668 research outputs found
Spin Transport in Disordered Two-Dimensional Hopping Systems with Rashba Spin-Orbit Interaction
The influence of Rashba spin-orbit interaction on the spin dynamics of a
topologically disordered hopping system is studied in this paper. This is a
significant generalization of a previous investigation, where an ordered
(polaronic) hopping system has been considered instead. It is found, that in
the limit, where the Rashba length is large compared to the typical hopping
length, the spin dynamics of a disordered system can still be described by the
expressions derived for an ordered system, under the provision that one takes
into account the frequency dependence of the diffusion constant and the
mobility (which are determined by charge transport and are independent of
spin). With these results we are able to make explicit the influence of
disorder on spin related quantities as, e.g., the spin life-time in hopping
systems.Comment: 12 pages, 6 figures, some clarifications adde
Relationship between solidification microstructure and hot cracking susceptibility for continuous casting of low-carbon and high-strength low-alloyed steels: A phase-field study
© The Minerals, Metals & Materials Society and ASM International 2013Hot cracking is one of the major defects in continuous casting of steels, frequently limiting the productivity. To understand the factors leading to this defect, microstructure formation is simulated for a low-carbon and two high-strength low-alloyed steels. 2D simulation of the initial stage of solidification is performed in a moving slice of the slab using proprietary multiphase-field software and taking into account all elements which are expected to have a relevant effect on the mechanical properties and structure formation during solidification. To account for the correct thermodynamic and kinetic properties of the multicomponent alloy grades, the simulation software is online coupled to commercial thermodynamic and mobility databases. A moving-frame boundary condition allows traveling through the entire solidification history starting from the slab surface, and tracking the morphology changes during growth of the shell. From the simulation results, significant microstructure differences between the steel grades are quantitatively evaluated and correlated with their hot cracking behavior according to the Rappaz-Drezet-Gremaud (RDG) hot cracking criterion. The possible role of the microalloying elements in hot cracking, in particular of traces of Ti, is analyzed. With the assumption that TiN precipitates trigger coalescence of the primary dendrites, quantitative evaluation of the critical strain rates leads to a full agreement with the observed hot cracking behavior. © 2013 The Minerals, Metals & Materials Society and ASM International
Doping, density of states and conductivity in polypyrrole and poly(p-phenylene vinylene)
The evolution of the density of states (DOS) and conductivity as function of
well controlled doping levels in OC_1C_10-poly(p-phenylene vinylene)
[OC_1C_10-PPV] doped by FeCl_3 and PF_6, and PF_6 doped polypyrrole (PPy-PF_6
have been investigated. At a doping level as high as 0.2 holes per monomer, the
former one remains non-metallic, while the latter crosses the metal-insulator
transition. In both systems a similar almost linear increase in DOS as function
of charges per unit volume c* has been observed from the electrochemical gated
transistor data. In PPy-PF_6, when compared to doped OC_1C_10-PPV, the energy
states filled at low doping are closer to the vacuum level; by the higher c* at
high doping more energy states are available, which apparently enables the
conduction to change to metallic. Although both systems on the insulating side
show log(sigma) proportional to T^-1/4 as in variable range hopping, for highly
doped PPy-PF_6 the usual interpretation of the hopping parameters leads to
seemingly too high values for the density of states.Comment: 4 pages (incl. 6 figures) in Phys. Rev.
Theory of electric-field-induced spin accumulation and spin current in the two-dimensional Rashba model
Based on the spin-density-matrix approach, both the electric-field-induced
spin accumulation and the spin current are systematically studied for the
two-dimensional Rashba model. Eigenmodes of spin excitations give rise to
resonances in the frequency domain. Utilizing a general and physically
well-founded definition of the spin current, we obtain results that differ
remarkably from previous findings. It is shown that there is a close
relationship between the spin accumulation and the spin current, which is due
to the prescription of a quasi-chemical potential and which does not result
from a conservation law. Physical ambiguities are removed that plagued former
approaches with respect to a spin-Hall current that is independent of the
electric field. For the clean Rashba model, the intrinsic spin-Hall
conductivity exhibits a logarithmic divergency in the low-frequency regime.Comment: 19 pages including figure
Ac hopping conduction at extreme disorder takes place on the percolating cluster
Simulations of the random barrier model show that ac currents at extreme
disorder are carried almost entirely by the percolating cluster slightly above
threshold; thus contradicting traditional theories contributions from isolated
low-activation-energy clusters are negligible. The effective medium
approximation in conjunction with the Alexander-Orbach conjecture leads to an
excellent analytical fit to the universal ac conductivity with no nontrivial
fitting parameters
Raman spectra of olivine measured in different planetary environments
Missions to bodies of our solar system are coming up and imply new instrumentation to be applied remotely and in situ. In ESA’s ExoMars mission the Raman Laser Spectrometer (RLS) will identify minerals and organic compounds in Martian surface rocks and soils. Here we present the results of a Raman study of different olivines with variable Fo and Fa contents. We chose olivine because it is a rock forming mineral and is found as an abundant mineral in Martian meteorites. We determined the
Raman spectra in different environmental conditions that include vacuum, 8 mbar CO2 atmosphere and temperatures between room temperature and 10 K.
These environmental conditions resemble those on asteroids as well as on Mars and Moon. Thus our study investigates the influence of these varying conditions on the position and band width of the Raman lines, which is to be known when such investigations are performed in future space missions
Polarons and slow quantum phonons
We describe the formation and properties of Holstein polarons in the entire
parameter regime. Our presentation focuses on the polaron mass and radius,
which we obtain with an improved numerical technique. It is based on the
combination of variational exact diagonalization with an improved construction
of phonon states, providing results even for the strong coupling adiabatic
regime. In particular we can describe the formation of large and heavy
adiabatic polarons. A comparison of the polaron mass for the one and three
dimensional situation explains how the different properties in the static
oscillator limit determine the behavior in the adiabatic regime. The transport
properties of large and small polarons are characterized by the f-sum rule and
the optical conductivity. Our calculations are approximation-free and have
negligible numerical error. This allows us to give a conclusive and impartial
description of polaron formation. We finally discuss the implications of our
results for situations beyond the Holstein model.Comment: Final version, 10 pages, 10 figure
Characteristic features of anharmonic effects in the lattice dynamics of fcc metals
The dispersion in the entire Brillouin zone and the temperature dependence
(right up to the melting temperature) of the anharmonic frequency shift and
phonon damping in a number of fcc metals is investigated on the basis of
microscopic calculations. It is found that the anharmonic effects depend
sharply on the wave vector in the directions -X, X-W, and -L
and, in contrast to bcc metals, the magnitude of the effects is not due to the
softness of the initial phonon spectrum. It is shown that the relative
frequency shifts and the phonon damping near melting do not exceed 10-20%. The
relative role of various anharmonic processes is examined, and the relation
between the results obtained and existing experimental data is discussed.Comment: 4 pages, 5 figures, LaTe
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