Second-harmonic generation of ZnO nanoparticles synthesized by laser ablation of solids in liquids

We report the synthesis of small zinc oxide nanoparticles (ZnO NPs) based colloidal suspensions and the study of second-harmonic generation from aggregated ZnO NPs deposited on glass substrates. The colloidal suspensions were obtained using the laser ablation of solids in liquids technique, ablating a Zn solid target immersed in acetone as the liquid medium, with ns-laser pulses (1064 nm) of a Nd-YAG laser. The per pulse laser fluence, the laser repetition rate frequency and the ablation time were kept constant. The absorption evolution of the obtained suspensions was optically characterized through absorption spectroscopy until stabilization. Raman spectroscopy, SEM and HRTEM were used to provide evidence of the ZnO NPs structure. HRTEM results showed that 5–8 nm spheroids ZnO NPs were obtained. Strong second-harmonic signal is obtained from random ZnO monocrystalline NPs and from aggregated ZnO NPs, suggesting that the high efficiency of the nonlinear process may not depend on the NPs size or aggregation state

Ensayo sobre la evaluación de la extinción en hábitats extremos

Inference and estimation are the Achilles heel of many biological disciplines. The validation of results is the first step before taking any further decision. In Biodiversity studies the technical problems in validation are similar to those faced in other disciplines. The main difference with areas like medicine is that a validation error in the latter can easily take you to court, but very few responsibilities apart from moral or ethical ones generally derive from a faulty estimation or validation in Biodiversity. However, many political decisions concerning conservation issues, which in many cases affect powerful economic interests depend on the reliability of those biodiversity studies. Getting good, reliable information is not always easy, and this explains in part, the success of critical voices like Simon (1998) and Lomborg (2001). New methodologies like Population Viability Analysis has been developed to take advantage of the potential information contained in periodical sampling. We apply it to a peculiar and difficult to study fauna: the fauna of the aquatic subterranean environment. Lack of regular information and scarcity of the fauna due to difficulty to reach their proper habitat are the main problems that confront this analysis. However, despite its limitations, the analysis points towards a need to better understand the structure of the subterranean habitat from “an animal point of view” and the need of more regular sampling at the same time that the other environmental parameters are taken.La inferencia y la estima son el talón de Aquiles de muchas disciplinas biológicas. La validación de resultados es el primer paso antes de tomar decisiones ulteriores. En estudios de Biodiversidad los problemas técnicos de validación son semejantes a los que se enfrentan otras disciplinas. La principal diferencia con áreas como Medicina es que un error en validación en ésta última puede terminar fácilmente en el juzgado, pero muy pocas responsabilidades, aparte de la éticas o morales suelen afectar a estimas o validaciones defectuosas de Biodiversidad. Sin embargo, muchas decisiones políticas en relación a la conservación de especies y habitats, que en muchos casos implican poderosos intereses económicos, dependen precisamente de la fiabilidad de los estudios de biodiversidad. Obtener una información buena y fiable no es siempre fácil y explica, en parte, el éxito de voces críticas como Simon (1998) o Lomborg (2001). En este trabajo revisamos uno de los problemas de estimación en un habitat especialmente difícil, el medio subterráneo acuático. La carencia de información periódica y la escasez de esta fauna, debido principalmente a las dificultades de acceso a su habitat, son los principales problemas que hemos encontrado al tratar de aplicar análisis PVA (Populations Viability Analysis). No obstante, a pesar de la escasez de datos consistentes, este análisis pone de manifiesto la necesidad de entender mejor la estructura del habitat subterráneo, en lo que respecta a la distribución de su fauna y la necesidad de realizar más muestreos y de realizarlos con mayor regularidad

White dwarfs as test objects of Lorentz violations

In the present work the thermodynamical properties of bosonic and fermionic gases are analyzed under the condition that a modified dispersion relation is present. This last condition implies a breakdown of Lorentz symmetry. The implications upon the condensation temperature will be studied, as well, as upon other thermodynamical variables such as specific heat, entropy, etc. Moreover, it will be argued that those cases entailing a violation of time reversal symmetry of the motion equations could lead to problems with the concept of entropy. Concerning the fermionic case it will be shown that Fermi temperature suffers a modification due to the breakdown of Lorentz symmetry. The results will be applied to white dwarfs and the consequences upon the Chandrasekhar mass--radius relation will be shown. The possibility of resorting to white dwarfs for the testing of modified dispersion relations is also addressed. It will be shown that the comparison of the current observations against the predictions of our model allows us to discard some values of one of the parameters appearing in the modifications of the dispersion relation.Comment: Accepted in Classical and Quantum Gravitatio

