Stress Balance in Synthetic Serpentinized Peridotites Deformed at Subduction Zone Pressures

Weak serpentine minerals affect the mechanical behavior of serpentinized peridotites at depth, and may play a significant role in deformation localization within subduction zones, at local or regional scale. Mixtures of olivine with 5, 10, 20 and 50 vol. % fraction of antigorite, proxies for serpentinized peridotites, were deformed in axial shortening geometry under high pressures (ca. 2–5 GPa) and moderate temperatures (ca. 350°C), with in situ stress and strain measurements using synchrotron X-rays. We evaluate the average partitioning of stresses at the grains scale within each phase (mineral) of the aggregate and compare with pure olivine aggregates in the same conditions. The in situ stress balance is different between low antigorite contents up to 10 vol. %, and higher contents above 20 vol. %. Microstructure and stress levels suggest the deformation mechanisms under these experimental conditions are akin to (semi)brittle and frictional processes. Unlike when close to dehydration temperatures, hardening of the aggregate is observed at low serpentine fractions, due to an increase in local stress concentrations. Below and above the 10–20 vol. % threshold, the stress state in the aggregate corresponds to friction laws already measured for pure olivine aggregates and pure antigorite aggregates respectively. As expected, the behavior of the two-phase aggregate does not evolve as calculated from simple iso-stress or iso-strain bounds, and calls for more advanced physical models of two-phase mixtures

CO2 production by impact in carbonates? An ATEM and stable isotope (C,O) study

Carbonates may have been a common target for large impacts on the Earth and possible related CO2 outgassing would have important consequences for the composition of the atmosphere. To estimate volatile release during such impacts, isotopic ratios (C-13/C-12 and O-18/O-16) were determined on highly shocked carbonate samples in combination with SEM and analytical transmission electron microscopy (ATEM) investigations. The study was performed on both naturally and experimentally shocked rocks, i.e. 50-60 GPa shocked limestone-dolomite fragments from the Haughton impact crater (Canada), and carbonates shocked in shock recovery experiments. For the experiments, unshocked carbonates consisting of mixture of dolomite and calcite from the Haughton area were used. Naturally shocked samples were collected in the polymict breccia near the center of the Haughton crater