5 research outputs found
Π’Π΅Ρ Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ΅ΡΠ΅Π½ΠΈΡ Π΄Π»Ρ ΡΡΡΠΎΠΈΡΠ΅Π»ΡΡΡΠ²Π° ΡΠ°Π·Π²Π΅Π΄ΠΎΡΠ½ΠΎΠΉ Π²Π΅ΡΡΠΈΠΊΠ°Π»ΡΠ½ΠΎΠΉ ΡΠΊΠ²Π°ΠΆΠΈΠ½Ρ Π³Π»ΡΠ±ΠΈΠ½ΠΎΠΉ 2520 ΠΌΠ΅ΡΡΠΎΠ² Π½Π° Π½Π΅ΡΡΠ΅Π³Π°Π·ΠΎΠ²ΠΎΠΌ ΠΌΠ΅ΡΡΠΎΡΠΎΠΆΠ΄Π΅Π½ΠΈΠΈ (ΠΡΠ°ΡΠ½ΠΎΡΡΡΠΊΠΈΠΉ ΠΊΡΠ°ΠΉ)
ΠΠ±ΡΠ΅ΠΊΡΠΎΠΌ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΡΠ²Π»ΡΠ΅ΡΡΡ Π½Π΅ΡΡΠ΅Π³Π°Π·ΠΎΠ²ΠΎΠΌ ΠΌΠ΅ΡΡΠΎΡΠΎΠΆΠ΄Π΅Π½ΠΈΠ΅ ΠΡΠ°ΡΠ½ΠΎΡΡΡΠΊΠΎΠ³ΠΎ ΠΊΡΠ°Ρ. Π¦Π΅Π»Ρ ΡΠ°Π±ΠΎΡΡ - ΠΏΡΠΎΠ΅ΠΊΡΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΏΡΠΎΡΠ΅ΡΡΠΎΠ² Π±ΡΡΠ΅Π½ΠΈΡ ΠΈ Π·Π°ΠΊΠ°Π½ΡΠΈΠ²Π°Π½ΠΈΡ ΡΠΊΠ²Π°ΠΆΠΈΠ½Ρ. Π ΠΏΡΠΎΡΠ΅ΡΡΠ΅ ΡΠ°Π±ΠΎΡΡ Π±ΡΠ» ΡΠΎΡΡΠ°Π²Π»Π΅Π½ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΠΉ ΠΏΡΠΎΠ΅ΠΊΡ Π½Π° ΡΡΡΠΎΠΈΡΠ΅Π»ΡΡΡΠ²ΠΎ ΡΠ°Π·Π²Π΅Π΄ΠΎΡΠ½ΠΎΠΉ Π²Π΅ΡΡΠΈΠΊΠ°Π»ΡΠ½ΠΎΠΉ ΡΠΊΠ²Π°ΠΆΠΈΠ½Ρ Π³Π»ΡΠ±ΠΈΠ½ΠΎΠΉ 2520 ΠΌΠ΅ΡΡΠΎΠ² Π½Π° Π½Π΅ΡΡΠ΅Π³Π°Π·ΠΎΠ²ΠΎΠΌ ΠΌΠ΅ΡΡΠΎΡΠΎΠΆΠ΄Π΅Π½ΠΈΠΈ ΠΡΠ°ΡΠ½ΠΎΡΡΡΠΊΠΎΠ³ΠΎ ΠΊΡΠ°Ρ. Π ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠ΅ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ Π±ΡΠ»ΠΈ ΡΠΏΡΠΎΠ΅ΠΊΡΠΈΡΠΎΠ²Π°Π½Ρ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ΅ΡΠ΅Π½ΠΈΡ ΡΡΡΠΎΠΈΡΠ΅Π»ΡΡΡΠ²ΠΎ ΡΠΊΠ²Π°ΠΆΠΈΠ½Ρ. ΠΠΏΠΈΡΠ°Π½Ρ ΠΊΠΎΠ½ΡΡΡΡΠΊΡΠΈΠ²Π½ΡΠ΅, ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΠΈ ΡΠ΅Ρ
Π½Π΅ΠΊΠΎ - ΡΠΊΠΎΠ½ΠΎΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»ΠΈ.The object of study is the oil and gas condensate field of the Krasnoyarsk Territory. The purpose of the work is the design of technological processes for drilling and well completion. In the process, a technological project was drawn up for the construction of an exploratory vertical well with a depth of 2520 meters at the oil and gas condensate field in the Krasnoyarsk Territory. As a result of the study, technological solutions for well construction were designed. The constructive, technological and techno-economic indicators are described
Development of new chemistry for a dual use hydrazine thruster, switchable room temperature ionic liquids, a study of silane grafting to polyethylene and its model compounds, synthesis of the novel hydrazine replacement fuel molecules 1,1-dimethyl-2-[2-azidoethyl]hydrazine and 1,1-dimethyl-2-[2-azidoethyl]hydrazone
This thesis focuses on the development of new compounds or new processes that are more environmentally friendly and economical than those currently in use. The decomposition of hydrazine, a well established liquid rocket fuel for both the aerospace and defense industries, to the product ammonia is studied. Control of this reaction will allow hydrazine to be used as a propellant for both chemical and electric propulsion. From this a dual stage thruster will be developed that will be more efficient than current systems decreasing the amount of propellant needed and allowing for either a larger mission payload or a longer duration of individual missions. Hydrazine, while beneficial and well established, is also highly toxic, so other work in this thesis focuses on the synthesis of the novel molecule 1,1-dimethyl-2-[2-azidoethyl]hydrazine or DMAEH and its hydrazone intermediate 1,1-dimethyl-2-[2-azidoethyl]hydrazone or De-DMAEH as less toxic hydrazine replacements.
Novel "switchable" ionic liquids have been investigated in this research. These are solvents that can change from molecular liquids to ionic liquids and back, simply with the addition or removal of COβ from the system. They can be used for a variety of applications, including as solvents for a reaction and separation system. Due to the recyclable nature of these solvents, waste is decreased making their development and implementation both environmentally and economically beneficial. Finally, the grafting reaction of vinyl silanes onto a hydrocarbon backbone is investigated. Fundamental work is being performed to study the graft distribution, selectivity and mechanism by which this reaction occurs. A more thorough understanding of how this reaction proceeds will allow for the development of a more efficient industrial process.Ph.D.Committee Chair: Liotta, Charles L.; Committee Co-Chair: Eckert, Charles A.; Committee Member: Collard, David; Committee Member: Hernandez, Rigoberto; Committee Member: Teja, Amy
One-component, switchable ionic liquids derived from siloxylated amines
A new class of one-component, thermally reversible, neutral to ionic liquid solvents derived from siloxylated amines is presented and characterized