Controlled Interfacial Reactions and Superior Mechanical Properties of High Energy Ball Milled/Spark Plasma Sintered Ti–6Al–4V–Graphene Composite

Ball milling process has become one of the effective methods for dispersing graphene nanoplates (GNPs) uniformly into matrix; however, there are often serious issues of structural integrity and interfacial reactions of GNPs with matrix. Herein, GNPs/Ti‐6Al‐4V (GNPs/TC4) composites are synthesized using high energy ball milling (HEBM) and spark plasma sintering. Effects of ball milling on microstructural evolution and interfacial reactions of GNPs/TC4 composite powders during HEBM are investigated. As ball milling time increase, particles size of TC4 is first increased (e.g., ≈104.15 μm, 5 h), but then decreased to ≈1.5 μm (15 h), which is much smaller than that of original TC4 powders (≈86.8 μm). TiC phases are in situ formed on the surfaces of TC4 particles when ball milling time is 10Thinsp;h. GNPs/TC4 composites exhibit 36–103% increase in compressive yield strength and 57–78% increase in hardness than those of TC4 alloy, whereas the ductility is reduced from 28% to 7% with an increase of ball milling time (from 2 to 15 h). A good balance between high strength (1.9 GPa) and ductility (17%) of GNPs/TC4 composites is achieved when the ball milling time is 10 h, attributing to the synergistic effects of grain refinement strengthening, solid solution strengthening, and load transfer strengthening from GNPs and in situ formed TiC

Microstructure and Corrosion Behavior of Composite Coating on Pure Mg Acquired by Sliding Friction Treatment and Micro-Arc Oxidation

For the purpose of detecting the influence of grain structure of a Mg matrix on the microstructure and corrosion resistance of micro-arc oxidation (MAO) coating, prior to MAO processing, sliding friction treatment (SFT) was adopted to generate a fine-grained (FG) layer on coarse-grained (CG) pure Mg surface. It showed that the FG layer had superior corrosion resistance, as compared to the CG matrix, owing to the grain refinement; furthermore, it successfully survived after MAO treatment. Thus, an excellent FG-MAO coating was gained by combining SFT and MAO. The surface morphology and element composition of FG-MAO and CG-MAO samples did not show significant changes. However, the FG layer favorably facilitated the formation of an excellent MAO coating, which possessed a superior bonding property and greater thickness. Consequently, the modified FG-MAO sample possessed enhanced corrosion resistance, since a lower hydrogen evolution rate, a larger impedance modulus and a lower corrosion current were observed on the FG-MAO sample

MXene Film Prepared by Vacuum-Assisted Filtration: Properties and Applications

MXene (Ti3C2Tx) film prepared by vacuum-assisted filtration (V-MXene film) is the most common 2D MXene macroscopic assembly with ultra-high electrical conductivity, tunable interlayer space, diverse surface chemical properties, favorable mechanical properties and so on, showing great commercial value in the fields of energy storage, electromagnetic interference shielding and actuators and so on. This paper focuses on the preparation, properties and applications of V-MXene film, objectively reviews and evaluates the important research progress of V-MXene film in recent years and analyzes the main problems at present. In addition, the development direction and trend of V-MXene film in the future are prospected from the aspects of preparation, property control and application fields, which provide guidance and inspiration for the further development of functional MXene-based films and make contributions to the progress of MXene technology

MXene Film Prepared by Vacuum-Assisted Filtration: Properties and Applications

MXene (Ti3C2Tx) film prepared by vacuum-assisted filtration (V-MXene film) is the most common 2D MXene macroscopic assembly with ultra-high electrical conductivity, tunable interlayer space, diverse surface chemical properties, favorable mechanical properties and so on, showing great commercial value in the fields of energy storage, electromagnetic interference shielding and actuators and so on. This paper focuses on the preparation, properties and applications of V-MXene film, objectively reviews and evaluates the important research progress of V-MXene film in recent years and analyzes the main problems at present. In addition, the development direction and trend of V-MXene film in the future are prospected from the aspects of preparation, property control and application fields, which provide guidance and inspiration for the further development of functional MXene-based films and make contributions to the progress of MXene technology

Electrochemical Corrosion Behavior and Mechanical Properties of Nanocrystalline Ti–6Al–4V Alloy Induced by Sliding Friction Treatment

A nanograined (NG) layer with an average grain size of less than 100 nm has been successfully prepared on a Ti–6Al–4V sheet surface by sliding friction treatment (SFT). The electrochemical corrosion/passive behavior and mechanical properties of an NG Ti–6Al–4V sheet were examined in this study. A bi-layer passive film that consisted of an outer TiO2-rich layer and an inner Al2O3-rich layer was formed on either an NG or coarse-grained (CG) surface. The improved corrosion was mainly caused by the enhanced stability and thickness of the passive layer. Tensile experiments were carried out to evaluate the mechanical properties at ambient temperature. The NG Ti–6Al–4V sample exhibited the high yield strength (956 MPa) with a moderate elongation of 8%. These superior comprehensive properties demonstrated its potential as a biomedical material