(2+1) resonant enhanced multiphoton ionization of H_2 via the E, F^(1)Σ^+_g state

In this paper, we report the results of ab initio calculations of photoelectron angular distributions and vibrational branching ratios for the (2+1) REMPI of H_2 via the E, F^(1)Σ^+_g state, and compare these with the experimental data of Anderson et al. [Chem. Phys. Lett. 105, 22 (1984)]. These results show that the observed non‐Franck–Condon behavior is predominantly due to the R dependence of the transition matrix elements, and to a lesser degree to the energy dependence. This work presents the first molecular REMPI study employing a correlated wave function to describe the Rydberg–valence mixing in the resonant intermediate state

China's energy consumption in the building sector: A Statistical Yearbook-Energy Balance Sheet based splitting method

China's energy consumption in the building sector (BEC) is not counted as a separate type of energy consumption, but divided and mixed in other sectors in China's statistical system. This led to the lack of historical data on China's BEC. Moreover, previous researches' shortages such as unsystematic research on BEC, various estimation methods with complex calculation process, and difficulties in data acquisition resulted in “heterogeneous” of current BEC in China. Aiming to these deficiencies, this study proposes a set of China building energy consumption calculation method (CBECM) by splitting out the building related energy consumption mixed in other sectors in the composition of China Statistical Yearbook-Energy Balance Sheet. Then, China's BEC from 2000 to 2014 are estimated using CBECM and compared with other studies. Results show that, from 2000 to 2014, China's BEC increased 1.7 times, rising from 301 to 814 million tons of standard coal consumed, with the BEC percentage of total energy consumption stayed relatively stable between 17.7% and 20.3%. By comparison, we find that our results are reliable and the CBECM has the following advantages over other methods: data source is authoritative, calculation process is concise, and it is easy to obtain time series data on BEC etc. The CBECM is particularly suitable for the provincial government to calculate the local BEC, even in the circumstance with statistical yearbook available only

China's building stock estimation and energy intensity analysis

Reliable and objective data regarding building stock is essential for predicting and analyzing energy demand and carbon emission. However, China's building stock data is lacking. This study proposes a set of China building floor space estimation method (CBFSM) based on the improved building stock turnover model. Then it measures China's building stocks by vintage and type from 2000 to 2015, as well as building energy intensity (national level and provincial level) and energy-efficient buildings. Results showed that total building stocks increased significantly, rising from 35.2 billion m2 in 2000 to 63.6 billion m2 in 2015, with the average growth rate 4.0%. The deviations were well below 10% by comparing with China Population Census, which validated the reliability of CBFSM and the results. As for energy intensity, urban dwellings and rural dwellings showed relatively stable and increasing trend respectively. The commercial building energy intensity saw a downward trend during “12th Five Year Plan” period. This indicated the effectiveness of building energy efficiency work for commercial buildings since 2005.38.6 billion m2 residential dwellings and 5.7 billion m2 commercial buildings still need to be retrofitted in future. CBFSM can overcome shortages in previous studies. It can also provide Chinese government with technical support and data evidence to promote the building energy efficiency work

Non-adiabatic Ring Polymer Molecular Dynamics in the Phase Space of the SU(N) Lie Group

We derive the non-adiabatic ring polymer molecular dynamics (RPMD) approach in the phase space of the SU(N) Lie Group. This method, which we refer to as the spin mapping non-adiabatic RPMD (SM-NRPMD), is based on the spin-mapping formalism for the electronic degrees of freedom (DOFs) and ring polymer path-integral description for the nuclear DOFs. Using the Stratonovich-Weyl transform for the electronic DOFs, and the Wigner transform for the nuclear DOFs, we derived an exact expression of the Kubo-transformed time-correlation function (TCF). We further derive the spin mapping non-adiabatic Matsubara dynamics using the Matsubara approximation that removes the high frequency nuclear normal modes in the TCF and derive the SM-NRPMD approach from the non-adiabatic Matsubara dynamics by discarding the imaginary part of the Liouvillian. The SM-NRPMD method has numerical advantages compared to the original NRPMD method based on the MMST mapping formalism, due to a more natural mapping using the SU(N) Lie Group that preserves the symmetry of the original system. We numerically compute the Kubo-transformed position auto-correlation function and electronic population correlation function for three-state model systems. The numerical results demonstrate the accuracy of the SM-NRPMD method, which outperforms the original MMST-based NRPMD. We envision that the SM-NRPMD method will be a powerful approach to simulate electronic non-adiabatic dynamics and nuclear quantum effects accurately

When and where do you want to hide? Recommendation of location privacy preferences with local differential privacy

