Inequivalent routes across the Mott transition in V2O3 explored by X-ray absorption

The changes in the electronic structure of V2O3 across the metal-insulator transition induced by temperature, doping and pressure are identified using high resolution x-ray absorption spectroscopy at the V pre K-edge. Contrary to what has been taken for granted so far, the metallic phase reached under pressure is shown to differ from the one obtained by changing doping or temperature. Using a novel computational scheme, we relate this effect to the role and occupancy of the a1g orbitals. This finding unveils the inequivalence of different routes across the Mott transition in V2O

1/T_1 nuclear relaxation time of \kappa-(BEDT-TTF)_ 2 Cu [N(CN)_2] Cl : effects of magnetic frustration

We study the role played by the magnetic frustration in the antiferromagnetic phase of the organic salt \kappa-(BEDT-TTF)_ 2 Cu [N(CN)_2] Cl. Using the spatially anisotropic triangular Heisenberg model we analyze previous and new performed NMR experiments. We compute the 1/T_1 relaxation time by means of the modified spin wave theory. The strong suppression of the nuclear relaxation time observed experimentally under varying pressure and magnetic field is qualitatively well reproduced by the model. Our results suggest the existence of a close relation between the effects of pressure and magnetic frustration.Comment: 10 pages, 9 figures, to appear in Journal of Phys.: Condens Matte

Charge gap in the one--dimensional dimerized Hubbard model at quarter-filling

We propose a quantitative estimate of the charge gap that opens in the one-dimensional dimerized Hubbard model at quarter-filling due to dimerization, which makes the system effectively half--filled, and to repulsion, which induces umklapp scattering processes. Our estimate is expected to be valid for any value of the repulsion and of the parameter describing the dimerization. It is based on analytical results obtained in various limits (weak coupling, strong coupling, large dimerization) and on numerical results obtained by exact diagonalization of small clusters. We consider two models of dimerization: alternating hopping integrals and alternating on--site energies. The former should be appropriate for the Bechgaard salts, the latter for compounds where the stacks are made of alternating $TMTSF$ and $TMTTF$ molecules. % $(TMTSF)_2 X$ and $(TMTTF)_2 X$ ($X$ denotes $ClO_4$, $PF_6$, $Br$...).Comment: 33 pages, RevTeX 3.0, figures on reques

Mechanism for the Singlet to Triplet Superconductivity Crossover in Quasi-One-Dimensional Organic Conductors

Superconductivity of quasi-one-dimensional organic conductors with a quarter-filled band is investigated using the two-loop renormalization group approach to the extended Hubbard model for which both the single electron hopping t_{\perp} and the repulsive interaction V_{\perp} perpendicular to the chains are included. For a four-patches Fermi surface with deviations to perfect nesting, we calculate the response functions for the dominant fluctuations and possible superconducting states. By increasing V_{\perp}, it is shown that a d-wave (singlet) to f-wave (triplet) superconducting state crossover occurs, and is followed by a vanishing spin gap. Furthermore, we study the influence of a magnetic field through the Zeeman coupling, from which a triplet superconducting state is found to emerge.Comment: 11 pages, 15 figures, published versio

Superconducting pairing and density-wave instabilities in quasi-one-dimensional conductors

Using a renormalization group approach, we determine the phase diagram of an extended quasi-one-dimensional electron gas model that includes interchain hopping, nesting deviations and both intrachain and interchain repulsive interactions. d-wave superconductivity, which dominates over the spin-density-wave (SDW) phase at large nesting deviations, becomes unstable to the benefit of a triplet $f$-wave phase for a weak repulsive interchain backscattering term $g_1^\perp>0$, despite the persistence of dominant SDW correlations in the normal state. Antiferromagnetism becomes unstable against the formation of a charge-density-wave state when $g_1^\perp$ exceeds some critical value. While these features persist when both Umklapp processes and interchain forward scattering ($g_2^\perp$) are taken into account, the effect of $g_2^\perp$ alone is found to frustrate nearest-neighbor interchain $d$- and $f$-wave pairing and instead favor next-nearest-neighbor interchain singlet or triplet pairing. We argue that the close proximity of SDW and charge-density-wave phases, singlet d-wave and triplet $f$-wave superconducting phases in the theoretical phase diagram provides a possible explanation for recent puzzling experimental findings in the Bechgaard salts, including the coexistence of SDW and charge-density-wave phases and the possibility of a triplet pairing in the superconducting phase.Comment: 19 pages, 13 figure

