9,786 research outputs found

    Local Operator Multipliers and Positivity

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    We establish an unbounded version of Stinespring's Theorem and a lifting result for Stinespring representations of completely positive modular maps defined on the space of all compact operators. We apply these results to study positivity for Schur multipliers. We characterise positive local Schur multipliers, and provide a description of positive local Schur multipliers of Toeplitz type. We introduce local operator multipliers as a non-commutative analogue of local Schur multipliers, and obtain a characterisation that extends earlier results concerning operator multipliers and local Schur multipliers. We provide a description of the positive local operator multipliers in terms of approximation by elements of canonical positive cones.Comment: 31 page

    Establishment of pluripotent cell lines from vertebrate species - Present status and future prospects

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    Pluripotent embryonic stem (ES) cells are undifferentiated cell lines derived from early embryos and are capable of unlimited undifferentiated proliferation in vitro. They retain the ability to differentiate into all cell types including germ cells in chimeric animals in vivo, and can be induced to form derivatives of all three germ layers in vitro. Mouse ES cells represent one of the most important tools in genetic research. Major applications include the targeted mutation of specific genes by homologous recombination and the discovery of new genes by gene trap strategies. These applications would be of high interest for other model organisms and also for livestock species, However, in spite of tremendous research activities, no proven ES cells colonizing the germ line have been established for vertebrate species other than mouse a nd chicken thus far. This review summarizes the current status of deriving pluripotent embryonic stem cell lines from vertebrates and recent developments in nuclear transfer technology, which may provide an alternative tool for genetic modification of livestock animals. Copyright (C) 1999 S. Karger AG, Basel

    Structural Effects of Carbon Monoxide Coordination to Carbon Centers. π and σ Bindings in Aliphatic Acyl \u3cem\u3eversus\u3c/em\u3e Aromatic Aroyl Cations

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    The binding of carbon monoxide to carbon centers has been examined with two series of aromatic and aliphatic oxocarbonium ions that are successfully isolated as crystalline and highly reactive (hygroscopic) aroylium and acylium salts with poorly coordinating counteranions. X-Ray crystallographic analyses at −150 °C afford precise structural parameters for the characteristic linear carbonyl bond (rCO) and the bond to the carbon centers (rCα). The correlations of these structural parameters evaluated for alkyl (Me, Et and i-Pr) and aryl (p-Me, 2,4,6-trimethyl, p-MeO and p-fluorophenyl) oxocarbonium ions with the corresponding carbonyl stretching frequencies in the solid-state (reflectance) IR spectra yield valuable insight into the binding mode of carbon monoxide. Most noteworthy is the synergic (π–σ) bonding in aroylium structures in contrast to the mainly σ bonding in acylium structures that are organic mimics for carbon monoxide bonding in classical and nonclassical metal carbonyls, respectively

    Quantitative analyses of empirical fitness landscapes

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    The concept of a fitness landscape is a powerful metaphor that offers insight into various aspects of evolutionary processes and guidance for the study of evolution. Until recently, empirical evidence on the ruggedness of these landscapes was lacking, but since it became feasible to construct all possible genotypes containing combinations of a limited set of mutations, the number of studies has grown to a point where a classification of landscapes becomes possible. The aim of this review is to identify measures of epistasis that allow a meaningful comparison of fitness landscapes and then apply them to the empirical landscapes to discern factors that affect ruggedness. The various measures of epistasis that have been proposed in the literature appear to be equivalent. Our comparison shows that the ruggedness of the empirical landscape is affected by whether the included mutations are beneficial or deleterious and by whether intra- or intergenic epistasis is involved. Finally, the empirical landscapes are compared to landscapes generated with the Rough Mt.\ Fuji model. Despite the simplicity of this model, it captures the features of the experimental landscapes remarkably well.Comment: 24 pages, 5 figures; to appear in Journal of Statistical Mechanics: Theory and Experimen

