Frictional experiments of dolerite at intermediate slip rates with controlled temperature: Rate weakening or temperature weakening?

A rotary shear apparatus has been newly set up in Chiba University which can control the temperature near a sliding surface, T_meas, up to 1000°C independently from slip rate, V. Frictional experiments at 0.010 m/s, 1 MPa normal stress, and variable T_meas for dolerite have revealed a remarkable effect of temperature on the friction coefficient, f. With increasing T_meas, f starts from 0.7 to 0.8 at room temperature (RT), decreases down to 0.5–0.6 at 400°C, increases until 800°C, and then decreases again. We have also conducted XRD analyses of the wear materials (mainly submicron particles) and investigated microstructures of the sliding surfaces developed at different temperatures T_meas, and we found that there is a negative correlation between f and the amount of amorphous material except at RT and 1000°C. The generation of the amorphous phase probably causes the weakening. There is no amorphous phase recognized for a sample at 1000°C which is an aggregate of rounded crystals. EBSD analyses show that the material on the sliding surface at 1000°C contains randomly oriented hematite grains, which together with the observed microstructural features suggests that granular flow was taking place. We have also demonstrated that f depends not only on the instantaneous value of temperature, but also on its history. By comparing with conventional rotary shear friction experiment for the same dolerite without temperature control, we conclude that strong “rate weakening” as recently observed in high-velocity frictional experiments without an active control of the temperature has a significant amount of contribution from the temperature effect

Some properties of one-pebble Turing machines with sublogarithmic space

AbstractThis paper investigates some aspects of the accepting powers of deterministic, nondeterministic, and alternating one-pebble Turing machines with spaces between loglogn and logn. We first investigate a relationship between the accepting powers of two-way deterministic one-counter automata and deterministic (or nondeterministic) one-pebble Turing machines, and show that they are incomparable. Then we investigate a relationship between nondeterminism and alternation, and show that there exists a language accepted by a strongly loglogn space-bounded alternating one-pebble Turing machine, but not accepted by any weakly o(logn) space-bounded nondeterministic one-pebble Turing machine. Finally, we investigate a space hierarchy, and show that for any one-pebble (fully) space constructible function L(n)⩽logn, and for any function L′(n)=o(L(n)), there exists a language accepted by a strongly L(n) space-bounded deterministic one-pebble Turing machine, but not accepted by any weakly L′(n) space-bounded nondeterministic one-pebble Turing machine

Illite-smectite mixed-layer minerals in hydrothermal alteration of volcanic rocks: I. One-dimensional XRD structure analysis and characterisation of component layers.

International audienceFor a series of mixed-layer illite-smectite (I-S) minerals from a drill hole near the Kakkonda geothermal field, one-dimensional structure analysis by X-ray diffraction (XRD) was performed using Ca-saturated specimens at both air-dried and ethylene glycol solvated states. The expandability characteristics of component layers were also examined by means of alkylammonium exchange and Li-saturation. The K content in illite layer was almost constant at 1.5-1.7/O20(OH)4 in the I-S series from 3% to 85% of I-layer content (% I). The layer charge of smectite layer varied slightly within the ranges of R1 I-S samples showed complicated expandability with alkylammonium exchange. The XRD patterns of dodecylammonium exchanged I-S samples can be interpreted by random interstratification of several types of sub-units such as layer-doublets, layer-triplets and layer-quarutets present in the crystallites. This interpretation is consistent with the variation in the occurrence probabilities of layer-multiplets calculated from the junction probabilities and the proportions of layers. Because the interpretation indicates that I-S is a stack of various types of the sub-units, the smectite illitization can be described by a systematic change in the type and proportion of the sub-units constituting crystallites

In vitro Activities of Oral Cephem and Telithromycin Against Clinical Isolates of Major Respiratory Pathogens in Japan

The in vitro antibacterial activities of oral cephem antibiotics and ketolide telithromycin against major respiratory pathogens possessing β-lactam-resistant mutations (within the pbp gene) and/or macrolide-resistant genes (erm and mef) were examined in clinical isolates collected at 66 institutes in all over the Japan between 2002 and 2003. Telithromycin showed the strongest antibacterial activity against methicillin-susceptible Staphylococcus aureus strains with and without macrolide-resistant genes, such as ermA or ermC gene. All the cephem antibiotics showed potent antibacterial activity against Streptococcus pyogenes, with minimum inhibitory concentrations (MICs) of 0.015 mg/L or lower. Cefdinir had a much higher MIC90 against genotypic penicillin-resistant Streptococcus pneumoniae (gPRSP) than cefditoren and cefcapene (8 mg/L cefdinir vs. 1 mg/L cefditoren and cefcapene). The majority of gPRSP harbored either ermB or mefA, and the antibacterial activity of telithromycin against these strains was decreased however some susceptibility was still sustained. Cefditoren exerted the strongest antibacterial activity against β-lactamase-negative ampicillin-resistant Haemophilus influenzae, with an MIC90 of 0.5 mg/L. These results underline the importance of checking the susceptibility and selecting an appropriate antibiotic against target pathogens

Potassium Fixation by Clay Minerals during Hydrothermal Treatment

Abstract--The amount of K fixed in K- and Ca-saturated montmodUonite, v rmiculite (trioctahedral), rec-torite-type and IMII-ordered mica/montmorillonites wa measured as a function of time (1-64 days), tem-perature (25~176 pH (6.0, 9.7, and 10.7), and K-concentration (0.02 and 1.0 M) in solution. The amount of K fixed by the clays generally increased with increasing temperature, pH, and K-concentration a d reached saturation i response to each experimental condition in 5 or 6 days. The K-montmorillonite and K-vermiculite fixed considerable amounts of K even at 25 ~ Fixed K in moutmoriUonite ncreased with an increase of the layer charge which is also influenced significantly by the interlayer cation, In detail, the behavior in K-fixation was specific to each clay. The type of structural transformation with K-fixation was different for each clay. In montmorillonite, especially, the type of transformation was related to the cationic omposition of the system; in K homoionic system, montmorillonite transformed rapidly into iUite/montmorillonite with about 40 % expandable layers at 300 ~ and in a mixed cation system with Ca and K, it reacted gradually to random illite/montmorillonites with increasing temperature. These data indicate that he cation-exchange process of a natural pore solution plays an important role in the gradual transformation fdetrital montmoriUonite to illite