43 research outputs found
N-(2-Pyridylmethyl)phthalimide
In the title compound, C14H10N2O2, the phtalimide and 2-pyridylmethyl units are almost perpendicular, with an interplanar angle of 85.74 (2)°. In the crystal, molecules are linked by weak C—H⋯O interactions, forming chains running along the b axis. The packing is further stabilized by offset π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.855 (2) Å
{2-Hydroxy-6-[(2-oxidophenyl)iminomethyl-κ2 N,O]phenolato-κO 1}phenylboron
The [4.3.0]heterobicyclic title structure, C19H14BNO3, is composed of a five-membered OBNC2 ring and a six-membered OBNC3 ring, each of which has an approximate envelope conformation. The coordination geometry of the B atom is distorted tetrahedral. In the crystal structure, centrosymmetrically related molecules are associated through pairs of O—H⋯O hydrogen bonds
2,4-Difluorophenylboronic acid
The molecular structure of the title compound, C6H5BF2O2, is essentially planar (mean deviation = 0.019 Å), indicating electronic delocalization between the dihydroxyboryl group and the aromatic ring. In the crystal structure, inversion dimers linked by two O—H⋯O hydrogen bonds arise. An intramolecular O—H⋯F hydrogen bond reinforces the conformation and the same H atom is also involved in an intermolecular O—H⋯F link, leading to molecular sheets in the crystal
3-Aminophenylboronic acid monohydrate
In the title compound, C6H8BNO2·H2O, the almost planar boronic acid molecules (r.m.s. deviation = 0.044 Å) form inversion dimers, linked by pairs of O—H⋯O hydrogen bonds. The water molecules link these dimers into [100] chains by way of O—H⋯O hydrogen bonds, and N—H⋯O links generate (100) sheets
Poly[aquabis(μ-benzene-1,2-dicarboxylato)ethanoltetralithium]
In the crystal structure of the title compound [Li4(C8H4O4)2(C2H5OH)(H2O)]n, there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxylate groups act as bidentate–bridging ligands producing a two-dimensional coordination network parallel to the ab plane. The coordination polymer is further stabilized by coordination of water and ethanol molecules by the Li+ ions. Simultaneously, the water and ethanol molecules are involved in O—H⋯O and C—H⋯π interactions
4-Methoxy-N-[6-methyl-2,3-dihydro-1,3-benzothiazol-2-ylidene]benzenesulfonamide
The title compound, C15H14N2O3S2, is of interest with respect to its biological activity. The crystal structure is stabilized by intermolecular N—H⋯N, C—H⋯O and C—H⋯π hydrogen-bonding interactions, as well as offset π–π interactions [distance between the centroids of the aryl and thiazole rings of adjacent molecules of 3.954 (2) Å]
Poly[potassium-μ-2-[2-(carboxymethyl)phenyl]acetato]
In the title salt, [K(C10H9O4)]n, the K+ ions are coordinated by six O atoms from three different anions, and there is a cation–π interaction at ca 3.14 Å. The 2-[2-(carboxymethyl)phenyl]acetate anions are stabilized by intramolecular O—H⋯O hydrogen bonds, and the K+ cations are linked into one-dimensional coordination polymers running along the b axis; these are further interconnected by weak C—H⋯O hydrogen bonds
(E)-2-{[2-(2-Hydroxyethylamino)ethylimino]methyl}phenol
The asymmetric unit of the title compound, C11H16N2O2, contains two independent conformational isomers which show intramolecular aromatic–imine O—H⋯N hydrogen bonds. In the crystal, neighboring molecules are linked through intermolecular aliphatic–aliphatic O—H⋯N, aliphatic–aromatic N—H⋯O and C—H⋯O interactions into hydrogen-bonded layers parallel to the ab plane
2-Methyl-2-(4-nitrophenoxy)propanoic acid
The title compound, C10H11NO5, is of interest with respect to its antidyslipidemic activity. It was prepared by reaction of 4-nitrophenol with ethyl 2-bromo-2-methylpropionate followed by ethyl ester hydrolysis. In the crystal, molecules are linked into centrosymmetric dimers by intermolecular O—H⋯O hydrogen bonds and the dimers are connected into chains by weak C—H⋯O interactions. The packing is further stabilized by offset π–π interactions between adjacent benzene rings with a centroid–centroid distance of 3.8643 (17) Å
2-Methyl-2-(4-nitrophenylsulfanyl)propanoic acid
The title compound, C10H11NO4S, is of interest with respect to its biological activity. The molecules are linked into centrosymmetric dimers by intermolecular O—H⋯O hydrogen bonds and the dimers are further connected into chains by weak C—H⋯O interactions