772 research outputs found
A coherent synchrotron X-ray microradiology investigation of bubble and droplet coalescence
Microradiology with coherent X-rays is shown to be very effective in revealing interfaces in multiphase systems and in particular gas bubbles. Its use has been tested in the study of bubble colescence validating the results with a simple theoretical analysis based on mass conservation
Nomenclature for the C60-Ih and C70-D5h(6) fullerenes (IUPAC Recommendations 2002)
Fullerenes are a new allotrope of carbon characterized by a closed-cage structure consisting of an even number of three-coordinate carbon atoms devoid of hydrogen atoms. This class was originally limited to closed-cage structures with 12 isolated five-membered rings, the rest being six-membered rings. Although it was recognized that existing organic ring nomenclature could be used for these structures, the resulting names would be extremely unwieldy and inconvenient for use. At the same time it was also recognized that established organic nomenclature principles could be used, or adapted, to provide a consistent nomenclature for this unique class of compounds based on the class name fullerene. However, it was necessary to develop an entirely new method for uniquely numbering closed-cage systems. This paper describes IUPAC recommendations for naming and uniquely numbering the two most common fullerenes with isolated pentagons, the icosahedral C60 fullerene and a D5h-C70 fullerene. It also describes recommendations for adapting organic nomenclature principles for naming fullerenes with nonclosed-cage structures, heterofullerenes, derivatives formed by substitution of hydrofullerenes, and the fusion of organic rings or ring systems to the fullerene cage. Finally, this paper suggests methods for describing structures consisting of two or more fullerene units and for denoting configurations of chiral fullerenes and their derivative
Synchrotron radiography and x-ray topography studies of hexagonal habitus SiC bulk crystals
Phase-sensitive synchrotron radiation (SR) radiography was combined with x-ray diffraction topography to study structural defects of SiC crystals. The particular bulk SiC crystals examined had a low micropipe density and a hexagonal habitus composed of prismatic, pyramidal, and basal faces well developed. X-ray diffraction topography images of the sliced (0001) wafers, which were formed due to the complex lattice distortions associated with defective boundaries, demonstrated the existence of two-dimensional defective boundaries in the radial direction, normal to the (0001) planes. In particular, those parallel to the 〈1120〉 directions extended rather far from the seed. On the other hand, by phase-sensitive SR radiography the effect of micropipe collection was detected. Micropipes grouped mostly in the vicinities of the defective boundaries but rarely appeared between groups. Some general remarks about possible reasons for the development of such peculiar defect structures were mad
Critical Properties in Photoemmision Spectra for One Dimensional Orbitally Degenerate Mott Insulator
Critical properties in photoemission spectra for the one-dimensional Mott
insulator with orbital degeneracy are studied by exploiting the integrable {\it
t-J} model, which is a supersymmetric generalization of the SU() degenerate
spin model. We discuss the critical properties for the holon dispersion as well
as the spinon dispersions, by applying the conformal field theory analysis to
the exact finite-size energy spectrum. We study the effect of orbital-splitting
on the spectra by evaluating the momentum-dependent critical exponents.Comment: 8 pages, REVTeX, 2 figures(available upon request), accepted for
publication in JPSJ 68 (1999) No.
Spectral function of the 1D Hubbard model in the limit
We show that the one-particle spectral functions of the one-dimensional
Hubbard model diverge at the Fermi energy like
in the limit. The Luttinger liquid behaviour
, where as ,
should be limited to (for large but
finite), which shrinks to a single point, ,in that limit.
The consequences for the observation of the Luttinger liquid behaviour in
photoemission and inverse photoemission experiments are discussed.Comment: 4 pages, RevTeX, 2 figures on reques
Interpretation of Photoemission Spectra of (TaSe4)2I as Evidence of Charge Density Wave Fluctuations
The competition between different and unusual effects in
quasi-one-dimensional conductors makes the direct interpretation of
experimental measurements of these materials both difficult and interesting. We
consider evidence for the existence of large charge-density-wave fluctuations
in the conducting phase of the Peierls insulator (TaSe4)2I, by comparing the
predictions of a simple Lee, Rice and Anderson theory for such a system with
recent angle-resolved photoemission spectra. The agreement obtained suggests
that many of the unusual features of these spectra may be explained in this
way. This view of the system is contrasted with the behaviour expected of a
Luttinger liquid.Comment: Archive copy of published paper. 19 pages, 12 figures, uses IOP
macro
Properties of a Luttinger Liquid with Boundaries at Finite Temperature and Size
We use bosonization methods to calculate the exact finite-temperature
single-electron Green's function of a spinful Luttinger liquid confined by open
boundaries. The corresponding local spectral density is constructed and
analyzed in detail. The interplay between boundary, finite-size and thermal
effects are shown to dramatically influence the low-energy properties of the
system. In particular, the well-known zero-temperature critical behavior in the
bulk always crosses over to a boundary dominated regime in the vicinity of the
Fermi level. Thermal fluctuations cause an enhanced depletion of spectral
weight for small energies E, with the spectral density scaling as E^2 for E
much less than the temperature. Consequences for photoemission experiments are
discussed.Comment: 18 pages in revtex format including 5 embedded figures (using epsf).
The latest complete postscript file is available from
http://fy.chalmers.se/~eggert/papers/longlutt.ps or by request from
[email protected]. To appear in Phys. Rev. B (Dec. 1997
Microscopic theory of the pseudogap and Peierls transition in quasi-one-dimensional materials
The problem of deriving from microscopic theory a Ginzburg-Landau free energy
functional to describe the Peierls or charge-density-wave transition in
quasi-one-dimensional materials is considered. Particular attention is given to
how the thermal lattice motion affects the electronic states. Near the
transition temperature the thermal lattice motion produces a pseudogap in the
density of states at the Fermi level. Perturbation theory diverges and the
traditional quasi-particle or Fermi liquid picture breaks down. The pseudogap
causes a significant modification of the coefficients in the Ginzburg-Landau
functional from their values in the rigid lattice approximation, which neglects
the effect of the thermal lattice motion. To appear in Physical Review B.Comment: 21 pages, RevTeX, 5 figures in uuencoded compressed tar fil
Synchrotron radiography and x-ray topography studies of hexagonal habitus SiC bulk crystals
Phase-sensitive synchrotron radiation (SR) radiography was combined with x-ray diffraction topography to study structural defects of SiC crystals. The particular bulk SiC crystals examined had a low micropipe density and a hexagonal habitus composed of prismatic, pyramidal, and basal faces well developed. X-ray diffraction topography images of the sliced (0001) wafers, which were formed due to the complex lattice distortions associated with defective boundaries, demonstrated the existence of two-dimensional defective boundaries in the radial direction, normal to the (0001) planes. In particular, those parallel to the directions extended rather far from the seed. On the other hand, by phase-sensitive SR radiography the effect of micropipe collection was detected. Micropipes grouped mostly in the vicinities of the defective boundaries but rarely appeared between groups. Some general remarks about possible reasons for the development of such peculiar defect structures were made
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