Luminescence of Ce3+ multicenters in Ca2+ -Mg2+ -Si4+ based garnet phosphors

Comparison of the luminescent properties of Ca3Sc2Si3O12: Ce and Ca2YMgScSi3O12: Ce single crystalline films (SCF) phosphors, grown by the liquid phase epitaxy method, was performed in this work. We have observed formation of the Ce3+ multicenters in Ca3Sc2Si3O12: Ce and Ca2YMgScSi3O12: Ce in the emission and excitation spectra as well as in the decay kinetics of the Ce3+ luminescence in SCFs of these garnets. Such Ce3+ multicenters possess different crystal field strength due to the inhomogeneous local surroundings of the dodecahedral positions of garnet host at the substitution of the octahedral positions by hetero-valence Mg2+ and Sc3+ ions and the tetrahedral positions by Si4+ ions. We confirm the presence of an effective energy transfer between different Ce3+ multicenters in Ce3+ doped Ca3Sc2Si3O12 and Ca2YMgScSi3O12 garnets. The positive trends in variations of the spectroscopic properties of the Ca2YMgScSi3O12: Ce garnet with respect to Ca3Sc2Si3O12: Ce garnet were observed also due to substitution of the dodecahedral sites of the garnet host by Y3+ ions and the octahedral sites by Mg2+ ions, which can be suitable for the development of new converters of white LEDs. Namely, due to the Y3+-Mg2+ doping, the luminescence spectrum of Ce3+ ions in Ca2YMgScSi3O12: Ce SCFs significantly extends in the red range in comparison with the Ca3Sc2Si3O12: Ce SCF counterpart

Application of Innovative Teaching Methods in a Technical University

В процессе поиска педагогических технологий, отвечающих требованиям нового времени, появился термин инновационное обучение. Использование инновационных методов активного обучения вызывает у студентов мотив интереса к учебе, что позволяет создать атмосферу творческого обучения и параллельно решать ряд задач: учебных, воспитательных, развивающих.In the process of searching for pedagogical technologies that meet the requirements of the new time, the term innovative teaching appeared. The use of innovative methods of active learning arouses in students the motive of interest in learning, which allows creating an atmosphere of creative learning and simultaneously solving a number of tasks: educational, developmental

Luminescent and scintillation properties of Ce3+ doped Ca2RMgScSi3O12 (R = Y, Lu) single crystalline films

The work is dedicated to the growth and investigation of the luminescent and scintillation properties of single crystalline films (SCFs) of Ca2-xR1+xMg1+xSc1-xSi3O12:Ce (R = Y, Lu) mixed garnets with x = 0-0.25, grown using the liquid phase epitaxy method onto Y3Al5O12 substrates from PbO-B2O3 based flux. The absorption, luminescent and scintillation properties of Ca2-xY1+xMg1+xSc1-xSi3O12:Ce and Ca2-xLu1+xMg1+xSc1-xSi3O12:Ce SCFs with x = 0 and 0.25 were investigated and compared with the reference YAG:Ce and LuAG:Ce SCFs. Using the Ca2+, Mg2+ and Si4+ alloying, the Ce3+ emission spectra in Ca2-xR1+xMg1+xSc1-xSi3O12:Ce (R = Y, Lu; x = 0-0.25) SCFs can be notably extended in the red range in comparison with YAG: Ce and LuAG: Ce SCFs due to the increase of crystal field strength and Ce3+ multicenter creation in the dodecahedral positions of the lattices of these mixed garnet compounds. Due to the formation of Ce4+ ions, the as-grown Ca2-xR1+xMg1+xSc1-xSi3O12:Ce (R = Y, Lu) SCFs at x = 0 and 0.25 show relatively low light yield. However, after annealing in reducing atmosphere (95% N-2 + 5% H-2) at T > 1000 degrees C, a recharging Ce4+ -> Ce3+ takes place. After that, these SCFs possess the light yield about of 30% and 31% in comparison with the reference YAG: Ce and LuAG: Ce SCFs, respectively, and a fast scintillation response with the decay times in the ns range under a-particles excitation by Pu-239 (5.15 MeV) source

Synthesis and luminescent properties of prospective Ce3+ doped silicate garnet phosphors for white LED converters

The results on crystallization and investigation of the luminescent properties of prospective ceramic phosphors based on the Ce3+ doped {Ca2R}[ScB](CSi2)O12 (R = Lu, Y, Gd; B = Sc, Ga, C = Ga, Al) silicate garnets are presented for the first time in this work. We have observed the variations of the spectroscopic properties of Ce3+ ions in the mentioned Ca2+-Si4+ garnet hosts depending on the cation content at the dodecahedral {}, octahedral [] and tetrahedral () sites of garnet lattice. These results can be useful for the development of new generation of ceramic phosphor converters for white LEDs based on the garnet compounds under study