion battery which is composed of LiMn2O4 / LiClO4 + propylene carbonate (PC) / Li-metal have been studied. 1H NMR images of electrolyte near cathode material (LiMn2O4) showed anomalous intensity distribution, which was quite inhomogeneous. From NMR images as a function of repetition time (TR), it was concluded that the anomalous intensity distribution was not due to change of relaxation time but an indirect (spatial) para-magnetization effect from cathode material. The paramagnetization induced by high magnetic field distorts linearity of magnetic gradient field, leading to apparent intensity variance. This functional image is an easy diagnostic measurement for magnetization of cathode material, which allows the possibility to check uniformity of cathode material and change of magnetization under electrochemical process. Received: 7 October 2010; Revised: 1 December 2010; Accepted: 17 December 201

Chemiluminescence emission in cholesteric liquid crystalline core-shell microcapsules

Chemiluminescence behaviour in the core region of water/oil/water double emulsion droplets with cholesteric liquid crystalline (CLC) middle phase (CLC core-shell microcapsules) was demonstrated. We successfully fabricated CLC core-shell microcapsules containing an aqueous luminol solution as the inner phase using a microfluidic device, in which the helical axis of the CLC phase is normal to the surface. The CLC core-shell microcapsules proved to be a plausible candidate for highly sensitive H₂O₂ sensors because of the omnidirectional photonic structures of the CLC phase.Iwai Y., Kaji H., Uchida Y., et al. Chemiluminescence emission in cholesteric liquid crystalline core-shell microcapsules. Journal of Materials Chemistry C 2, 4904 (2014); https://doi.org/10.1039/c4tc00699b

Ultrafast Photoinduced Formation of Metallic State in a Perovskite-type Manganite with Short Range Charge and Orbital Order

Femtosecond reflection spectroscopy was performed on a perovskite-type manganite, Gd0.55Sr0.45MnO3, with the short-range charge and orbital order (CO/OO). Immediately after the photoirradiation, a large increase of the reflectivity was detected in the mid-infrared region. The optical conductivity spectrum under photoirradiation obtained from the Kramers-Kronig analyses of the reflectivity changes demonstrates a formation of a metallic state. This suggests that ferromagnetic spin arrangements occur within the time resolution (ca. 200 fs) through the double exchange interaction, resulting in an ultrafast CO/OO to FM switching.Comment: 4 figure

Detection and Localization of Periodontopathic Bacteria in Abdominal Aortic Aneurysms

AbstractObjectivesWe examined a possible link between periodontal disease and abdominal aortic aneurysm (AAA) by studying resected aneurysmal specimens from AAA patients for the presence of periodontitopathic bacteria.DesignProspective case control study.Material and methodsThirty-two AAA patients were enrolled in the study. Periodontitis was classified according to the probing depth of preriodontal pocket. Thirty-two aneurysmal walls, 16 mural thrombi, 5 atherosclerotic occlusive aorta and 5 control arterial tissue, were examined for 7 periodontal bacteria using polymerase chain reaction (PCR) method. The localization of the bacteria in the aneurysmal/atherosclerotic wall was determined by thromboendarterectomy.ResultsAll patients had periodontal disease, and most cases were severe. PCR examination of the aneurysmal specimens showed that 86% were positive for periodontal bacterial DNA. No bacteria were detected in the control specimens. The bacteria were found in both the intimal/medial layer and the adventitial layer of the aneurysmal wall but only in intimal/medial layer of the atherosclerotic occlusive aorta.ConclusionPeriodontopathic bacteria were present in a high percentage of specimens of diseased arteries from AAA patients and were found throughout the whole aneurysmal wall. These bacteria may play a role in the development of AAAs and/or contribute to weakening the aneurysmal wall

RELATIONSHIP BETWEEN MUSCULAR OUTPUTS AND THE HORIZONTAL PERTURBATION IN THE EARLY PHASE OF BENCH PRESS MOVEMENT UNDER STABLE AND UNSTABLE CONDITIONS

We demonstrated the relationship between the change rates of muscular outputs and horizontal perturbation under stable and unstable conditions in dynamic bench press movement. Twenty-seven male collegiate athletes attended the study. We used a tri-axis accelerometer attached to the barbell shaft to obtain the acceleration data in the bench press and computed peak force output, rate of force development (RFD), and horizontal acceleration trajectory length for 0.2 seconds after the initiation. Significant reduction was found in the peak force output and RFD under stable and unstable conditions, but not in the horizontal acceleration trajectory length. Significant correlation was found between the change rate of RFD and the horizontal acceleration trajectory length under stable and unstable conditions (r=0.55,