Fullerenes, PAHs, Amino Acids and High Energy Astrophysics

We present theoretical, observational and laboratory work on the spectral properties of fullerenes and hydrogenated fullerenes. Fullerenes in its various forms (individual, endohedral, hydrogenated, etc.) can contribute to the UV bump in the extinction curves measured in many lines of sight of the Galaxy. They can also produce a large number of absorption features in the optical and near infrared which could be associated with diffuse interstellar bands. We summarise recent laboratory work on the spectral characterisation of fullerenes and hydrogenated fullerenes (for a range of temperatures). The recent detection of mid-IR bands of fullerenes in various astrophysical environments (planetary nebulae, reflection nebulae) provide additional evidence for a link between fullerene families and diffuse interstellar bands. We describe recent observational work on near IR bands of C60+ in a protoplanetary nebula which support fullerene formation during the post-AGB phase. We also report on the survival of fullerenes to irradiation by high energy particles and gamma photons and laboratory work to explore the chemical  reactions that take place when fullerenes are exposed to this radiations in the presence of water, ammonia and other molecules as a potential path to form amino acids

A search for naphthalene in diffuse interstellar clouds

We have obtained high resolution optical spectroscopy of 10 reddened O-type stars with UVES at VLT to search for interstellar bands of the naphthalene cation (C$_{10}$H$_{8}$$^+$) in the intervening clouds. No absorption features were detected near the laboratory strongest band of this cation at 6707 \AA except for star HD 125241 (O9 I). Additional bands in the optical spectrum of this star appear to be consistent with other transitions of this cation. Under the assumption that the bands are caused by naphthalene cations we derive a column density N$_{Np^+}$ = (1.2$\pm$ 0.3) x 10 $^{13}$ cm$^{-2}$ similar to the column density claimed in the Perseus complex star Cernis 52 (Iglesias-Groth et al. 2008). The strength ratio of the two prominent diffuse interstellar bands at 5780 and 5797 \AA suggests the presence of a $\sigma$-type cloud in the line of sight of HD 125241.Comment: Accepted for publication in MNRA

A rich molecular chemistry in the gas of the IC 348 star cluster of the Perseus Molecular Cloud

We present Spitzer 10-34 {\mu}m spectroscopic observations of the diffuse gas in the inner region of the star-forming region IC 348 of the Perseus Molecular Cloud. We find evidence for the strongest mid-IR bands of common molecules as H\textsubscript{2}, OH, H\textsubscript{2}O,CO\textsubscript{2} and NH\textsubscript{3} and of several carbonaceous molecules which may play an important role in the production of more complex hydrocarbons: HCN, C\textsubscript{2}H\textsubscript{2}, C\textsubscript{4}H\textsubscript{2}, HC\textsubscript{3}N, HC\textsubscript{5}N, C\textsubscript{2}H\textsubscript{6}, C\textsubscript{6}H\textsubscript{2}, C\textsubscript{6}H\textsubscript{6}. The excitation diagram of H\textsubscript{2} reveals the presence of warm gas (270 +- 30 K) at the observed locations. Assuming this temperature, the derived abundances of CO\textsubscript{2} and NH\textsubscript{3} relative to H\textsubscript{2} are 10\textsuperscript{-8} and 10\textsuperscript{-7}, respectively. From the water lines we obtain an abundance of order 10\textsuperscript{-6} and higher gas temperatures. The abundances derived for HCN and C\textsubscript{2}H\textsubscript{2}, key molecules in the development of prebiotic building blocks, are of order 10\textsuperscript{-7} and 10\textsuperscript{-9}, respectively. More complex molecules such as PAHs and the fullerenes C\textsubscript{60} and C\textsubscript{70} are also present. IC 348 appears to be very rich and diverse in molecular content. The JWST spectroscopic capabilities may provide details on the spatial distribution of all these molecules and extend the present search to more complex hydrocarbons.Comment: 33 pages, 24 figures, 4 tables, ACCEPTED in MNRA

A search for interstellar anthracene toward the Perseus anomalous microwave emission region

We report the discovery of a new broad interstellar (or circumstellar) band at 7088.8 +- 2.0 \AA coincident to within the measurement uncertainties with the strongest band of the anthracene cation (C$_{14}$H$_{10}$$^+$) as measured in gas-phase laboratory spectroscopy at low temperatures (Sukhorukov et al.2004). The band is detected in the line of sight of star Cernis 52, a likely member of the very young star cluster IC 348, and is probably associated with cold absorbing material in a intervening molecular cloud of the Perseus star forming region where various experiments have recently detected anomalous microwave emission. From the measured intensity and available oscillator strength we find a column density of N$_{an^+}$= 1.1(+-0.4) x 10$^{13}$ cm$^{-2}$ implying that ~0.008% of the carbon in the cloud could be in the form of C$_{14}$H$_{10}$$^+$. A similar abundance has been recently claimed for the naphthalene cation (Iglesias-Groth et al. 2008) in this cloud. This is the first location outside the Solar System where specific PAHs are identified. We report observations of interstellar lines of CH and CH$^+$ that support a rather high column density for these species and for molecular hydrogen. The strength ratio of the two prominent diffuse interstellar bands at 5780 and 5797 \AA suggests the presence of a ``zeta'' type cloud in the line of sight (consistent with steep far-UV extinction and high molecular content). The presence of PAH cations and other related hydrogenated carbon molecules which are likely to occur in this type of clouds reinforce the suggestion that electric dipole radiation from fast spinning PAHs is responsible of the anomalous microwave emission detected toward Perseus.Comment: Accepted for publication in Monthly Notices of the Royal Astronomical Societ

The Chemical Composition of Cernis 52 (BD+31 640)

We present an abundance analysis of the star Cernis 52 in whose spectrum we recently reported the napthalene cation in absorption at 6707.4 {\AA}. This star is on a line of sight to the Perseus molecular complex. The analysis of high-resolution spectra using a chi^2-minimization procedure and a grid of synthetic spectra provides the stellar parameters and the abundances of O, Mg, Si, S, Ca, and Fe. The stellar parameters of this star are found to be T_{eff} = 8350 +- 200 K, logg= 4.2 +- 0.4 dex. We derived a metallicity of [Fe/H] = -0.01 +- 0.15. These stellar parameters are consistent with a star of $\sim 2$ \Msun in a pre-main-sequence evolutionary stage. The stellar spectrum is significantly veiled in the spectral range 5150-6730 {\AA} up to almost 55 per cent of the total flux at 5150 {\AA} and decreasing towards longer wavelengths. Using Johnson-Cousins and 2MASS photometric data, we determine a distance to Cernis 52 of 231$^{+135}_{-85}$ pc considering the error bars of the stellar parameters. This determination places the star at a similar distance to the young cluster IC 348. This together with its radial velocity, v_r=13.7+-1 km/s, its proper motion and probable young age support Cernis 52 as a likely member of IC 348. We determine a rotational velocity of v\sin i=65 +- 5 km/s for this star. We confirm that the stellar resonance line of \ion{Li}{1} at 6707.8 {\AA} is unable to fit the broad feature at 6707.4 {\AA}. This feature should have a interstellar origin and could possibly form in the dark cloud L1470 surrounding all the cluster IC 348 at about the same distance.Comment: Accepted for publication in The Astrophysical Journa