Entropic Barriers, Frustration and Order: Basic Ingredients in Protein Folding

We solve a model that takes into account entropic barriers, frustration, and the organization of a protein-like molecule. For a chain of size $M$, there is an effective folding transition to an ordered structure. Without frustration, this state is reached in a time that scales as $M^{\lambda}$, with $\lambda\simeq 3$. This scaling is limited by the amount of frustration which leads to the dynamical selectivity of proteins: foldable proteins are limited to $\sim 300$ monomers; and they are stable in {\it one} range of temperatures, independent of size and structure. These predictions explain generic properties of {\it in vivo} proteins.Comment: 4 pages, 4 Figures appended as postscript fil

Continuous distribution of frequencies and deformed dispersion relations

The possibilities that, in the realm of the detection of the so--called deformed dispersion relation, a light source with a continuous distribution of frequencies offers is discussed. It will be proved that the presence of finite coherence length entails the emergence of a new term in the interference pattern. This is a novel trait, which renders a new possibility in the quest for bounds associated with these deformed dispersion relations.Comment: Accepted in Classical and Quantum Gravit

Habitat Constraints in Epikarstic Waters of an Iberian Peninsula Cave System

14 páginas, 6 figuras, 11 tables et al..The epikarstic waters of a restricted sector of the Ojo Guareña cave (north Iberian Peninsula) were investigated to characterize the physico-chemical variation in an annual cycle, to improve the scarce knowledge of the aquatic cave fauna on the Iberian Peninsula, to look for distribution patterns of species per habitat along the annual cycle, and to search for the environmental basis (either physico- or hydro-geochemical) that could explain species distribution in the epikarst. The habitats studied included all puddles and gours present in the sector selected making a total of 51 chemical and 42 biological samples for the entire cycle. The waters show no appreciable contaminationand exhibit small chemical variations throughout the year which are patently affected by external weather conditions. The 53 taxa found belong to ten higher taxonomic groups (Oligochaeta, Turbellaria, Mollusca, Copepoda, Ostracoda, Isopoda, Bathynellacea, Tardigrada, Acarina and Cnidaria), and consist mainly of crustacea with a total of 27 species. Fourteen species were stygobionts (belonging to ten genera), nine of which are new to science and ten of which are endemic. Cave pools that appeared to be more stable in terms of water volume and mineralization, had a lower pCO2 and were carbonate oversaturated, harboured the greatest number of taxa. It is these pools that can maintain strictly cave dwelling species. Pools with lower levels of mineralization and greater water volume fluctuations had a lower diversity of fauna and in general lacked stygobiotic species.Projects PASCALIS EVK2-CT-2001-00121; Convenio Junta de Castilla y León-CSIC (2002-2004) and BTE2002-04492-C02-02.Peer reviewe

Hydrachnidia (Acari, Parasitengona) de la Comunidad de Madrid

This paper includes a list of the water mites (Acari, Parasitengona, Hydrachnidia) of Comunidad de Madrid, with geographical location and habitat.Se incluye un listado de los ácaros acuáticos (Acari, Parasitengona, Hydrachnidia) de la Comunidad de Madrid, incluyendo localización geográfica y habitat

Lista de estigofauna conocida en la Comunidad de Madrid

Knowledge of Comunidad de Madrid stygofauna is very scarce due to the fact that very few researchers have paid attention to it. The data comes from sporadic sampling, mainly with a taxonomic purpose. In this paper we include all taxonomic information available on subterranean aquatic invertebrates, found in caves, artificial wells and interstitial environment associated with streams of Comunidad de Madrid.El conocimiento de la estigofauna de la Comunidad de Madrid es muy escaso debido a que ha recibido muy poca atención por parte de los investigadores. Se conocen muy pocos datos que proceden de muestreos esporádicos y puntuales realizados, en la mayor parte de los casos, con objetivos taxonómicos. En este trabajo hemos intentado recoger toda la información publicada acerca de las especies de invertebrados acuáticos subterráneos, en sentido amplio, encontrados en cuevas, pozos artificiales, surgencias y medio intersticial asociado a ríos de la Comunidad de Madrid

Folding in two-dimenensional off-lattice models of proteins

Model off-lattice sequences in two dimensions are constructed so that their native states are close to an on-lattice target. The Hamiltonian involves the Lennard-Jones and harmonic interactions. The native states of these sequences are determined with a high degree of certainty through Monte Carlo processes. The sequences are characterized thermodynamically and kinetically. It is shown that the rank-ordering-based scheme of the assignment of contact energies typically fails in off-lattice models even though it generates high stability of on-lattice sequences. Similar to the on-lattice case, Go-like modeling, in which the interaction potentials are restricted to the native contacts in a target shape, gives rise to good folding properties. Involving other contacts deteriorates these properties.Comment: REVTeX, 9 pages, 8 EPS figure