353 research outputs found

    Parish Clergy of Voronezh Diocese in Fight Against the Cholera Epidemic of 1892—1893

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    The article is devoted to the study of the role of clergy and clergymen of the Voronezh diocese in the fight against the spread of the cholera epidemic of 1892-1893. The novelty of the study lies in the fact that the contribution of the clergy of the Orthodox Russian Church to countering the spread of infectious diseases has practically not been studied. It is noted that in the Russian Empire, Orthodox clerics were not only ministers of the altar, but also performed a number of socially significant functions. Based on a wide range of historical sources, the author analyzes the attitude of the population of the Voronezh province to cholera disease. The educational activity of clerics, the participation of clergy in organizing aid to parishioners are considered. It is emphasized that the clergy were closely associated with the peasant population of the empire, daily contact with them during the divine service. The study showed that the state tried to use the experience and knowledge of the clergy and clergymen, considering them as the social support of the autocratic system. The author concludes that the parish clergy and clergymen played an important role in the fight against infectious disease, not only participating in educational activities and spiritually supporting the population, but also providing those in need with initial medical assistance

    Dynamik der kulturellen Wertigkeiten und Architektur des Rationalismus im Wandel der Zeit - von Hannes Meyer bis Aldo Rossi

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    Wissenschaftliches Kolloquium vom 27. bis 30. Juni 1989 in Weimar an der Hochschule für Architektur und Bauwesen zum Thema: ‚Produktivkraftentwicklung und Umweltgestaltung. Sozialer und wissenschaftlich-technischer Fortschritt in ihren Auswirkungen auf Architektur und industrielle Formgestaltung in unserer Zeit. Zum 100. Geburtstag von Hannes Meyer

    Cyclotron resonance of extremely conductive 2D holes in high Ge content strained heterostructures

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    Cyclotron resonance has been observed in steady and pulsed magnetic fields from high conductivity holes in Ge quantum wells. The resonance positions, splittings and linewidths are compared to calculations of the hole Landau levels

    Temperature-driven single-valley Dirac fermions in HgTe quantum wells

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    We report on temperature-dependent magnetospectroscopy of two HgTe/CdHgTe quantum wells below and above the critical well thickness dcd_c. Our results, obtained in magnetic fields up to 16 T and temperature range from 2 K to 150 K, clearly indicate a change of the band-gap energy with temperature. The quantum well wider than dcd_c evidences a temperature-driven transition from topological insulator to semiconductor phases. At the critical temperature of 90 K, the merging of inter- and intra-band transitions in weak magnetic fields clearly specifies the formation of gapless state, revealing the appearance of single-valley massless Dirac fermions with velocity of 5.6×1055.6\times10^5 m×\timess−1^{-1}. For both quantum wells, the energies extracted from experimental data are in good agreement with calculations on the basis of the 8-band Kane Hamiltonian with temperature-dependent parameters.Comment: 5 pages, 3 figures and Supplemental Materials (4 pages

    Injuries and Diseases of the Population of the Upper Sura and Moksha Rivers in the 17th–18th CC

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    The article characterizes the anthropological materials with traces of pathological changes. All material has been discovered in the territory of the Upper Sura and Moksha rivers, and dated the 17th-18th centuries. Two osteological collections from older cemeteries were studied. The first collection was found in the territory of Penza city, and the second collection was found discovered in Narovchat town. Traces of post-traumatic changes are often identified on the bones. They are localized on the cranial vault, in the orbit region, etc. Traces of fractures on the clavicles are often revealed. Traces of oncology disease are relatively rare. There are nu­merous bones with traces of syphilis pathological changes in the materials from the territory of Penza. These traces are discovered on the skulls and bones of the postcranial skeleton (mostly the tibia). The materials from Narovchat feature two skulls with tooth incision pathologies. In one case, there were signs of anomalies in the development of pelvic bones as a result of rhizomelic spondylitis

    Temperature-dependent magnetospectroscopy of HgTe quantum wells

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    We report on magnetospectroscopy of HgTe quantum wells in magnetic fields up to 45 T in temperature range from 4.2 K up to 185 K. We observe intra- and inter-band transitions from zero-mode Landau levels, which split from the bottom conduction and upper valence subbands, and merge under the applied magnetic field. To describe experimental results, realistic temperature-dependent calculations of Landau levels have been performed. We show that although our samples are topological insulators at low temperatures only, the signature of such phase persists in optical transitions at high temperatures and high magnetic fields. Our results demonstrate that temperature-dependent magnetospectroscopy is a powerful tool to discriminate trivial and topological insulator phases in HgTe quantum wells

    Copper(II) complexes of functionalized 2,2’:6’,2’’-terpyridines and 2,6-di(thiazol-2-yl)pyridine : structure, spectroscopy, cytotoxicity and catalytic activity

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    Six new copper(II) complexes with 2,2’:6’,2’’-terpyridine (4’-Rn-terpy) [1 (R1 = furan-2-yl), 2 (R2 = thiophen- 2-yl), and 3 (R3 = 1-methyl-1H-pyrrol-2-yl)] and 2,6-di(thiazol-2-yl)pyridine derivatives (Rn-dtpy) [4 (R1), 5 (R2), and 6 (R3)] have been synthesized by a reaction between copper(II) chloride and the corresponding ligand. The complexes have been characterized by UV-vis and IR spectroscopy, and their structures have been determined by X-ray analysis. The antiproliferative potential of copper(II) complexes of 2,2’:6’,2’’-terpyridine and 2,6-di(thiazol-2-yl)pyridine derivatives towards human colorectal (HCT116) and ovarian (A2780) carcinoma as well as towards lung (A549) and breast adenocarcinoma (MCF7) cell lines was examined. Complex 1 and complex 6 were found to have the highest antiproliferative effect on A2780 ovarian carcinoma cells, particularly when compared with complex 2, 3 with no antiproliferative effect. The order of cytotoxicity in this cell line is 6 > 1 > 5 > 4 > 2 ≈ 3. Complex 2 seems to be much more specific towards colorectal carcinoma HCT116 and lung adenocarcinoma A549 cells. The viability loss induced by the complexes agrees with Hoechst 33258 staining and typical morphological apoptotic characteristics like chromatin condensation and nuclear fragmentation. The specificity towards different types of cell lines and the low cytotoxic activity towards healthy cells are of particular interest and are a positive feature for further developments. Complexes 1–6 were also tested in the oxidation of alkanes and alcohols with hydrogen peroxide and tert-butyl-hydroperoxide (TBHP). The most active catalyst 4 gave, after 120 min, 0.105 M of cyclohexanol + cyclohexanone after reduction with PPh3. This concentration corresponds to a yield of 23% and TON = 210. Oxidation of cis-1,2-dimethylcyclohexane with m-CPBA catalyzed by 4 in the presence of HNO3 gave a product of a stereoselective reaction (trans/cis = 0.47). Oxidation of secondary alcohols afforded the target ketones in yields up to 98% and TON = 630
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