The Quantum Compass Model on the Square Lattice

Using exact diagonalizations, Green's function Monte Carlo simulations and high-order perturbation theory, we study the low-energy properties of the two-dimensional spin-1/2 compass model on the square lattice defined by the Hamiltonian $H = - \sum_{\bm{r}} (J_x \sigma_{\bm{r}}^x \sigma_{\bm{r} + \bm{e}_x}^x + J_z \sigma_{\bm{r}}^z \sigma_{\bm{r} + \bm{e}_z}^z)$. When $J_x\ne J_z$, we show that, on clusters of dimension $L\times L$, the low-energy spectrum consists of $2^L$ states which collapse onto each other exponentially fast with $L$, a conclusion that remains true arbitrarily close to $J_x=J_z$. At that point, we show that an even larger number of states collapse exponentially fast with $L$ onto the ground state, and we present numerical evidence that this number is precisely $2\times 2^L$. We also extend the symmetry analysis of the model to arbitrary spins and show that the two-fold degeneracy of all eigenstates remains true for arbitrary half-integer spins but does not apply to integer spins, in which cases eigenstates are generically non degenerate, a result confirmed by exact diagonalizations in the spin-1 case. Implications for Mott insulators and Josephson junction arrays are briefly discussed.Comment: 8 pages, 8 figure

Identification of an RVB liquid phase in a quantum dimer model with competing kinetic terms

Starting from the mean-field solution of a spin-orbital model of LiNiO$_2$, we derive an effective quantum dimer model (QDM) that lives on the triangular lattice and contains kinetic terms acting on 4-site plaquettes and 6-site loops. Using numerical exact diagonalizations and Green's function Monte Carlo simulations, we show that the competition between these kinetic terms leads to a resonating valence bond (RVB) state for a finite range of parameters. We also show that this RVB phase is connected to the RVB phase identified in the Rokhsar-Kivelson model on the same lattice in the context of a generalized model that contains both the 6--site loops and a nearest-neighbor dimer repulsion. These results suggest that the occurrence of an RVB phase is a generic feature of QDM with competing interactions.Comment: 8 pages, 12 figure

Fat fractal percolation and k-fractal percolation

We consider two variations on the Mandelbrot fractal percolation model. In the k-fractal percolation model, the d-dimensional unit cube is divided in N^d equal subcubes, k of which are retained while the others are discarded. The procedure is then iterated inside the retained cubes at all smaller scales. We show that the (properly rescaled) percolation critical value of this model converges to the critical value of ordinary site percolation on a particular d-dimensional lattice as N tends to infinity. This is analogous to the result of Falconer and Grimmett that the critical value for Mandelbrot fractal percolation converges to the critical value of site percolation on the same d-dimensional lattice. In the fat fractal percolation model, subcubes are retained with probability p_n at step n of the construction, where (p_n) is a non-decreasing sequence with \prod p_n > 0. The Lebesgue measure of the limit set is positive a.s. given non-extinction. We prove that either the set of connected components larger than one point has Lebesgue measure zero a.s. or its complement in the limit set has Lebesgue measure zero a.s.Comment: 27 pages, 3 figure

Dissolution and phosphate-induced transformation of ZnO nanoparticles in synthetic saliva probed by AGNES without previous solid-liquid separation. Comparison with UF-ICP-MS

The variation over time of free Zn2+ ion concentration in stirred dispersions of ZnO nanoparticles (ZnO NPs) prepared in synthetic saliva at pH 6.80 and 37 degrees C was followed in situ (without solid liquid separation step) with the electroanalytical technique AGNES (Absence of Gradients and Nernstian Equilibrium Stripping). Under these conditions, ZnO NPs are chemically unstable due to their reaction with phosphates. The initial stage of transformation (around 5-10 h) involves the formation of a metastable solid (presumably ZnHPO4), which later evolves into the more stable hopeite phase. The overall decay rate of ZnO NPs is significantly reduced in comparison with phosphate-free background solutions of the same ionic strength and pH. The effective equilibrium solubilities of ZnO (0.29-0.47 mg.L-1), as well as conditional excess-ligand stability constants and fractional distributions of soluble Zn species, were determined in the absence and presence of organic components. The results were compared with the conventional ultrafiltration and inductively coupled plasma-mass spectrometry (UF-ICP-MS) methodology. AGNES proves to be advantageous in terms of speed, reproducibility, and access to speciation information. KeywordsThis work was supported by the Spanish Ministry MINECOunder Grant No. CTM2016-78798 and European UnionSeventh Framework Programme FP7-NMP.2012.1.3-3 underGrant No. 310584 (NANoREG). FQ gratefully acknowledgesa grant from AGAUR

Large-N Limit of Crossing Probabilities, Discontinuity, and Asymptotic Behavior of Threshold Values in Mandelbrot's Fractal Percolation Process

We study Mandelbrot's percolation process in dimension $d \geq 2$. The process generates random fractal sets by an iterative procedure which starts by dividing the unit cube $[0,1]^d$ in $N^d$ subcubes, and independently retaining or discarding each subcube with probability $p$ or $1-p$ respectively. This step is then repeated within the retained subcubes at all scales. As $p$ is varied, there is a percolation phase transition in terms of paths for all $d \geq 2$, and in terms of $(d-1)$-dimensional "sheets" for all $d \geq 3$. For any $d \geq 2$, we consider the random fractal set produced at the path-percolation critical value $p_c(N,d)$, and show that the probability that it contains a path connecting two opposite faces of the cube $[0,1]^d$ tends to one as $N \to \infty$. As an immediate consequence, we obtain that the above probability has a discontinuity, as a function of $p$, at $p_c(N,d)$ for all $N$ sufficiently large. This had previously been proved only for $d=2$ (for any $N \geq 2$). For $d \geq 3$, we prove analogous results for sheet-percolation. In dimension two, Chayes and Chayes proved that $p_c(N,2)$ converges, as $N \to \infty$, to the critical density $p_c$ of site percolation on the square lattice. Assuming the existence of the correlation length exponent $\nu$ for site percolation on the square lattice, we establish the speed of convergence up to a logarithmic factor. In particular, our results imply that $p_c(N,2)-p_c=(\frac{1}{N})^{1/\nu+o(1)}$ as $N \to \infty$, showing an interesting relation with near-critical percolation.Comment: 24 pages, 2 figure