Arylation of 1,2,4-triazines in the presence of AlCl3

This paper presents a method for introducing toluene and bromobenzene moieties into 1,2,4-triazines as an alternative to cross-coupling reactions. It is demonstrated that the C=N bond of a wide range of 1,2,4-triazines undergoes addition of arenes in the presence of AlCl3. © 2014 Verlag der Zeitschrift für Naturforschung

59Co NMR study of the Co states in superconducting and anhydrous cobaltates

$^{59}$Co NMR spectra in oriented powders of Na$_{0.35}$CoO$_{2}$ and in its hydrated superconducting phase (HSC) Na$_{0.35}$CoO$_{2}$,1.3H$_{2}$O reveal a single electronic Co state with identical $T$ independent NMR shift tensor. These phases differ markedly from Na$_{0.7}$CoO$_{2}$, in which we resolve 3 types of Co sites. The large T variation of their spin susceptibilities $\chi ^{s}$ and the anisotropy of the orbital susceptibility $\chi ^{orb}$ allow us to conclude that charge disproportionation occurs, in a non magnetic Co$^{3+}$ and two magnetic sites with about 0.3 and 0.7 holes in the $t_{2g}$ multiplet. The data are consistent with those for the single Co site in the anhydrous and HSC phase assuming the expected Co$^{3.65+}$ charge.Comment: 5 pages, 3 figures, accepted for publication in Phys. Rev. Let

Strong light-matter coupling: parametric interactions in a cavity and free-space

We consider parametric interactions of laser pulses in a coherent macroscopic ensemble of resonant atoms, which are possible in the strong coupling regime of light-matter interaction. The spectrum condensation (lasing at collective vacuum Rabi sidebands) was studied in an active cavity configuration. Parametric interactions under the strong light-matter coupling were proved even in free space. In contrast to bichromatic beats in a cavity, they were shown to appear due to interference between polaritonic wave packets of different group velocities.Comment: 4 pages, 2 figure

Cyclotrimerization of 3-R-1,2,4-triazin-5(4H)-ones with cyclic ketones

New heterocyclic tetracyclic systems were synthesized. Interaction between 3-R-1,2,4-triazin-5(4H)-ones and cyclic ketones under acidic conditions leads to the formation of zwitterion derivatives of 5,6,7,8,9,10,11,12-octahydro-[1,2,4] triazino[1,6- f ]phenanthridine and 1,2,3,6,7,8-hexahydro-bicyclopenta[b,d] pyrido[1,2- f ][1,2,4]triazine. © 2010 Verlag der Zeitschrift für Naturforschung, Tübingen

Analysis of Transient Processes in a Radiophysical Flow System

Transient processes in a third-order radiophysical flow system are studied and a map of the transient process duration versus initial conditions is constructed and analyzed. The results are compared to the arrangement of submanifolds of the stable and unstable cycles in the Poincare section of the system studied.Comment: 3 pages, 2 figure

Electronic structure of GaAs1-xNx alloy by soft-X-ray absorption and emission: Origin of the reduced optical efficiency

The local electronic structure of N atoms in a diluted GaAs1-xNx (x=3%) alloy, in view of applications in optoelectronics, is determined for the first time using soft-X-ray absorption (SXA) and emission (SXE). Deviations from crystalline GaN, in particular in the conduction band, are dramatic. Employing the orbital character and elemental specificity of the SXE/SXA spectroscopies, we identify a charge transfer from the N atoms at the valence band maximum, reducing the overlap with the wavefunction in conduction band minimum, as the main factor limiting the optical efficiency of GaAs1-xNx alloys. Moreover, a k-conserving process of resonant inelastic x-ray scattering involving the L1 derived valence and conduction states is discovered.Comment: 3 pages, physica status solidi (Rapid Research Notes), in pres

Coherent interaction of laser pulses in a resonant optically dense extended medium under the regime of strong field-matter coupling

Nonstationary pump-probe interaction between short laser pulses propagating in a resonant optically dense coherent medium is considered. A special attention is paid to the case, where the density of two-level particles is high enough that a considerable part of the energy of relatively weak external laser-fields can be coherently absorbed and reemitted by the medium. Thus, the field of medium reaction plays a key role in the interaction processes, which leads to the collective behavior of an atomic ensemble in the strongly coupled light-matter system. Such behavior results in the fast excitation interchanges between the field and a medium in the form of the optical ringing, which is analogous to polariton beating in the solid-state optics. This collective oscillating response, which can be treated as successive beats between light wave-packets of different group velocities, is shown to significantly affect propagation and amplification of the probe field under its nonlinear interaction with a nearly copropagating pump pulse. Depending on the probe-pump time delay, the probe transmission spectra show the appearance of either specific doublet or coherent dip. The widths of these features are determined by the density-dependent field-matter coupling coefficient and increase during the propagation. Besides that, the widths of the coherent features, which appear close to the resonance in the broadband probe-spectrum, exceed the absorption-line width, since, under the strong-coupling regime, the frequency of the optical ringing exceeds the rate of incoherent relaxation. Contrary to the stationary strong-field effects, the density- and coordinate-dependent transmission spectra of the probe manifest the importance of the collective oscillations and cannot be obtained in the framework of the single-atom model.Comment: 10 pages, 8 figures, to be published in Phys. Rev.

Disturbances of electron density in the high latitude upper (F-region) ionosphere induced by X-mode HF pump waves from EISCAT UHF radar observations

The paper presents experimental results concerning disturbances of electron density in the high latitude ionosphere F-region, induced by powerfulHF radio waves (pump waves) with extraordinary (X-mode) polarization. The experiments were carried out at the EISCAT/Heating facility at Tromsø, Norway. The EISCAT UHF incoherent scatter radar (ISR), running at 930 MHz, co-located with a heating facility, was used to detect the disturbances of electron density. In the course of the experiments, the X-mode HF pump waves radiated into the F-region towards the magnetic zenith at different pump frequencies and ratios of the pump frequency to the critical frequency of the F2 layer.The effective radiated power was ERP = 360–820 MW. An increase in electron densities was found in a wide altitude range, giving rise to field-aligned ducts with enhanced electron density. The features and behavior of the ducts were investigated. It was revealed that the ducts are formed under quiet background geophysical conditions in a wide altitude range up to the upper altitude limit of EISCAT ISR measurements, when the pump frequencies were both below and above the critical frequency of the F2 layer (fH ≤ foF2 or fH > foF2). A plausible formation mechanism of the ducts is discussed.Представлены результаты экспериментальных исследований возмущений электронной концентрацииNe в высокоширотной F-области ионосферы, вызванные воздействием мощных КВ-радиоволн необыкновенной (Х-мода) поляризации. Эксперименты выполнялись на КВ нагревном стенде EISCAT/ Heating в г. Тромсё, Норвегия при эффективной мощности излучения 360–820 МВт. В качестве средства диагностики возмущений Ne использовался EISCAT радар некогерентного рассеяния радиоволн (НР) на частоте 930 МГц, пространственно совмещенный с КВ нагревным стендом. Обнаружено возрастание Ne в широком диапазоне высот, которое формирует каналы повышенной электронной плотности, вытянутые вдоль магнитного поля Земли. Исследованы характеристики и условия создания каналов. Обсуждается возможный механизм формирования каналов Ne при Х-нагреве высокоширотной F-области ионосферы