    Experimental tests of reaction rate theory: Mu+H2 and Mu+D2

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    Copyright @ 1987 American Institute of Physics.Bimolecular rate constants for the thermal chemical reactions of muonium (Mu) with hydrogen and deuterium—Mu+H2→MuH+H and Mu+D2→MuD+D—over the temperature range 473–843 K are reported. The Arrhenius parameters and 1σ uncertainties for the H2 reaction are log A (cm3 molecule-1 s-1)=-9.605±0.074 and Ea =13.29±0.22 kcal mol-1, while for D2 the values are -9.67±0.12 and 14.73±0.40, respectively. These results are significantly more precise than those reported earlier by Garner et al. For the Mu reaction with H2 our results are in excellent agreement with the 3D quantum mechanical calculations of Schatz on the Liu–Siegbahn–Truhlar–Horowitz potential surface, but the data for both reactions compare less favorably with variational transition-state theory, particularly at the lower temperatures.NSERC (Canada) and the Petroleum Research Foundation of the Americal Chemical Society

    Phases of 4D Scalar-tensor black holes coupled to Born-Infeld nonlinear electrodynamics

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    Recent results show that when non-linear electrodynamics is considered the no-scalar-hair theorems in the scalar-tensor theories (STT) of gravity, which are valid for the cases of neutral black holes and charged black holes in the Maxwell electrodynamics, can be circumvented. What is even more, in the present work, we find new non-unique, numerical solutions describing charged black holes coupled to non-linear electrodynamics in a special class of scalar-tensor theories. One of the phases has a trivial scalar field and coincides with the corresponding solution in General Relativity. The other four phases that we find are characterized by the value of the scalar field charge. The causal structure and some aspects of the stability of the solutions have also been studied. For the scalar-tensor theories considered, the black holes have a single, non-degenerate horizon, i.e., their causal structure resembles that of the Schwarzschild black hole. The thermodynamic analysis of the stability of the solutions indicates that a phase transition may occur.Comment: 18 pages, 8 figures, new phases, figures, clarifying remarks and acknowledgements adde

    Teff and log g dependence of velocity fields in M-stars

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    We present an investigation of velocity fields in early to late M-type hydrodynamic stellar atmosphere models. These velocities will be expressed in classical terms of micro- and macro-turbulent velocities for usage in 1D spectral synthesis. The M-star model parameters range between log g of 3.0 - 5.0 and Teff of 2500 K - 4000 K. We characterize the Teff- and log g-dependence of the hydrodynamical velocity fields in these models with a binning method, and for the determination of micro-turbulent velocities, the Curve of Growth method is used. The macro-turbulent velocities are obtained by convolutions with Gaussian profiles. Velocity fields in M-stars strongly depend on log g and Teff. Their velocity amplitudes increase with decreasing log g and increasing Teff. The 3D hydrodynamical and 1D macro-turbulent velocities range from ~100 m/s for cool high gravity models to ~ 800 m/s - 1000 m/s for hot models or models with low log g. The micro-turbulent velocities range in the order of ~100 m/s for cool models, to ~600 m/s for hot or low log g models. Our M-star structure models are calculated with the 3D radiative-hydrodynamics (RHD) code CO5BOLD. The spectral synthesis on these models is performed with the line synthesis code LINFOR3D.Comment: 8 pages, 6 Figures, Proceeding fot the "Recent directions in astrophysical quantitative spectroscopy and radiation hydrodynamics" conferenc

    Noncommutative Einstein Equations

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    We study a noncommutative deformation of general relativity where the gravitational field is described by a matrix-valued symmetric two-tensor field. The equations of motion are derived in the framework of this new theory by varying a diffeomorphisms and gauge invariant action constructed by using a matrix-valued scalar curvature. Interestingly the genuine noncommutative part of the dynamical equations is described only in terms of a particular tensor density that vanishes identically in the commutative limit. A noncommutative generalization of the energy-momentum tensor for the matter field is studied as well.Comment: 17 Pages, LaTeX, reference adde
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