Catalysts for electrochemical generation of oxygen

An effort was made to study the effects of cation and anion additions on oxygen evolution kinetics on platinum and the inhibitive or catalytic nature of the additions. The kinetics and mechanism of oxygen evolution on planitum metal in hydrofluoric and sulfuric acids, including the effects of foreign anions, were examined. The LEED-Auger-thin layer electrochemical system was developed for the examination of electrocatalytic surfaces. Samples for electrocatalytic LEED-Auger studies were prepared and examined

Electrochemical generation of oxygen. 1: The effects of anions and cations on hydrogen chemisorption and anodic oxide film formation on platinum electrode. 2: The effects of anions and cations on oxygen generation on platinum electrode

The effects were studied of anions and cations on hydrogen chemisorption and anodic oxide film formation on Pt by linear sweep voltammetry, and on oxygen generation on Pt by potentiostatic overpotential measurement. The hydrogen chemisorption and anodic oxide film formation regions are greatly influenced by anion adsorption. In acids, the strongly bound hydrogen occurs at more cathodic potential when chloride and sulfate are present. Sulfate affects the initial phase of oxide film formation by produced fine structure while chloride retards the oxide-film formation. In alkaline solutions, both strongly and weakly bound hydrogen are influenced by iodide, cyanide, and barium and calcium cations. These ions also influence the oxide film formation. Factors considered to explain these effects are discussed. The Tafel slope for oxygen generation was found to be independent on the oxide thickness and the presence of cations or anions. The catalytic activity indicated by the exchange current density was observed decreasing with increasing oxide layer thickness, only a minor dependence on the addition of certain cations and anions was found

Comparison of wind and turbulence measurements from Doppler lidar and instrumented aircraft

Wind fields were measured with the ground based lidar, NOAA Wave Propagation Laboratory and with the NASA B-57B instrumented aircraft. The remotely sensed winds are compared with the in situ aircraft measurements. Three flight plans were carried out during the two different field programs. At NASA/MSFC the aircraft circled while the lidar scanned conically and the aircraft flew 6 deg approach path along the fixed lidar beam. The aircraft flew an approach along the lidar beam directed south-north (parallel to the mountain range) and a climbout along the lidar beam which alternately shifted east-west (perpendicular to the mountain range). Turbulence intensities and spectra were calculated from the temporal fluctuations in the lidar-measured radial wind speed component. These field tests provided unique sets of data to examine the mean wind and turbulence measurements made by remote sensing instruments. The comparison of aircraft measured turbulence intensities and spectra with lidar time histories of radial wind speed were in good agreement

Revised Huang-Yang multipolar pseudopotential

A number of authors have recently pointed out inconsistencies of results obtained with the Huang-Yang multipolar pseudo-potential for low-energy scattering [K. Huang and K. C. Yang, Phys. Rev. A, v 105, 767 (1957); later revised in K. Huang, ``Statistical Mechanics'', (Wiley, New York, 1963)]. The conceptual validity of their original derivation has been questioned. Here I show that these inconsistencies are rather due to an {\em algebraic} mistake made by Huang and Yang. With the corrected error, I present the revised version of the multipolar pseudo-potential

Studies related to ocean dynamics. Task 3.2: Aircraft Field Test Program to investigate the ability of remote sensing methods to measure current/wind-wave interactions

The feasibility of remote sensing of current flows in the ocean and the remote sensing of ocean currents by backscattering cross section techniques was studied. It was established that for capillary waves, small scale currents could be accurately measured through observation of wave kinematics. Drastic modifications of waves by changing currents were noted. The development of new methods for the measurement of capillary waves are discussed. Improvement methods to resolve data processing problems are suggested