7,222 research outputs found
Quantitative motor unit action potential analysis in two paraspinal muscles in sound adult warmblood horses
Splitting between Bright and Dark excitons in Transition Metal Dichalcogenide Monolayers
The optical properties of transition metal dichalcogenide monolayers such as
the two-dimensional semiconductors MoS and WSe are dominated by
excitons, Coulomb bound electron-hole pairs. The light emission yield depends
on whether the electron-hole transitions are optically allowed (bright) or
forbidden (dark). By solving the Bethe Salpeter Equation on top of wave
functions in density functional theory calculations, we determine the sign and
amplitude of the splitting between bright and dark exciton states. We evaluate
the influence of the spin-orbit coupling on the optical spectra and clearly
demonstrate the strong impact of the intra-valley Coulomb exchange term on the
dark-bright exciton fine structure splitting.Comment: 6 pages, 2 figure
Exciton states in monolayer MoSe2: impact on interband transitions
We combine linear and non-linear optical spectroscopy at 4K with ab initio
calculations to study the electronic bandstructure of MoSe2 monolayers. In
1-photon photoluminescence excitation (PLE) and reflectivity we measure a
separation between the A- and B-exciton emission of 220 meV. In 2-photon PLE we
detect for the A- and B-exciton the 2p state 180meV above the respective 1s
state. In second harmonic generation (SHG) spectroscopy we record an
enhancement by more than 2 orders of magnitude of the SHG signal at resonances
of the charged exciton and the 1s and 2p neutral A- and B-exciton. Our
post-Density Functional Theory calculations show in the conduction band along
the direction a local minimum that is energetically and in k-space
close to the global minimum at the K-point. This has a potentially strong
impact on the polarization and energy of the excitonic states that govern the
interband transitions and marks an important difference to MoS2 and WSe2
monolayers.Comment: 8 pages, 3 figure
Anwendung des Prinzips der nachhaltigen Entwicklung fĂŒr die Ressource Landschaft : Fallstudien zum Konzept der institutionellen Ressourcenregime
Properties of vector mesons at finite temperature -effective lagrangian approach-
The properties of -mesons at finite temperature () are examined with
an effective chiral lagrangian in which vector and axial-vector mesons are
included as massive Yang-Mills fields of the chiral symmetry. It is shown that,
at order, the effective mass is not changed but only the mixing effect in
vector and axial-vector correlator appears.Comment: 13 pages (REVTeX), two figures
Salmonella enterica Serotype Uganda Infection in New York City and Chicago1
Outbreaks associated with distinct strains of Salmonella enterica serotype Uganda, a rare serotype, occurred in New York City and Chicago during the summer of 2001. Both outbreaks were linked to eating ready-to-eat pork products. This serotype may emerge as a more frequent cause of human infections
Comment on current correlators in QCD at finite temperature
We address some criticisms by Eletsky and Ioffe on the extension of QCD sum
rules to finite temperature. We argue that this extension is possible, provided
the Operator Product Expansion and QCD-hadron duality remain valid at non-zero
temperature. We discuss evidence in support of this from QCD, and from the
exactly solvable two- dimensional sigma model O(N) in the large N limit, and
the Schwinger model.Comment: 10 pages, LATEX file, UCT-TP-208/94, April 199
Catalysis to discriminate single atoms from subnanometric ruthenium particles in ultra-high loading catalysts
We report a procedure for preparing ulta-high metal loading (10-20 % w/w Ru) Ru@C60 nanostructured catalysts comprising exclusively Ru single atoms. We show that by changing the Ru/C60 ratio and the nature of the solvent used during the synthesis, it is possible to increase the Ru loading up to 50% w/w, and to produce hetero-structures containing subnanometric Ru nanoparticles. Several techniques such as high-resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy â high angle annular dark field (STEM-HAADF), Raman spectroscopy, wideangle X-ray scattering (WAXS), extended X-ray absorption fine structure (EXAFS) and X-ray photoelectron spectroscopy (XPS) together with theoretical calculations were used to characterize these materials. At such high metal loading, the distinction between Ru single atoms and clusters is not trivial, even with this combination of techniques. We evaluated the catalytic properties of these materials for the hydrogenation of nitrobenzene and 2,3-dimethyl-2-butene. The catalysts containing only Ru single atoms are much less active for these reactions than the ones containing clusters. For nitrobenzene hydrogenation, this is because electro-deficient Ru single atoms and few atom Run clusters are not performant for H2 activation compared to larger clusters (n â„ 13), as shown by density functional theory (DFT) calculations. For the more crowded substrate 2,3-dimethyl-2-butene, DFT calculations have shown that this is due to steric hindrance. These simple tests can thus been used to distinguish samples containing metallic sub-nanometer nanoparticles. These novel catalysts are also extremely active for the hydrogenation of -substituted 2,3-dimethyl-2-butene
Molecular Epidemiology of Adenovirus Type 7 in the United States, 1966â20001
Genetic variation among 166 isolates of human adenovirus 7 (Ad7) obtained from 1966 to 2000 from the United States and Eastern Ontario, Canada, was determined by genome restriction analysis. Most (65%) isolates were identified as Ad7b. Two genome types previously undocumented in North America were also identified: Ad7d2 (28%), which first appeared in 1993 and was later identified throughout the Midwest and Northeast of the United States and in Canada; and Ad7h (2%), which was identified only in the U.S. Southwest in 1998 and 2000. Since 1996, Ad7d2 has been responsible for several civilian outbreaks of Ad7 disease and was the primary cause of a large outbreak of respiratory illness at a military recruit training center. The appearance of Ad7d2 and Ad7h in North America represents recent introduction of these viruses from previously geographically restricted areas and may herald a shift in predominant genome type circulating in the United States
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