Tetrazoles: Synthesis, Structures, Physico-Chemical Properties and Application

The paper represents a brief review of works published by the authors over a period of 1980-2003 years in the field of synthesis and investigations of properties of tetrazole derivatives. The main attention is given to problems of regioselective functionalization of the tetrazole ring and the development of simple and convenient methods for the synthesis of N- and C-substituted tetrazoles, to peculiarities of structure of crystalline tetrazoles including quaternary salts and complexes with transition metal salts as well as to the data on electronic, spatial structure and energetic characteristics of tetrazoles obtained using both quantum-chemical methods and IR-, XH , 13C and 15N NMR spectroscopy. The features of thermal decomposition and combustion of various tetrazoles and polyvinyltetrazoles determining the prospects of their use as effective components of different kind combustible and thermally decomposing systems, including those capable of liquid-flame combustion, which has been revealed for the first time, are considere

Higher Order and boundary Scaling Fields in the Abelian Sandpile Model

The Abelian Sandpile Model (ASM) is a paradigm of self-organized criticality (SOC) which is related to $c=-2$ conformal field theory. The conformal fields corresponding to some height clusters have been suggested before. Here we derive the first corrections to such fields, in a field theoretical approach, when the lattice parameter is non-vanishing and consider them in the presence of a boundary.Comment: 7 pages, no figure

Scaling fields in the two-dimensional abelian sandpile model

We consider the isotropic two-dimensional abelian sandpile model from a perspective based on two-dimensional (conformal) field theory. We compute lattice correlation functions for various cluster variables (at and off criticality), from which we infer the field-theoretic description in the scaling limit. We find a perfect agreement with the predictions of a c=-2 conformal field theory and its massive perturbation, thereby providing direct evidence for conformal invariance and more generally for a description in terms of a local field theory. The question of the height 2 variable is also addressed, with however no definite conclusion yet.Comment: 22 pages, 1 figure (eps), uses revte

Dynamically Driven Renormalization Group Applied to Sandpile Models

The general framework for the renormalization group analysis of self-organized critical sandpile models is formulated. The usual real space renormalization scheme for lattice models when applied to nonequilibrium dynamical models must be supplemented by feedback relations coming from the stationarity conditions. On the basis of these ideas the Dynamically Driven Renormalization Group is applied to describe the boundary and bulk critical behavior of sandpile models. A detailed description of the branching nature of sandpile avalanches is given in terms of the generating functions of the underlying branching process.Comment: 18 RevTeX pages, 5 figure

Self-Organized States in Cellular Automata: Exact Solution

The spatial structure, fluctuations as well as all state probabilities of self-organized (steady) states of cellular automata can be found (almost) exactly and {\em explicitly} from their Markovian dynamics. The method is shown on an example of a natural sand pile model with a gradient threshold.Comment: 4 pages (REVTeX), incl. 2 figures (PostScript

Scaling of waves in the Bak-Tang-Wiesenfeld sandpile model

We study probability distributions of waves of topplings in the Bak-Tang-Wiesenfeld model on hypercubic lattices for dimensions D>=2. Waves represent relaxation processes which do not contain multiple toppling events. We investigate bulk and boundary waves by means of their correspondence to spanning trees, and by extensive numerical simulations. While the scaling behavior of avalanches is complex and usually not governed by simple scaling laws, we show that the probability distributions for waves display clear power law asymptotic behavior in perfect agreement with the analytical predictions. Critical exponents are obtained for the distributions of radius, area, and duration, of bulk and boundary waves. Relations between them and fractal dimensions of waves are derived. We confirm that the upper critical dimension D_u of the model is 4, and calculate logarithmic corrections to the scaling behavior of waves in D=4. In addition we present analytical estimates for bulk avalanches in dimensions D>=4 and simulation data for avalanches in D<=3. For D=2 they seem not easy to interpret.Comment: 12 pages, 17 figures, submitted to Phys. Rev.

Correlation Functions of Dense Polymers and c=-2 Conformal Field Theory

The model of dense lattice polymers is studied as an example of non-unitary Conformal Field Theory (CFT) with $c=-2$. ``Antisymmetric'' correlation functions of the model are proved to be given by the generalized Kirchhoff theorem. Continuous limit of the model is described by the free complex Grassmann field with null vacuum vector. The fundamental property of the Grassmann field and its twist field (both having non-positive conformal weights) is that they themselves suppress zero mode so that their correlation functions become non-trivial. The correlation functions of the fields with positive conformal weights are non-zero only in the presence of the Dirichlet operator that suppresses zero mode and imposes proper boundary conditions.Comment: 5 pages, REVTeX, remark is adde

Probability distribution of residence-times of grains in sandpile models

We show that the probability distribution of the residence-times of sand grains in sandpile models, in the scaling limit, can be expressed in terms of the survival probability of a single diffusing particle in a medium with absorbing boundaries and space-dependent jump rates. The scaling function for the probability distribution of residence times is non-universal, and depends on the probability distribution according to which grains are added at different sites. We determine this function exactly for the 1-dimensional sandpile when grains are added randomly only at the ends. For sandpiles with grains are added everywhere with equal probability, in any dimension and of arbitrary shape, we prove that, in the scaling limit, the probability that the residence time greater than t is exp(-t/M), where M is the average mass of the pile in the steady state. We also study finite-size corrections to this function.Comment: 8 pages, 5 figures, extra file delete

Sandpiles with height restrictions

We study stochastic sandpile models with a height restriction in one and two dimensions. A site can topple if it has a height of two, as in Manna's model, but, in contrast to previously studied sandpiles, here the height (or number of particles per site), cannot exceed two. This yields a considerable simplification over the unrestricted case, in which the number of states per site is unbounded. Two toppling rules are considered: in one, the particles are redistributed independently, while the other involves some cooperativity. We study the fixed-energy system (no input or loss of particles) using cluster approximations and extensive simulations, and find that it exhibits a continuous phase transition to an absorbing state at a critical value zeta_c of the particle density. The critical exponents agree with those of the unrestricted Manna sandpile.Comment: 10 pages, 14 figure

Turbulence without pressure in d dimensions

The randomly driven Navier-Stokes equation without pressure in d-dimensional space is considered as a model of strong turbulence in a compressible fluid. We derive a closed equation for the velocity-gradient probability density function. We find the asymptotics of this function for the case of the gradient velocity field (Burgers turbulence), and provide a numerical solution for the two-dimensional case. Application of these results to the velocity-difference probability density function is discussed.Comment: latex, 5 pages, revised and enlarge