933 research outputs found
Optimality of broken extremals
In this paper we analyse the optimality of broken Pontryagin extremal for an
n-dimensional affine control system with a control parameter, taking values in
a k- dimensional closed ball. We prove the optimality of broken normal
extremals when n = 3 and the controllable vector fields form a contact
distribution, and when the Lie algebra of the controllable fields is locally
orthogonal to the singular locus and the drift does not belong to it. Moreover,
if k = 2, we show the optimality of any broken extremal even abnormal when the
controllable fields do not form a contact distribution in the point of
singularity.Comment: arXiv admin note: text overlap with arXiv:1610.0675
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Simplified risk model for waste management and environmental restoration activities
A Simplified Risk Model (SRM) is being developed to support environmental restoration and waste management (EM) planning activities. The SRM is designed to be able to quantitatively estimate risk for various EM alternatives within hours or days, given limited information about the processes covered within the alternative. The risk model covers radiological, chemical, and industrial risk from both accidents and normal, incident free operations. A simple risk equation is used to model accident risk. Normal, incident free operation risk is modeled using a multiplier on accident risk. Ongoing applications of the SRM are expected to lead to significant improvements to the model in the near future
Toward a simulation approach for alkene ring-closing metathesis : scope and limitations of a model for RCM
A published model for revealing solvent effects on the ring-closing metathesis (RCM) reaction of di-Et diallylmalonate 7 has been evaluated over a wider range of conditions, to assess its suitability for new applications. Unfortunately, the model is too flexible and the published rate consts. do not agree with exptl. studies in the literature. However, by fixing the values of important rate consts. and restricting the concn. ranges studied, useful conclusions can be drawn about the relative rates of RCM of different substrates, precatalyst concn. can be simulated accurately and the effect of precatalyst loading can be anticipated. Progress has also been made toward applying the model to precatalyst evaluation, but further modifications to the model are necessary to achieve much broader aims
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