In recent years, it has become easy to obtain location information quite precisely. However, the acquisition of such information has risks such as individual identification and leakage of sensitive information, so it is necessary to protect the privacy of location information. For this purpose, people should know their location privacy preferences, that is, whether or not he/she can release location information at each place and time. However, it is not easy for each user to make such decisions and it is troublesome to set the privacy preference at each time. Therefore, we propose a method to recommend location privacy preferences for decision making. Comparing to existing method, our method can improve the accuracy of recommendation by using matrix factorization and preserve privacy strictly by local differential privacy, whereas the existing method does not achieve formal privacy guarantee. In addition, we found the best granularity of a location privacy preference, that is, how to express the information in location privacy protection. To evaluate and verify the utility of our method, we have integrated two existing datasets to create a rich information in term of user number. From the results of the evaluation using this dataset, we confirmed that our method can predict location privacy preferences accurately and that it provides a suitable method to define the location privacy preference

Parent training for preschool ADHD: a randomized controlled trial of specialized and generic programs

BackgroundThe New Forest Parenting Package' (NFPP), an 8-week home-based intervention for parents of preschoolers with attention-deficit/hyperactivity disorder (ADHD), fosters constructive parenting to target ADHD-related dysfunctions in attention and impulse control. Although NFPP has improved parent and laboratory measures of ADHD in community samples of children with ADHD-like problems, its efficacy in a clinical sample, and relative to an active treatment comparator, is unknown. The aims are to evaluate the short- and long-term efficacy and generalization effects of NFPP compared to an established clinic-based parenting intervention for treating noncompliant behavior [Helping the Noncompliant Child' (HNC)] in young children with ADHD. MethodsA randomized controlled trial with three parallel arms was the design for this study. A total of 164 3-4-year-olds, 73.8% male, meeting DSM-IV ADHD diagnostic criteria were randomized to NFPP (N=67), HNC (N=63), or wait-list control (WL, N=34). All participants were assessed at post-treatment. NFPP and HNC participants were assessed at follow-up in the next school year. Primary outcomes were ADHD ratings by teachers blind to and uninvolved in treatment, and by parents. Secondary ADHD outcomes included clinician assessments, and laboratory measures of on-task behavior and delay of gratification. Other outcomes included parent and teacher ratings of oppositional behavior, and parenting measures. (Trial name: Home-Based Parent Training in ADHD Preschoolers; Registry: ClinicalTrials.gov Identifier: NCT01320098; URL: ). ResultsIn both treatment groups, children's ADHD and ODD behaviors, as well as aspects of parenting, were rated improved by parents at the end of treatment compared to controls. Most of these gains in the children's behavior and in some parenting practices were sustained at follow-up. However, these parent-reported improvements were not corroborated by teacher ratings or objective observations. NFPP was not significantly better, and on a few outcomes significantly less effective, than HNC. ConclusionsThe results do not support the claim that NFPP addresses putative dysfunctions underlying ADHD, bringing about generalized change in ADHD, and its underpinning self-regulatory processes. The findings support documented difficulties in achieving generalization across nontargeted settings, and the importance of using blinded measures to provide meaningful assessments of treatment effects

Dual-task motor performance with a tongue-operated assistive technology compared with hand operations

<p>Abstract</p> <p>Background</p> <p>To provide an alternative motor modality for control, navigation, and communication in individuals suffering from impairment or disability in hand functions, a Tongue Drive System (TDS) has been developed that allows for real time tracking of tongue motion in an unobtrusive, wireless, and wearable device that utilizes the magnetic field generated by a miniature disk shaped magnetic tracer attached to the tip of the tongue. The purpose of the study was to compare the influence of a concurrent motor or cognitive task on various aspects of simple movement control between hand and tongue using the TDS technology.</p> <p>Methods</p> <p>Thirteen young able-bodied adults performed rapid and slow goal-directed movements of hand and tongue (with TDS) with and without a concurrent motor (hand or tongue) or cognitive (arithmetic and memory) task. Changes in reaction time, completion time, speed, correctness, accuracy, variability of displacement, and variability of time due to the addition of a concurrent task were compared between hand and tongue.</p> <p>Results</p> <p>The influence of an additional concurrent task on motor performance was similar between the hand and tongue for slow movement in controlling their displacement. In rapid movement with a concurrent motor task, most aspects of motor performance were degraded in hand, while tongue speed during rapid continuous task was maintained. With a concurrent cognitive task, most aspects of motor performance were degraded in tongue, while hand accuracy during the rapid discrete task and hand speed during the rapid continuous task were maintained.</p> <p>Conclusion</p> <p>Rapid goal-directed hand and tongue movements were more consistently susceptible to interference from concurrent motor and cognitive tasks, respectively, compared with the other movement.</p