Hall effect and conduction anisotropy in the organic conductor TMTSF2PF6

Long missing basic experiments in the normal phase of the anisotropic electron system of TMTSF2PF6 were performed. Both the Hall effect and the ab'-plane conduction anisotropy are directly addressing the unconventional electrical properties of this Bechgaard salt. We found that the dramatic reduction of the carrier density deduced from recent optical data is not reflected in an enhanced Hall-resistance. The pressure- and temperature dependence of the b'-direction resitivity reveal isotropic relaxation time and do not require explanations beyond the Fermi liquid theory. Our results allow a coherent-diffusive transition in the interchain carrier propagation, however the possible crossover to Luttinger liquid behavior is placed to an energy scale above room temperature.Comment: 5 pages, 5 figures, to be published in Phys. Rev. Let

Role of Interchain Hopping in the Magnetic Susceptibility of Quasi-One-Dimensional Electron Systems

The role of interchain hopping in quasi-one-dimensional (Q-1D) electron systems is investigated by extending the Kadanoff-Wilson renormalization group of one-dimensional (1D) systems to Q-1D systems. This scheme is applied to the extended Hubbard model to calculate the temperature ($T$) dependence of the magnetic susceptibility, $\chi (T)$. The calculation is performed by taking into account not only the logarithmic Cooper and Peierls channels, but also the non-logarithmic Landau and finite momentum Cooper channels, which give relevant contributions to the uniform response at finite temperatures. It is shown that the interchain hopping, $t_\perp$, reduces $\chi (T)$ at low temperatures, while it enhances $\chi(T)$ at high temperatures. This notable $t_\perp$ dependence is ascribed to the fact that $t_\perp$ enhances the antiferromagnetic spin fluctuation at low temperatures, while it suppresses the 1D fluctuation at high temperatures. The result is at variance with the random-phase-approximation approach, which predicts an enhancement of $\chi (T)$ by $t_\perp$ over the whole temperature range. The influence of both the long-range repulsion and the nesting deviations on $\chi (T)$ is further investigated. We discuss the present results in connection with the data of $\chi (T)$ in the (TMTTF)$_2X$ and (TMTSF)$_2X$ series of Q-1D organic conductors, and propose a theoretical prediction for the effect of pressure on magnetic susceptibility.Comment: 17 pages, 19figure

Superconductivity and Antiferromagnetism in Quasi-one-dimensional Organic Conductors

We review the current understanding of superconductivity in the quasi-one-dimensional organic conductors of the Bechgaard and Fabre salt families. We discuss the interplay between superconductivity, antiferromagnetism, and charge-density-wave fluctuations. The connection to recent experimental observations supporting unconventional pairing and the possibility of a triplet-spin order parameter for the superconducting phase is also presented.Comment: (v1) 30 pages, 13 figures; Review article for the 20th anniversary of high-Tc superconductivity, to appear in J. Low Temp. Phys. (v2) 1 Ref. adde

Properties of a Luttinger Liquid with Boundaries at Finite Temperature and Size

We use bosonization methods to calculate the exact finite-temperature single-electron Green's function of a spinful Luttinger liquid confined by open boundaries. The corresponding local spectral density is constructed and analyzed in detail. The interplay between boundary, finite-size and thermal effects are shown to dramatically influence the low-energy properties of the system. In particular, the well-known zero-temperature critical behavior in the bulk always crosses over to a boundary dominated regime in the vicinity of the Fermi level. Thermal fluctuations cause an enhanced depletion of spectral weight for small energies E, with the spectral density scaling as E^2 for E much less than the temperature. Consequences for photoemission experiments are discussed.Comment: 18 pages in revtex format including 5 embedded figures (using epsf). The latest complete postscript file is available from http://fy.chalmers.se/~eggert/papers/longlutt.ps or by request from [email protected]. To appear in Phys. Rev. B (Dec. 1997

Bond and charge density waves in the isotropic interacting two-dimensional quarter-filled band and the insulating state proximate to organic superconductivity

We report two surprising results regarding the nature of the spatial broken symmetries in the two-dimensional (2D), quarter-filled band with strong electron-electron interactions. First, in direct contradiction to the predictions of one-electron theory, we find a coexisting ``bond-order and charge density wave'' (BCDW) insulating ground state in the 2D rectangular lattice for all anisotropies, including the isotropic limit. Second, we find that the BCDW further coexists with a spin-density wave (SDW) in the range of large anisotropy. Further, in contrast to the interacting half-filled band, in the interacting quarter-filled band there are two transitions: first, a similar singlet-to-AFM/SDW transition for large anisotropy and second, an AFM/SDW-to-singlet transition at smaller anisotropy. We discuss how these theoretical results apply to the insulating states that are proximate to the superconducting states of 2:1 cationic charge-transfer solids (CTS). An important consequence of this work is the suggestion that organic superconductivity is related to the proximate Coulomb-induced BCDW, with the SDW that coexists for large anisotropies being also a consequence of the BCDW, rather than the driver of superconductivity.Comment: 29 pages, 18 eps figures. Revised with new appendices; to appear in Phys. Rev. B 62, Nov 15, 200